Hostname: page-component-848d4c4894-ndmmz Total loading time: 0 Render date: 2024-05-23T11:53:44.764Z Has data issue: false hasContentIssue false
  • English
  • Français

Dislocation Associated Incubational Domain Formation in Lightly Gadolinium-Doped Ceria

Published online by Cambridge University Press:  19 November 2010

Zhi-Peng Li ,
Toshiyuki Mori ,
Fei Ye ,
Ding Rong Ou ,
Jin Zou  and
John Drennan
Zhi-Peng Li*
Affiliation:
Fuel Cell Materials Center, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan
Toshiyuki Mori
Affiliation:
Fuel Cell Materials Center, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan
Fei Ye
Affiliation:
Key Laboratory of Materials Modification, School of Materials Science and Engineering, Dalian University of Technology, 2 Linggong Road, Dalian 116024, P.R. China
Ding Rong Ou
Affiliation:
Laboratory of Fuel Cells, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, P.R. China
Jin Zou
Affiliation:
School of Engineering, The University of Queensland, St. Lucia, Brisbane, Queensland 4072, Australia Center for Microscopy and Microanalysis, The University of Queensland, St. Lucia, Brisbane, Queensland 4072, Australia
John Drennan
Affiliation:
Center for Microscopy and Microanalysis, The University of Queensland, St. Lucia, Brisbane, Queensland 4072, Australia
*
Corresponding author. E-mail: LI.Zhipeng@nims.go.jp
Get access

Abstract

Nanosized incubational domain was observed in 10 at.% gadolinium-doped ceria (GDC) using high-resolution transmission electron microscopy. Dislocations were extensively observed in 10 at.% GDC instead of heavily doped 25 at.% GDC. By Fast Fourier Transform and Inverse Fast Fourier Transform analysis, it was noticed that the incubational domain existing in 10 at.% GDC has different lattice spacing and orientation from the neighboring ceria matrix. Furthermore, dislocations were usually observed in the interface region between the incubational domain and the ceria matrix. Based on experimental results, the formation mechanism of dislocation associated incubational domain in lightly gadolinium-doped ceria is rationalized.

Keywords

dislocationdomaingadolinium-doped ceriamicrostructuresolid oxide fuel cellTEM
Type
TEM and STEM Materials Applications
Information
Microscopy and Microanalysis , Volume 17 , Issue 1 , February 2011 , pp. 49 - 53
Copyright
Copyright © Microscopy Society of America 2011

