Hostname: page-component-848d4c4894-ttngx Total loading time: 0 Render date: 2024-06-01T01:35:24.830Z Has data issue: false hasContentIssue false

Mineralogy and Geochemistry of the Host-Rock Alterations Associated with the Shea Creek Unconformity-Type Uranium Deposits (Athabasca Basin, Saskatchewan, Canada). Part 2. Regional-Scale Spatial Distribution of the Athabasca Group Sandstone Matrix Minerals

Published online by Cambridge University Press:  01 January 2024

Philippe Kister*
Affiliation:
UMR CNRS 7566 G2R-CREGU, UHP, BP 239, 54506 Vandœuvre-lès-Nancy Cedex, France
Emmanuel Laverret
Affiliation:
HydrASA, UMR CNRS 6532, Université de Poitiers, 40 av. du Recteur Pineau, 86022 Poitiers Cedex, France
David Quirt
Affiliation:
Saskatchewan Research Council, 15 Innovation Blvd., Saskatoon, Saskatchewan, S7N 2X8, Canada
Michel Cuney
Affiliation:
UMR CNRS 7566 G2R-CREGU, UHP, BP 239, 54506 Vandœuvre-lès-Nancy Cedex, France
Patricia Patrier Mas
Affiliation:
HydrASA, UMR CNRS 6532, Université de Poitiers, 40 av. du Recteur Pineau, 86022 Poitiers Cedex, France
Daniel Beaufort
Affiliation:
HydrASA, UMR CNRS 6532, Université de Poitiers, 40 av. du Recteur Pineau, 86022 Poitiers Cedex, France
Patrice Bruneton
Affiliation:
COGEMA, Business Unit Mines, 2, rue Paul Dautier, BP 4, 78141 Velizy Cedex, France
*
*E-mail address of corresponding author: pkister@cogema.fr

Abstract

The spatial distribution of the dominant matrix minerals present in the middle-Proterozoic Athabasca Group sandstone (kaolin, illite, sudoite, dravite, hematite) was studied at a regional scale in the Shea Creek region (Saskatchewan, Canada), in which two epigenetic unconformity-type uranium deposits have been discovered. 3D models of matrix mineral distribution were derived from normative mineral calculations and 3D interpolation using whole-rock geochemical analyses of sandstone samples collected from both mineralized and barren areas. The calculations were constrained by information obtained from petrographic and crystal-chemical clay mineralogical studies on representative samples. The 3D mineral distribution models were compared to the lithostratigraphy and structural features of the Athabasca Group sandstone to ascertain the source and mobility of the main elements involved in the sandstone host-rock alteration processes related to the U mineralization. The distribution of Al is conformable with the lithostratigraphy throughout the studied area, regardless of proximity to basement-rooted structures and U ore bodies. The distribution of illite displays similar features, but the intensity of the illitization of kaolin decreases with increasing distance from the structures and U ore bodies. Hematite bleaching and neoformation of sudoite and dravite were restricted to the vicinity of the fault zones above the U ore bodies. The spatial configurations of the mineral anomalies show that syn-ore fluids flowed from the basement towards the sandstone cover via the fault zones, as described in current metallogenic models. Although Al remained immobile (mass transfer), the anomalous K, B and Mg present in the host-rock alteration haloes were probably imported from the basement rocks (mass transport). Unlike B and Mg, K migrated laterally at least several kilometers from the basement-rooted faults. The mineral distribution models were used to quantify the volume of altered sandstone (10−2−10−1 km3) and the amounts of K, Mg and B which were imported to the alteration haloes above the Shea Creek U ore bodies: 186,000 t of K, 66,000 t of Mg, and 11,000 t of B above the Anne ore body, and 24,000 t of K, 185,000 t of Mg, and a similar 11,000 t of B above the Colette ore body.

