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Spatial and temporal evolution of hydrothermal alteration at Lavras do sul, Brazil: Evidence from dioctahedral clay minerals

Published online by Cambridge University Press:  01 January 2024

Everton Marques Bongiolo ,
Patricia Patrier-Mas ,
André Sampaio Mexias ,
Daniel Beaufort  and
Milton Luiz Laquintinie Formoso
Everton Marques Bongiolo*
Affiliation:
CPRM, Geological Survey of Brazil, Rua Banco da Província 105, 90840-030, Porto Alegre, RS, Brasil Universidade Federal do Rio Grandedo Sul, UFRGS, Instituto de Geociências, Av. Bento Gonçalves 9500, 91509-900, Porto Alegre, RS, Brazil
Patricia Patrier-Mas
Affiliation:
Université de Poitiers, CNRS, HYDRASA, 40 Avenue du Recteur Pineau, 86022 Poitiers, France
André Sampaio Mexias
Affiliation:
Universidade Federal do Rio Grandedo Sul, UFRGS, Instituto de Geociências, Av. Bento Gonçalves 9500, 91509-900, Porto Alegre, RS, Brazil
Daniel Beaufort
Affiliation:
Université de Poitiers, CNRS, HYDRASA, 40 Avenue du Recteur Pineau, 86022 Poitiers, France
Milton Luiz Laquintinie Formoso
Affiliation:
Universidade Federal do Rio Grandedo Sul, UFRGS, Instituto de Geociências, Av. Bento Gonçalves 9500, 91509-900, Porto Alegre, RS, Brazil
*
* E-mail address of corresponding author: ebongiolo@pa.cprm.gov.br
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Abstract

TheAu-Cu (±Pb, Zn, Ag) prospects of Lavras do Sul, southernmost Brazil, arehosted in Neoproterozoic granitic and volcanogenic rocks. Mineralization occurs in structurally controlled N40°W to E-W quartz veins; sericite (±chlorite) and sulfides are the main secondary minerals in associated wall rocks.

In the present contribution we use petrography (optical microscopy and scanning electron microscopy (SEM)), mineralogy (X-ray diffraction (XRD) with polytypes, FWHM, decomposition of diffraction patterns), and crystal chemistry of samples from several prospects to document the spatial and temporal evolution of sericitic alteration of veins and wall rocks associated with gold.

Hexagonal, coarse-grained 2M1 phengite-rich alteration (± illite) is best developed with coarse-grained primary growth (comb) quartz + pyrite ± Au veins and altered wall rock from the western portion of the granitic complex (phyllic alteration). Pure phengite was recognized by narrow XRD profiles (FWHM ⩽ 0.2°2θ CuKα) of the <5 µm particle-size fraction, non-expandable d001 X-ray reflections and interlayer charge (IC) >0.9 per O10(OH)2.

Towards the eastern zones of the granitic complex and in the volcanogenic rocks, wider XRD profiles (FWHM values ⩾ 0.2°2θ CuKα) were decomposed. They contain mixtures of coarse- to fine-grained, lath-like crystals of both 2M1 and 1M illite (non-expandable d001 X-ray reflections, IC between 0.85 and 0.89 per O10(OH)2) with expandable d001 reflections associated with lath-like, fine-grained crystals of ordered (R ⩾ 1) illite-rich I-S (80–90% of illite; IC of ∼0.8 per O10(OH)2), and minor amounts of regularly ordered (R = 1), illite-rich I-S mixed layers (75% of illite; IC of ∼0.74 per O10(OH)2). The dioctahedral clay association of illite + illite-rich I-S mixed layers (intermediate argillic alteration) is best developed in quartz + pyrite ± Au veins, breccias, and wall-rock alteration from the eastern portion of the granitic complex and in the volcanic area. Quartz from veins and breccias has fine-grained primary growth, recrystallization, and replacement textures, similar to those in epithermal deposits.

The overall distribution of the dioctahedral clays indicates that the study area represents a fracture-controlled, tilted, porphyry to epithermal deposit, with telescoping alteration features observed in the east of the mining district. Deeper levels of exposure of a large hydrothermal system are observed in the west of the mining district, as shown by higher-rank dioctahedral minerals (phengite) that crystallize at relatively high temperatures (Tphe ≈ 300°C, phyllic alteration) associated with coarse-grained, primary-growth quartz veins, similar to those observed in porphyry deposits. On the other hand, shallower levels of exposure are observed in the east of the study area, associated with abundant, lower-rank dioctahedral clay minerals (illite + illite-rich I-S mixed layers, intermediate argillic alteration) that crystallize at relatively lower temperatures (TI-S ≈ 120–200°C).

Available data show that gold is associated with phengite, but that lower-rank, overprinting alteration characterized by illite-I-S may have locally modified the original gold grades.

Keywords

BrazilClay MineralsGoldHydrothermal AlterationIlliteLavras do SulMixed-layer Illite-smectitePhengitePolytypesProspectsX-ray Diffraction
Type
Research Article
Information
Clays and Clay Minerals , Volume 56 , Issue 2 , April 2008 , pp. 222 - 243
Copyright
Copyright © 2008, The Clay Minerals Society

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