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Polarization of Water Molecules in Phyllosilicates in Relation to Exchange Cations as Studied by Near Infrared Spectroscopy

Published online by Cambridge University Press:  02 April 2024

F. Cariati ,
L. Erre ,
G. Micera ,
P. Piu  and
C. Gessa
F. Cariati
Affiliation:
Istituto di Chimica Generate e Inorganica, Università di Sassari, Via Vienna 2, 07100 Sassari, Italy
L. Erre
Affiliation:
Istituto di Chimica Generate e Inorganica, Università di Sassari, Via Vienna 2, 07100 Sassari, Italy
G. Micera
Affiliation:
Istituto di Chimica Generate e Inorganica, Università di Sassari, Via Vienna 2, 07100 Sassari, Italy
P. Piu
Affiliation:
Istituto di Chimica Generate e Inorganica, Università di Sassari, Via Vienna 2, 07100 Sassari, Italy
C. Gessa
Affiliation:
Istituto di Chimica Agraria, Università di Sassari, Via de Nicola, 07100 Sassari, Italy
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Abstract

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Keywords

BentoniteExchangeable cationsNear infrared spectroscopyPolarizationWater
Type
Note
Information
Clays and Clay Minerals , Volume 31 , Issue 2 , April 1983 , pp. 155 - 157
Copyright
Copyright © 1983, The Clay Minerals Society

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References

Bart, J. C. J., Cariati, F., Erre, L., Gessa, C., Micera, G. and Piu, P., 1979 Formation of polymeric species in the interlayer of bentonite Clays & Clay Minerals 27 429–432.CrossRefGoogle Scholar
Cariati, F., Erre, L., Micera, G., Piu, P. and Gessa, C., 1981 Water molecules and hydroxyl groups in montmorillonites as studied by near infrared spectroscopy Clays & Clay Minerals 29 157–159.CrossRefGoogle Scholar
Farmer, V. C. and Russell, J. D., 1971 Interlayer complexes in layer silicates: the structure of water in lamellar ionic solutions Trans. Faraday Soc. 67 2737–2749.CrossRefGoogle Scholar
Fripiat, J. J., Chaussidon, J. and Touillaux, R., 1960 Study of dehydration of montmorillonite and vermiculite by infrared spectroscopy J. Phys. Chem. 64 1234–1241.CrossRefGoogle Scholar
Fripiat, J. J., Helsen, J. A. and Vielvoye, J., 1964 Formation de radicaux libre sur la surface des montmorillonites Bull. Groupe Franc. Argiles 10 3–10.CrossRefGoogle Scholar
McBride, M. B., Pinnavaia, T. J. and Mortland, M. M., 1975 Electron spin relaxation and the mobility of manganese(II) exchange ions in smectites Amer. Mineral. 60 66–72.Google Scholar
McBride, M. B., Pinnavaia, T. J. and Mortland, M. M., 1975 Electron spin resonance studies of cation orientation in restricted water layers on phyllosilicate (smectite) surface J. Phys. Chem. 79 2430–2435.CrossRefGoogle Scholar
Mortland, M. M. and Raman, K. V., 1968 Surface acididy of smectites in relation to hydration, exchangeable cation, and structure Clays & Clay Minerals 16 393–398.CrossRefGoogle Scholar
Pietracaprina, A., Novelli, G. and Rinaldi, A., 1972 Bentonite deposit at Uri, Sardinia, Italy Clay Miner. 9 351–355.CrossRefGoogle Scholar
Poinsignon, C., Cases, J. M. and Fripiat, J. J., 1978 Electrical polarization of water molecules adsorbed by smectites. An infrared study J. Phys. Chem. 82 1855–1860.CrossRefGoogle Scholar
Russell, J. D. and Farmer, V. C., 1964 Infrared spectroscopic study of the dehydration of montmorillonite and sap-onite Clay Miner. Bull. 5 443–464.CrossRefGoogle Scholar