Type
Research Article
Copyright
Copyright © 2006, The Clay Minerals Society

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Armstrong, R.L. and Ramaekers, P., (1985) Srisotopic study of Helikian sediment and basaltic dykes in the Athabasca Basin, northern Saskatchewan Canadian Journal of Earth Sciences 22 399407 10.1139/e85-038.CrossRefGoogle Scholar
Beaufort, D. Cassagnabère, A. Petit, S. Lanson, B. Berger, G. Lacharpagne, J.-C. and Johansen, H., (1998) Kaolinite-to-dickite reaction in sandstone reservoir Clay Minerals 33 297316 10.1180/000985598545499.CrossRefGoogle Scholar
Berger, G. Lacharpagne, J.-C. Velde, B. Beaufort, D. and Lanson, B., (1997) Kinetic constraints on illitization reactions and the effect of organic diagenesis in sandstone/shales sequences Applied Geochemistry 12 2335 10.1016/S0883-2927(96)00051-0.CrossRefGoogle Scholar
Berger, G. Velde, B. and Aigouy, T., (1999) Potassium sources and illitization in Texas Gulf Coast shale diagenesis Journal of Sedimentary Research 69 151157 10.2110/jsr.69.151.CrossRefGoogle Scholar
Billaut, V. Beaufort, D. Patrier, P. and Petit, S., (2002) Crystal chemistry of Fe-sudoites from uranium deposits in the Athabasca Basin (Saskatchewan, Canada) Clays and Clay Minerals 50 7081 10.1346/000986002761002847.CrossRefGoogle Scholar
Brouand, M. and Cuney, M., (2002) Age and nature of the plutonism of the western part of the Athabasca basin basement (northern Saskatchewan, Canada) GAC-MAC Joint Annual Meeting, Saskatoon, SK 27 14 Abstracts.Google Scholar
Card, C.D. (2002) New investigations of basement to the western Athabasca Basin. Pp. 117 in: Summary of Investigations 2002, Volume 2, Saskatchewan Geological Survey, Miscellaneous Report 2002–4.2.Google Scholar
Collier, B. (2002) Detailed stratigraphy and facies analysis of the Paleoproterozoic Athabasca Group along the Shea-Creek-Douglas River transect, northern Saskatchewan. Pp. 116 in: Summary of Investigations 2002, Volume 2, Saskatchewan Geological Survey, Miscellaneous Report 2002–4.2.Google Scholar
Collier, B., Yeo, G., Long, D., Robbins, J. and Koning, E. (2001) Preliminary report on the stratigraphy of the Athabasca Group in the vicinity of the Shea Creek project, southwestern Athabasca Basin. Pp. 266271 in: Summary of Investigations 2001, Volume 2, Saskatchewan Geological Survey, Miscellaneous Report 2001–4.2.Google Scholar
Derome, D. Cathelineau, M. Cuney, M. Fabre, C. and Cuney, M., (2003) Reconstitution of the P, T, X characteristics of paleofluids in the McArthur River unconformity-type uranium deposit (Saskatchewan, Canada) Uranium Geochemistry 2003 Nancy, France International Conference Proceedings, UMR-CNRS 7566 G2R 141144.Google Scholar
Drever, J.I. and Drever, J.I., (1988) Stability relationships and silicate equilibria The Geochemistry of Natural Waters New Jersey Prentice Hall 99123.Google Scholar
Drummond, S.A. and Palmer, D.A., (1986) Thermal decarboxylation of acetate. Part II. Boundary conditions for the role of acetate in the primary migration of natural gas and the transportation of metals in hydrothermal systems Geochimica et Cosmochimica Acta 50 825833 10.1016/0016-7037(86)90358-3.CrossRefGoogle Scholar
Fein, J.B. Yane, L. and Handa, T., (1994) The effect of aqueous complexation on the decarboxylation rate of oxalate Geochimica et Cosmochimica Acta 58 39753981 10.1016/0016-7037(94)90260-7.CrossRefGoogle Scholar
Garven, G. Raffensperger, J.P. and Barnes, H.L., (1997) Hydrogeology and geochemistry of ore genesis in sedimentary basins Geochemistry of Hydrothermal Ore Deposits New York John Wiley & Sons 125189.Google Scholar
Heinrich, C.A. and Seward, T.M., (1990) A spectrophotometric study of aqueous iron (II) chloride complexation from 25°C to 200°C Geochimica et Cosmochimica Acta 54 22072221 10.1016/0016-7037(90)90046-N.CrossRefGoogle Scholar
