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Changes in surface area and composition during grinding of silicon in environments of various quality

Published online by Cambridge University Press:  03 March 2011

Klára Tkáčová ,
Nadežda Števulová ,
Zdeněk Bastl ,
Pavel Stopka  and
Magdaléna Bálintová
Klára Tkáčová
Affiliation:
Institute of Geotechnics, Slovak Academy of Sciences, Košice, Slavakia
Nadežda Števulová
Affiliation:
Institute of Geotechnics, Slovak Academy of Sciences, Košice, Slavakia
Zdeněk Bastl
Affiliation:
J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Prague, Czech Republic
Pavel Stopka
Affiliation:
Institute of Inorganic Chemistry, Academy of Sciences of the Czech Republic, Prague, Czech Republic
Magdaléna Bálintová
Affiliation:
Institute of Geotechnics, Slovak Academy of Sciences, Košice, Slovakia
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Abstract

Changes in particle size, surface properties, and composition brought about by planetary grinding of silicon in air and various permittivity liquids were investigated. Using a variety of spectroscopic techniques (ESR, IRS, and XPS), a mechanically induced surface oxidation was proved. While at grinding in air and organic liquids a part of the centers originating from dangling orbitals on SiIII are preserved, the properties of water-ground silicon are fully governed by the oxide surface shell. The most effective particle size reduction and surface protection can be reached by grinding in nonpolar liquids.

Type
Articles
Information
Journal of Materials Research , Volume 10 , Issue 11 , November 1995 , pp. 2728 - 2735
Copyright
Copyright © Materials Research Society 1995

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