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Low-temperature FTIR study of kaolin-group minerals

Published online by Cambridge University Press:  01 January 2024

Cliff T. Johnston ,
Jessica Elzea Kogel ,
David L. Bish ,
Toshihiro Kogure  and
Haydn H. Murray
Cliff T. Johnston*
Affiliation:
Crop, Soil and Environmental Sciences, Purdue University, 915 W. State Street, West Lafayette, IN 47907-2054, USA
Jessica Elzea Kogel
Affiliation:
IMERYS, Sandersville, GA 31082, USA
David L. Bish
Affiliation:
Department of Geological Sciences, Indiana University, Bloomington, IN 47405, USA
Toshihiro Kogure
Affiliation:
Department of Earth and Planetary Science, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
Haydn H. Murray
Affiliation:
Department of Geological Sciences, Indiana University, Bloomington, IN 47405, USA
*
* E-mail address of corresponding author: clays@purdue.edu
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Abstract

Low-temperature FTIR spectroscopy was used to characterize the v(OH) region of kaolin-group minerals including well ordered to poorly ordered kaolins from Georgia, Brazil, and England, along with samples of discrete dickite and nacrite. Low-temperature FTIR spectra were useful in resolving dickite- and nacrite-like features present in the spectra of kaolins when cooled to <30 K. These features were not resolved at room temperature and only partially resolved at liquid N2 temperature (77 K). The room-temperature and low-temperature positions of the ν(OH) bands of kaolinite, dickite, and nacrite were linearly correlated with the interatomic OH⋯O distances and this relationship served as the basis for polytype/disorder identification. Dickite or dickite-like disorder was found in high Hinckley-Index kaolinite from Keokuk, Iowa, and from Cornwall, England. Dickite- and nacrite-like features were observed in both high- and low-Hinckley-index kaolinite and the amounts of these stacking sequences generally increased with decreasing Hinckley Index.

Keywords

DickiteFTIR SpectroscopyHinckley IndexKaolin-group MineralsKaoliniteLow-temperature FTIR SpectroscopyNacriteStructural Disorder
Type
Article
Information
Clays and Clay Minerals , Volume 56 , Issue 4 , August 2008 , pp. 470 - 485
Copyright
Copyright © 2008, The Clay Minerals Society

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