Hostname: page-component-848d4c4894-4hhp2 Total loading time: 0 Render date: 2024-06-08T08:24:06.861Z Has data issue: false hasContentIssue false
  • English
  • Français

Preparation of a Hierarchical Pore Zeolite with High-Temperature Calcination and Acid-Base Leaching

Published online by Cambridge University Press:  01 January 2024

Chengdong Wang ,
Jinhong Li ,
Xiang Wang ,
Zhiwei Yang  and
Kaiyue Huang
Chengdong Wang
Affiliation:
Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, School of Materials Science and Technology, China University of Geosciences, 100083, People's Republic of China
Jinhong Li*
Affiliation:
Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, School of Materials Science and Technology, China University of Geosciences, 100083, People's Republic of China
Xiang Wang
Affiliation:
Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, School of Materials Science and Technology, China University of Geosciences, 100083, People's Republic of China
Zhiwei Yang
Affiliation:
Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, School of Materials Science and Technology, China University of Geosciences, 100083, People's Republic of China
Kaiyue Huang
Affiliation:
Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, School of Materials Science and Technology, China University of Geosciences, 100083, People's Republic of China
*
*E-mail address of corresponding author: jinhong@cugb.edu.cn
Get access Rights & Permissions [Opens in a new window]

Abstract

Microporous structure in zeolite leads to diffusion limitation, which causes coke formation and is harmful to catalytic reactions. Hierarchical zeolite containing primary microporosity and secondary porosity at the meso- and macroscales has received much attention due to its enhanced mass transport. Hierarchical Y zeolites were obtained by treating NH4-Y zeolite with high-temperature calcining and acid-base leaching. The results demonstrated that the calcined zeolite showed great crystallinity after acid-base leaching. The mechanism of introduction of mesopores was demonstrated in detail. The calcination transformed framework Al to extra-framework Al and enlarged the defect by acid and alkali. The mesopores increased with the calcining temperature and holding time. The relationship between the heating rate and the removal of Al species was non-linear; a heating rate of 100°C/h exhibited good protection for the zeolite structure.

Keywords

Acid siteAcid-base leachingCalcinationHierarchical Y zeolitePore structure
Type
Article
Information
Clays and Clay Minerals , Volume 67 , Issue 4 , August 2019 , pp. 265 - 274
Copyright
Copyright © Clay Minerals Society 2019

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

This paper was originally presented during the World Forum on Industrial Minerals, held in Qing Yang, China, October 2018

