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Incorporation of Fe in the interlayer of Na-bentonite via treatment with FeCl3 in acetone

Published online by Cambridge University Press:  01 January 2024

Andrea Komlósi ,
Ernő Kuzmann ,
Noémi M. Nagy ,
Zoltán Homonnay ,
Shiro Kubuki  and
József Kónya
Andrea Komlósi
Affiliation:
Isotope Laboratory, Department of Colloid and Environmental Chemistry, University of Debrecen, Debrecen, 4010 PO Box 8, Hungary
Ernő Kuzmann
Affiliation:
Research Group for Nuclear Methods in Structural Chemistry, Hungarian Academy of Sciences, Eötvö s Loránd University, Pázmány P. s. 1/a, Budapest 1117, Hungary
Noémi M. Nagy*
Affiliation:
Isotope Laboratory, Department of Colloid and Environmental Chemistry, University of Debrecen, Debrecen, 4010 PO Box 8, Hungary
Zoltán Homonnay
Affiliation:
Research Group for Nuclear Methods in Structural Chemistry, Hungarian Academy of Sciences, Eötvö s Loránd University, Pázmány P. s. 1/a, Budapest 1117, Hungary
Shiro Kubuki
Affiliation:
Research Group for Nuclear Methods in Structural Chemistry, Hungarian Academy of Sciences, Eötvö s Loránd University, Pázmány P. s. 1/a, Budapest 1117, Hungary
József Kónya
Affiliation:
Isotope Laboratory, Department of Colloid and Environmental Chemistry, University of Debrecen, Debrecen, 4010 PO Box 8, Hungary
*
*E-mail address of corresponding author: noemi@tigris.unideb.hu
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Abstract

The effect of FeCl3 in acetonic medium on the structure of Na-bentonite was studied using X-ray diffraction (XRD), 57Fe Mössbauer spectroscopy, X-ray fluorescence spectroscopy and infrared spectroscopy to describe the structure of the bentonite before and after treatment. In the samples treated with FeCl3, an increase in the basal spacing was found by XRD, while a new magnetically split component assigned to Fe3+ incorporated within the interlayer regions of montmorillonite showed up in the low-temperature Mössbauer spectra. The Mössbauer parameters observed were close to those of Fe oxyhydroxides, suggesting the presence of some kind of nanoparticles. These results show that the treatment with acetonic FeCl3 solution is an effective method for introducing Fe into montmorillonite in the form of Fe3+ accommodated in the interlayer region. The treated samples proved to be efficient Lewis catalysts in the acylation of aldehydes (benzaldehyde and 4-OH-benzaldehyde) by acetic acid anhydride.

Keywords

BentoniteClayInterlayerIronInfrared SpectroscopyMössbauer SpectroscopyXRDXRF
Type
Research Article
Information
Clays and Clay Minerals , Volume 55 , Issue 1 , February 2007 , pp. 89 - 95
Copyright
Copyright © 2007, The Clay Minerals Society

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Footnotes

on leave from Ube National College of Technology, Japan

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