Hiatt, E. and Kyser, K. (2000) Links between depositional and diagenetic processes in basin analysis: an overview of porosity and permeability evolution in sedimentary rocks. Pp. 6390 in: Fluids and Basin Evolution (Kyser, K., editor). Short Course Series 28, Mineralogical Association of Canada.Google Scholar
Hoeve, J. and Quirt, D. (1984) Mineralization and host rock alteration in relation to clay mineral diagenesis and evolution of the middle-Proterozoic Athabasca Basin, northern Saskatchewan, Canada. SRC Technical Report 187, Saskatchewan Research Council, 187 pp.Google Scholar
Hoeve, J. and Sibbald, T.I.I., (1978) On the genesis of Rabbit Lake and other unconformity-type uranium deposits in northern Saskatchewan, Canada Economic Geology 73 14501473 10.2113/gsecongeo.73.8.1450.CrossRefGoogle Scholar
Hurst, A. and Irwin, H., (1982) Geological modeling of clay diagenesis in sandstones Clay Minerals 17 522 10.1180/claymin.1982.017.1.03.CrossRefGoogle Scholar
Hutcheon, I. (2000) Principles of diagenesis and what drives mineral change. Pp. 93114 in: Fluids and Basin Evolution (Kyser, K., editor). Short Course Series, 28, Mineralogical Association of Canada.Google Scholar
Jambor, J.L. and Dilabio, R.N. (1978) Distribution of hydrothermal clays in the Highland Valley copper porphyry deposit, British Columbia. Geological Survey of Canada Paper 7790.CrossRefGoogle Scholar
Komninou, A. and Sverjensky, D.A., (1996) Geochemical modeling of the formation of an unconformity-type uranium deposit Economic Geology 91 590606 10.2113/gsecongeo.91.3.590.CrossRefGoogle Scholar
Kotzer, T.G. and Kyser, T.K., (1995) Petrogenesis of the Proterozoic Athabasca Basin, northern Saskatchewan, Canada, and its relation to diagenesis, hydrothermal uranium mineralization and paleohydrogeology Chemical Geology 120 4589 10.1016/0009-2541(94)00114-N.CrossRefGoogle Scholar
Kyser, K. and Hiatt, E.E., (2003) Fluids in sedimentary basins: an introduction Journal of Geochemical Exploration 80 139149 10.1016/S0375-6742(03)00188-2.CrossRefGoogle Scholar
Lanson, B. Beaufort, D. Berger, G. Bauer, A. Cassagnabère, A. and Meunier, A., (2002) Authigenic kaolin and illitic minerals during burial diagenesis of sandstones: a review Clay Minerals 37 122 10.1180/0009855023710014.CrossRefGoogle Scholar
Laverret, E., (2002) Les paragénèses argileuses associées aux gisements d’uranium sous discordance, secteur de Shea Creek (Bassin de l’Athabasca, Canada) France Université de Poitiers 192 pp.Google Scholar
Laverret, E. Patrier Mas, P. Beaufort, D. Kister, P. Quirt, D. Bruneton, P. and Clauer, N., (2006) Mineralogy and geochemistry of the host-rock alterations associated with the Shea Creek unconformity-type uranium deposits (Athabasca Basin, Saskatchewan, Canada) Part 1. Spatial variation of illite properties Clays and Clay Minerals 54 275294 10.1346/CCMN.2006.0540301.CrossRefGoogle Scholar
Lorilleux, G. Jébrak, M. Cuney, M. and Baudemont, D., (2002) Polyphase hydrothermal breccias associated with unconformity-type uranium mineralization (Canada): from fractal analysis to structural significance Journal of Structural Geology 24 323338 10.1016/S0191-8141(01)00068-2.CrossRefGoogle Scholar
Lorilleux, G. Cuney, M. Jébrak, M. Rippert, J.C. and Portella, P., (2003) Chemical brecciation processes in the Sue unconformity-type uranium deposits, Eastern Athabasca Basin (Canada) Journal of Geochemical Exploration 80 241258 10.1016/S0375-6742(03)00193-6.CrossRefGoogle Scholar
Mallet, J.-L., (1992) Discrete smooth interpolation Computer Design 24 178191 10.1016/0010-4485(92)90054-E.Google Scholar
McGill, B.D. Marlartt, J.L. Matthews, R.B. Sopuck, V.J. and Homeniuk, L.A., (1993) The P2 North Uranium Deposit, Saskatchewan, Canada Exploration and Mining Geology 2 321331.Google Scholar
