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Effects of the Inclusion of Ce and Ni Species on Ti for Modification of K10-Clay by Sol-Gel and their Use as Catalysts in the Liquid-Phase Esterification Systems

Published online by Cambridge University Press:  01 January 2024

G. Rangel-Porras ,
A. Quiroga-Almaguer ,
A. Ramírez-Hernández ,
B. Bachiller-Baeza ,
H. Pfeiffer-Perea  and
P. Rangel-Rivera
G. Rangel-Porras*
Affiliation:
Department of Chemistry, Division of Nature and Exact Sciences, University of Guanajuato, Noria Alta s/n, 36050 Guanajuato, Guanajuato, Mexico
A. Quiroga-Almaguer
Affiliation:
Department of Chemistry, Division of Nature and Exact Sciences, University of Guanajuato, Noria Alta s/n, 36050 Guanajuato, Guanajuato, Mexico
A. Ramírez-Hernández
Affiliation:
Institute of Applied Chemistry, University of Papaloapan, Circuíto Central No. 200, Parque Industrial, Tuxtepec, 68301 Oaxaca, Mexico
B. Bachiller-Baeza
Affiliation:
Group of Heterogeneous Catalysts for Selective Chemical Processes, Institute of Catalysis and Petrochemistry, C/Marie Curie 2, Cantoblanco, 28049, Madrid, Spain
H. Pfeiffer-Perea
Affiliation:
Department of Low Dimensional Materials, Institute of Materials Research, National Autonomous University of Mexico, Circuíto Exterior s/n, Ciudad Universitaria, Coyoacán, 04510 Mexico City, Mexico
P. Rangel-Rivera*
Affiliation:
Department of Chemistry, Division of Nature and Exact Sciences, University of Guanajuato, Noria Alta s/n, 36050 Guanajuato, Guanajuato, Mexico
*
e-mail: gporras@ugto.mx
e-mail: pedro.rangel.rivera.dr@gmail.com
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Abstract

The modification of montmorillonite with metallic species affects directly its crystalline structure, texture, porosity, and surface. The interaction of the metallic molecules with the clay matrix, derived from the modification pathway and the characteristics of the adsorbate, modifies the physicochemical properties of montmorillonite, enabling the creation of materials with varied characteristics to be used both as catalysts and adsorbents. Small amounts of metallic species can confer various structural and physicochemical characteristics on the same montmorillonite matrix, depending on the metal incorporated. The objective of the present study was to create an acid-base catalyst based on montmorillonite K10 (K10 Mnt), modified with Ti, Ce, and Ni, for the catalytic esterification of acetic acid and penta-1-ol. K10-Mnt was modified using particles of Ti and of Ti modified with Ce and Ni. The effect of the inclusion of Ti and modified Ti species on the transformation of the physicochemical properties of the K10 Mnt and their contributions to the catalytic esterification syntheses were investigated. Samples were characterized by scanning electron microscopy coupled to an energy-dispersive X-ray spectroscopy system (SEM-EDS), powder X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), physisorption of N2 at 77 K (BET and BJH), and thermogravimetric analysis (TGA-DTGA). Finally, the original and modified K10 Mnt samples were tested for their catalytic esterification of acetic acid and penta-1-ol in the liquid phase.

Keywords

EsterificationMontmorillonite K10Sol-gelTitaniumTitanium-ceriumTitanium-nickel
Type
Original Paper
Information
Clays and Clay Minerals , Volume 71 , Issue 2 , April 2023 , pp. 191 - 206
Copyright
Copyright © The Author(s), under exclusive licence to The Clay Minerals Society 2023

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