References

Cui, Q. Wang, S. Wei, Q. Mu, L. Yu, G. Zhang, T. Zhou, Y., Synthesis and characterization of Zr incorporated small crystal size Y zeolite supported NiW catalysts for hydrocracking of vacuum gas oil Fuel 2019 237 597–605 10.1016/j.fuel.2018.10.040.CrossRefGoogle Scholar
Davis, M. E., Ordered porous materials for emerging applications Nature 2002 417 813–821 10.1038/nature00785.CrossRefGoogle ScholarPubMed
Fals, J. García, J. R. Falco, M. Sedran, U., Coke from SARA fractions in VGO. Impact on Y zeolite acidity and physical properties Fuel 2018 225 26–34 10.1016/j.fuel.2018.02.180.CrossRefGoogle Scholar
Feliczak-Guzik, A., Hierarchical zeolites: synthesis and catalytic properties Microporous & Mesoporous Materials 2017 259 S138718111730642X.Google Scholar
Galadima, A. Muraza, O., Hydrocracking catalysts based on hierarchical zeolites: a recent progress Journal of Industrial and Engineering Chemistry 2018 61 265–280 10.1016/j.jiec.2017.12.024.CrossRefGoogle Scholar
Hartmann, M. Machoke, A. G. Schwieger, W., Catalytic test reactions for the evaluation of hierarchical zeolites Chemical Society Reviews 2016 45 3313 10.1039/C5CS00935A.CrossRefGoogle ScholarPubMed
Hermann, J. Trachta, M. Nachtigall, P. Bludský, O., Theoretical investigation of layered zeolite frameworks: surface properties of 2D zeolites Catalysis Today 2014 227 2–8 10.1016/j.cattod.2013.09.016.CrossRefGoogle Scholar
Hong, Y. Fripiat, J. J., Microporous characteristics of H-Y, H-ZSM-5 and H-mordenite dealuminated by calcination Microporous Materials 1995 4 323–334 10.1016/0927-6513(95)00038-B.CrossRefGoogle Scholar
Iyoki, K., Yamaguchi, Y., Endo, A., Yonezawa, Y., Umeda, T., Yamada, H., Yanaba, Y., Yoshikawa, T., Ohara, K., & Yoshida, K. (2018) Formation of a dense non-crystalline layer on the surface of zeolite Y crystals under high-temperature steaming conditions. Microporous & Mesoporous Materials, 268.CrossRefGoogle Scholar
Ji, D., Liu, H., Wang, X., Liu, H., Gao, X., Xu, C., & Wei, S. (2017) Mesostructured Y zeolite from NaY with low Si/Al by one-step method based on bifunctional surfactant. Materials Chemistry & Physics, 196.CrossRefGoogle Scholar
Lee, K. Lee, S. Jun, Y. Choi, M., Cooperative effects of zeolite mesoporosity and defect sites on the amount and location of coke formation and its consequence in deactivation Journal of Catalysis 2017 347 222–230 10.1016/j.jcat.2017.01.018.CrossRefGoogle Scholar
Li, Cheng Guo, Linlin Liu, Peng Gong, K. e. Jin, Wenlong Li, Lei Zhu, Xiaochun Liu, Xianchun Shen, Baojian, Defects in AHFS-dealuminated Y zeolite: A crucial factor for mesopores formation in the following base treatment procedure Microporous and Mesoporous Materials 2018 255 242–252 10.1016/j.micromeso.2017.07.046.CrossRefGoogle Scholar
Manful, J. T. Grimm, C. C. Gayin, J. Coker, R. D., Effect of variable parboiling on crystallinity of rice samples Cereal Chemistry 2008 85 92–95 10.1094/CCHEM-85-1-0092.CrossRefGoogle Scholar
Moosavifar, M. Fathyunes, L., Influence of the post-synthesis method on the number and size of secondary mesoporous structure of NaY zeolite and its effect on catalyst loading. An efficient and eco-friendly catalyst for synthesis of xanthenes under conventional heating Journal of the Iranian Chemical Society 2016 13 1–8 10.1007/s13738-016-0929-4.CrossRefGoogle Scholar
Petrovic, I. Navrotsky, A., Thermochemistry of Na-faujasites with varying Si/Al ratios Microporous Materials 1997 9 1–12 10.1016/S0927-6513(96)00060-0.CrossRefGoogle Scholar
Qin, Z. Shen, B. Gao, X. Lin, F. Wang, B. Xu, C., Mesoporous Y zeolite with homogeneous aluminum distribution obtained by sequential desilication–dealumination and its performance in the catalytic cracking of cumene and 1,3,5-triisopropylbenzene Journal of Catalysis 2011 278 266–275 10.1016/j.jcat.2010.12.013.CrossRefGoogle Scholar
