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Thermal behaviour of filatovite – a rare aluminoarsenate mineral of the feldspar group

Published online by Cambridge University Press:  27 February 2024

Liudmila A. Gorelova Open the ORCID record for Liudmila A. Gorelova [Opens in a new window] ,
Oleg S. Vereshchagin Open the ORCID record for Oleg S. Vereshchagin [Opens in a new window] ,
Vladimir N. Bocharov ,
Nadezhda V. Potekhina (née Shchipalkina) Open the ORCID record for Nadezhda V. Potekhina (née Shchipalkina) [Opens in a new window] ,
Elena S. Zhitova Open the ORCID record for Elena S. Zhitova [Opens in a new window]  and
Igor V. Pekov
Liudmila A. Gorelova*
Affiliation:
Saint Petersburg State University, University Emb. 7/9, 199034 St. Petersburg, Russia
Oleg S. Vereshchagin
Affiliation:
Saint Petersburg State University, University Emb. 7/9, 199034 St. Petersburg, Russia
Vladimir N. Bocharov
Affiliation:
Saint Petersburg State University, University Emb. 7/9, 199034 St. Petersburg, Russia
Nadezhda V. Potekhina (née Shchipalkina)
Affiliation:
Faculty of Geology, Moscow State University, Vorobievy Gory, 119991 Moscow, Russia
Elena S. Zhitova
Affiliation:
Institute of Volcanology and Seismology FEB RAS, Boulevard Piip 9, 683006 Petropavlovsk-Kamchatsky, Russia
Igor V. Pekov
Affiliation:
Faculty of Geology, Moscow State University, Vorobievy Gory, 119991 Moscow, Russia
*
Corresponding author: Liudmila A. Gorelova; Email: l.gorelova@spbu.ru
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Abstract

The high-temperature behaviour of a feldspar-group mineral, filatovite (with the simplified formula: K(Al,Zn)2(As,Si)2O8), in which the Al:As:Si ratio is close to 2:1:1), was studied by in situ high-temperature single-crystal X-ray diffraction and in situ high-temperature (hot stage) Raman spectroscopy up to 600°C. In the temperature range studied (25–600°С) filatovite does not undergo any phase transition, whereas at 800°C it decomposes to X-ray amorphous phase(s). The evolution of 12 main Raman bands was traced during heating, which indicates a gradual change in the crystal structure. The thermal expansion coefficients of filatovite demonstrate a sharply anisotropic character of thermal expansion: the maximal expansion is close to the a axis (α11 = 17.7(1) × 10–6 °C–1), whereas along the b and c axes the thermal expansion coefficients are close to zero. Such behaviour is typical for minerals with a similar crystal structure topology; it indicates the dominant role of structure geometry in the thermal behaviour of the mineral.

Keywords

filatovitefeldsparthermal expansionX-ray diffractionRaman spectroscopy
Type
Article
Information
Mineralogical Magazine , Volume 88 , Issue 2 , April 2024 , pp. 176 - 184
Copyright
Copyright © The Author(s), 2024. Published by Cambridge University Press on behalf of The Mineralogical Society of the United Kingdom and Ireland

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Footnotes

Associate Editor: Oleg I Siidra

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