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Arai, H., Kunisaki, T., Shimizu, Y. & Seiyama, T. (1986). Electrical properties of calcia-doped ceria with oxygen ion conduction. Solid State Ionics 20, 241–248.CrossRefGoogle Scholar
Balazs, G.B. & Glass, R.S. (1995). Ac impedance studies of rare earth oxide doped ceria. Solid State Ionics 76, 155–162.CrossRefGoogle Scholar
Eguchi, K., Setoguchi, T., Inoue, T. & Arai, H. (1992). Electrical properties of ceria-based oxides oxides and their application to solid oxide fuel cells. Solid State Ionics 52, 165–172.CrossRefGoogle Scholar
Hartmanova, M., Lomonova, E.E., Navratil, V., Kundracik, F. & Kostic, I. (2004). The influence of ceria addition on the quality of grown yttria crystals, their crystalline and defect structures. Mater Sci Eng B 113, 1–6.CrossRefGoogle Scholar
Iguchi, F., Endo, Y., Ishida, T., Yokobori, T., Yugami, H., Otake, T., Kawada, T. & Mizusaki, J. (2005). Oxygen partial pressure dependence of creep on yttria-doped ceria ceramics. Solid State Ionics 176, 641–644.CrossRefGoogle Scholar
Inaba, H. & Tagawa, H. (1996). Ceria-based solid electrolytes. Solid State Ionics 83, 1–16.CrossRefGoogle Scholar
Kilner, J.A. & Brook, R.J. (1982). A study of oxygen ion conductivity in doped non-stoichiometric oxides. Solid State Ionics 6, 237–252.CrossRefGoogle Scholar
Kilner, J.A & Waters, C.D. (1982). The effects of dopant cation-oxygen vacancy complexes on the anion transport properties of non-stoichiometric fluorite oxides. Solid State Ionics 6, 253–259.CrossRefGoogle Scholar
Kudo, T. & Obayashi, H. (1976). Mixed electrical conduction in the fluorite-type Ce1–xGdxO2–x/2. J Electrochem Soc 123, 415–419.CrossRefGoogle Scholar
Li, P., Chen, I.W., Hahn, J.E. & Tien, T.Y. (1991). X-ray absorption studies of ceria with trivalent dopants. J Am Ceram Soc 74, 958–967.CrossRefGoogle Scholar
Li, J.G., Ikegami, T. & Mori, T. (2004). Low temperature processing of dense samarium-doped CeO2 ceramics: Sintering and grain growth behaviors. Acta Mater 52, 2221–2228.CrossRefGoogle Scholar
Mori, T., Drennan, J., Wang, Y., Lee, J.H., Li, J.G. & Ikegam, T. (2003). Electrolytic properties and nanostructural features in the La2O3-CeO2 system. J Electrochem Soc 150, A665–A673.CrossRefGoogle Scholar
Mori, T., Kobayashi, T., Wang, Y., Auchterlonie, G., Nishimura, T., Li, J.G. & Kobayashi, H. (2005). Synthesis and characterization of nano-hetero-structured Dy doped CeO2 solid electrolytes using a combination of spark plasma sintering and conventional sintering. J Am Ceram Soc 88, 1981–1984.CrossRefGoogle Scholar
Mori, T., Ou, D.R., Ye, F., Zou, J. & Drennan, J. (2007). Influence of microstructure in doped CeO2 solid electrolytes on conducting properties. Microsc Microanal 13(S2), 600–601 (CD-ROM).CrossRefGoogle Scholar
Mori, T., Wang, Y., Drennan, J., Auchterlonie, G., Li, J.G. & Ikegami, T. (2004). Influence of particle morphology on nanostructural feature and conduction property in Sm-doped CeO2 sintered body. Solid State Ionics 175, 641–649.CrossRefGoogle Scholar
Ou, D.R., Mori, T., Ye, F., Kobayashi, T., Zou, J., Auchterlonie, G. & Drennan, J. (2006a). Oxygen vacancy ordering in heavily rare-earth-doped ceria. Appl Phys Lett 89, 171911-1–171911-3.CrossRefGoogle Scholar
Ou, D.R., Mori, T., Ye, F., Takahashi, M., Zou, J. & Drennan, J. (2006b). Microstructures and electrolytic properties of yittrium-doped ceria electrolytes: Dopant concentration and grain size dependence. Acta Mater 54, 3737–3746.CrossRefGoogle Scholar
Ou, D.R., Mori, T., Ye, F., Zou, J., Auchterlonie, G. & Drennan, J. (2007). Microstructural inhomogeneity in Holminum-doped ceria and its influence on the ionic conduction. J Electrochem Soc 154, B616–B622.CrossRefGoogle Scholar
Ou, D.R., Mori, T., Ye, F., Zou, J., Auchterlonie, G. & Drennan, J. (2008). Oxygen vacancy ordering in lanthanide-doped ceria: Dopant-type dependence and structure model. Phys Rev B 77, 024108-1–024108-8.CrossRefGoogle Scholar
Peng, R., Xia, C., Liu, X., Peng, D. & Meng, G. (2002). Intermediate-temperature SOFCs with thin Ce0.8Y0.2O1.9 films prepared by screen-printing. Solid State Ionics 152, 561–565.CrossRefGoogle Scholar
Pienkowaski, M.C., Jenkins, M.L. & Moseley, P.T. (1991). Microdomains in urania-yttria and urania-ceria. J Sol State Chem 92, 543–564.CrossRefGoogle Scholar
Schneider, D., Martin, G. & Gauckler, L.J. (1997). Nonstoichiometry and defect chemistry of ceria solid solutions. J Electroceram 1, 165–172.Google Scholar
Seitz, F. (1950). Influence of plastic flow on the electrical and photographic properties of the alkali halide crystals. Phys Rev 80, 239–243.CrossRefGoogle Scholar
Selladurai, S., Muthukkumaran, K., Kuppusami, P., Divakar, R., Mohandas, E. & Raghunathan, V.S. (2007). Microstructural study of thin films of 5 mol% gadolinia-doped ceria prepared by plused laser ablation. Ionics 13, 87–92.CrossRefGoogle Scholar
Steele, B.C.H. (2000). Appraisal of Ce1−yGdyO2−y/2electrolytes for IT-SOFC operation at 500°C. Solid State Ionics 129, 95–110.CrossRefGoogle Scholar
Steele, B.C.H. & Heinezl, A. (2001). Materials for fuel-cell technologies. Nature 414, 345–352.CrossRefGoogle ScholarPubMed
Wang, D.Y., Park, D.S., Griffith, J. & Nowick, A.S. (1981). Oxygen-ion conductivity and defect interactions in yttria-doped ceria. Solid State Ionics 2, 95–105.CrossRefGoogle Scholar
Ye, F., Mori, T., Ou, D.R., Cormack, A.N., Raymond, J.L. & Drennan, J. (2008a). Simulation of ordering in large defect clusters in gadolinium-doped ceria. Solid State Ionics 179, 1962–1967.CrossRefGoogle Scholar
Ye, F., Mori, T., Ou, D.R., Takahashi, M., Zou, J. & Drennan, J. (2007a). Ionic conductivities and microstructure of ytterbium-doped ceria. J Electrochem Soc 154, B180–B185.CrossRefGoogle Scholar
Ye, F., Mori, T., Ou, D.R., Zou, J., Auchterlonie, G. & Drennan, J. (2007b). Compositional and valent state inhomogeneities and ordering of oxygen vacancies in terbium-doped ceria. J Appl Phys 101, 113528-1–113528-5.CrossRefGoogle Scholar
Ye, F., Mori, T., Ou, D.R., Zou, J., Auchterlonie, G. & Drennan, J. (2008b). Compositional and structural characteristics of nano-sized domains in gadolinium-doped ceria. Solid State Ionics 179, 827–831.CrossRefGoogle Scholar