Pacquet, A. and Weber, F., (1993) Pétrographie et minéralogie des haloes d’altération autour du gisement de Cigar Lake et leurs relations avec les minéralisations Canadian Journal of Earth Science 30 674688 10.1139/e93-055.CrossRefGoogle Scholar
Pagel, M. and Svab, M. (1985) Petrographic and geochemical variations within the Carswell Structure metamorphic core and their implications with respect to uranium mineralization. Pp. 5570 in: The Carswell Structure Uranium Deposits, Saskatchewan, (Lainé, R., Alonso, D. and Svab, M., editors). Special Paper 29, Geological Association of Canada.Google Scholar
Percival, J.B. Bell, K. and Torrance, J.K., (1993) Clay mineralogy and isotope geochemistry of the alteration halo at the Cigar Lake uranium deposit Canadian Journal of Earth Sciences 30 689704 10.1139/e93-056.CrossRefGoogle Scholar
Quirt, D.H., (1995) Norm calculation procedure for sandstone clay minerals Canada Saskatchewan Research Council 14 pp.Google Scholar
Quirt, D.H., (2001) Kaolinite and dickite in the Athabasca Sandstone, northern Saskatchewan, Canada Canada Saskatchewan Research Council 27pp.Google Scholar
Quirt, D., Kotzer, T. and Kyser, T.K. (1991) Tourmaline, phosphate minerals, zircon and pitchblende in the Athabasca Group: Maw Zone and McArthur River areas, Saskatchewan. Pp. 181191 in: Summary of Investigations 1991, Saskatchewan Geological Survey, Miscellaneous Report 1991–4.Google Scholar
Raffensperger, J.P. and Garven, G., (1995) The formation of unconformity-type uranium ore deposits. 2. Coupled hydro-chemical modeling American Journal of Science 295 639696 10.2475/ajs.295.6.639.CrossRefGoogle Scholar
Ramaekers, P., (1990) Geology of the Athabasca Group (Helikian) in Northern Saskatchewan Canada Saskatchewan Geological Survey 49 pp.Google Scholar
Ramaekers, P., Yeo, G. and Jefferson, G. (2001) Preliminary overview of regional stratigraphy in the Late Paleoproterozoic Athabasca Basin, Saskachewan and Alberta. Pp. 240251 in: Summary of Investigations 2001, Volume 2, Saskatchewan Geological Survey, Miscellaneous Report 2001–4.2, Canada.Google Scholar
Reed, M.H. and Barnes, H.L., (1997) Hydrothermal alteration and its relationship to ore fluid composition Geochemistry of Hydrothermal Ore Deposits New York John Wiley & Sons, Inc. 303366.Google Scholar
Rippert, J.C. Koning, E. Robbins, J. Koch, R. and Baudemont, D., (2000) The Shea Creek Uranium Project, West Athabasca Basin, Saskatchewan, Canada Abstract 570 in Proceedings of Geo Canada 2000, The Millennium Geoscience Summit Calagary GAC-MAC joint annual meeting.Google Scholar
Salvi, S. Pokrovski, G.S. and Schott, J., (1998) Experimental investigation of aluminium-silica aqueous complexing at 300°C Chemical Geology 151 5167 10.1016/S0009-2541(98)00070-9.CrossRefGoogle Scholar
Skinner, B.J. and Barnes, H.L., (1997) Hydrothermal mineral deposits: what we do and don’t know Geochemistry of Hydrothermal Ore Deposits New York John Wiley & Sons, Inc. 129.Google Scholar
Thomas, D.J. Matthews, R.B. and Sopuck, V., (2000) Athabasca Basin (Canada) Unconformity-Type Uranium Deposits: Exploration Model, Current Mine Developments and Exploration Directions Geology and Ore Deposits 2000: The Great Basin and Beyond USA Geological Society of Nevada 123.Google Scholar
Wilkinson, M. and Haszeldine, R.S., (1996) Aluminium loss during sandstone diagenesis Journal of the Geological Society, London 153 657660 10.1144/gsjgs.153.5.0657.CrossRefGoogle Scholar
Wilkinson, M. and Haszeldine, R.S., (1997) Discussion on aluminium loss during sandstone diagenesis Journal of the Geological Society, London 154 747751 10.1144/gsjgs.154.4.0747.Google Scholar
Wilson, J.A., (1984) Crandallite group minerals in the Helikian Athabasca Group in Alberta, Canada Canadian Journal of Earth Sciences 22 637641 10.1139/e85-065.CrossRefGoogle Scholar