Remy, M. J. Stanica, D. Poncelet, G. Feijen, EJP Grobet, P. J. Martens, J. A. Jacobs, P. A., Dealuminated H-Y zeolites: relation between physicochemical properties and catalytic activity in heptane and decane isomerization The Journal of Physical Chemistry 1996 100 12440–12447 10.1021/jp953006x.CrossRefGoogle Scholar
Saepurahman, Hashaikeh, R., Insight into ball milling for size reduction and nanoparticles production of H-Y zeolite Materials Chemistry and Physics 2018 220 322–330 10.1016/j.matchemphys.2018.08.080.CrossRefGoogle Scholar
Sandoval-Díaz, L-E González-Amaya, J-A Trujillo, C-A, General aspects of zeolite acidity characterization Microporous & Mesoporous Materials 2015 215 229–243 10.1016/j.micromeso.2015.04.038.CrossRefGoogle Scholar
Saravanamurugan, S. Riisager, A., Zeolite catalyzed transformation of carbohydrates to alkyl levulinates ChemCatChem 2013 5 1754–1757 10.1002/cctc.201300006.CrossRefGoogle Scholar
Scherzer, J. (1984) Catalytic materials: Relationship between structure and reactivity. ACS Symposium Series, 157–200 pp.CrossRefGoogle Scholar
Shiralkar, V. P. Joshi, P. N. Eapen, M. J. Rao, B. S., Synthesis of Zsm-5 with variable crystallite size and its influence on physicochemical properties Zeolites 1991 11 511–516 10.1016/S0144-2449(05)80127-7.CrossRefGoogle Scholar
Triantafillidis, C. S. And, AGV Evmiridis, N. P., Dealuminated H−Y zeolites: influence of the degree and the type of dealumination method on the structural and acidic characteristics of H−Y zeolites Industrial & Engineering Chemistry Research 2000 39 307–319 10.1021/ie990568k.CrossRefGoogle Scholar
Van Oers, C. J. Stevens, WJJ Bruijn, E. Mertens, M. Lebedev, O. I. Van Tendeloo, G. Meynen, V. Cool, P., Formation of a combined micro- and mesoporous material using zeolite beta nanoparticles Microporous & Mesoporous Materials 2009 120 29–34 10.1016/j.micromeso.2008.08.056.CrossRefGoogle Scholar
Wei, R. Yang, H. Scott, J. A. Aguey-Zinsou, K. Zhang, D., Synthesis of 2D MFI zeolites in the form of self-interlocked nanosheet stacks with tuneable structural and chemical properties for catalysis Applied Materials Today 2018 11 22–33 10.1016/j.apmt.2018.01.007.CrossRefGoogle Scholar
Wojtaszek-Gurdak, A. Zielinska, M. Ziolek, M., MWW layered zeolites modified with niobium species-surface and catalytic properties Catalysis Today 2019 325 89–97 10.1016/j.cattod.2018.07.044.CrossRefGoogle Scholar
Xu, B. Bordiga, S. Prins, R. Bokhoven, JAV, Effect of framework Si/Al ratio and extra-framework aluminum on the catalytic activity of Y zeolite Applied Catalysis A General 2007 333 245–253 10.1016/j.apcata.2007.09.018.CrossRefGoogle Scholar
Yu, Z. W. Zheng, A. M. Wang, Q. A. Chen, L. Xu, J. Amoureux, J. P. Deng, F., Insights into the dealumination of zeolite HY revealed by sensitivity-enhanced Al-27 DQ-MAS NMR spectroscopy at high field Angewandte Chemie-International Edition 2010 49 8657–8661 10.1002/anie.201004007.CrossRefGoogle Scholar
Zhang, X. J. Wang, Y. Xin, F., Coke deposition and characterization on titanium silicalite-1 catalyst in cyclohexanone ammoximation Applied Catalysis A: General 2006 307 222–230 10.1016/j.apcata.2006.03.050.CrossRefGoogle Scholar
Zhao, J. Wang, G. Qin, L. Li, H. Chen, Y. Liu, B., Synthesis and catalytic cracking performance of mesoporous zeolite Y Catalysis Communications 2016 73 98–102 10.1016/j.catcom.2015.10.020.CrossRefGoogle Scholar
Zhou, C. Keeling, J., Fundamental and applied research on clay minerals: From climate and environment to nanotechnology Applied Clay Science 2013 74 3–9 10.1016/j.clay.2013.02.013.CrossRefGoogle Scholar
Zhou, C. Zhao, L. Wang, A. Chen, T. He, H., Current fundamental and applied research into clay minerals in China Applied Clay Science 2016 119 3–7 10.1016/j.clay.2015.07.043.CrossRefGoogle Scholar