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Solution processing approaches for solid electrolytes and electrode materials

Published online by Cambridge University Press:  31 January 2011

Steven P. Simner ,
Pu-Wei Wu  and
Bruce Dunn
Steven P. Simner
Affiliation:
Department of Materials Science and Engineering, University of California–Los Angeles, Los Angeles, California 90095–1595
Pu-Wei Wu
Affiliation:
Department of Materials Science and Engineering, University of California–Los Angeles, Los Angeles, California 90095–1595
Bruce Dunn
Affiliation:
Department of Materials Science and Engineering, University of California–Los Angeles, Los Angeles, California 90095–1595
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Abstract

Solution processing methods have been used to prepare a solid electrolyte, copper-doped bismuth vanadate, and several different lithium transition metal oxide cathode materials. Dense thin films of the bismuth vanadate were prepared by pyrolysis of metal organic precursors deposited on various oxide substrates. A high degree of crystal orientation was obtained using single crystal MgO substrates. The Pechini process was used to prepare powders of the different materials and a variety of results were obtained. The bismuth vanadate exhibited a second phase of BiVO4 while LiNiO2 and the LiCoxNi1−xO2 solid solution require further efforts at obtaining the proper phase and stoichiometry. The LiCoO2 system formed readily and exhibited good electrochemical performance.

Type
Articles
Information
Journal of Materials Research , Volume 13 , Issue 4 , April 1998 , pp. 866 - 874
Copyright
Copyright © Materials Research Society 1998

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