Hostname: page-component-848d4c4894-2pzkn Total loading time: 0 Render date: 2024-06-01T17:18:39.369Z Has data issue: false hasContentIssue false
  • English
  • Français

Synthesis and Characterization of Zinc Oxide Nanoparticles (ZnO NPs) in Powder and in Thin Film using Corn Husk Extract via Green Chemistry

Published online by Cambridge University Press:  03 February 2020

M. Bakayoko ,
A. Fall ,
I. Ngom ,
J. Sackey ,
B.D. Ngom ,
P.D. Tall  and
M. Maaza
M. Bakayoko*
Affiliation:
Nanosciences African Network (NANOAFNET), iThemba LABS-National Research Foundation, Old Faure road, 7129, Somerset West, South Africa UNESCO-UNISA Africa Chair in Nanosciences/Nanotechnology, College of Graduate Studies, University of South Africa (UNISA), Muckleneuk ridge, P.O. Box 392, Pretoria-South Africa Physics Department, University of Cheikh Anta Diop, Dakar, Senegal
A. Fall
Affiliation:
Nanosciences African Network (NANOAFNET), iThemba LABS-National Research Foundation, Old Faure road, 7129, Somerset West, South Africa UNESCO-UNISA Africa Chair in Nanosciences/Nanotechnology, College of Graduate Studies, University of South Africa (UNISA), Muckleneuk ridge, P.O. Box 392, Pretoria-South Africa Physics Department, University of Cheikh Anta Diop, Dakar, Senegal
I. Ngom
Affiliation:
Nanosciences African Network (NANOAFNET), iThemba LABS-National Research Foundation, Old Faure road, 7129, Somerset West, South Africa UNESCO-UNISA Africa Chair in Nanosciences/Nanotechnology, College of Graduate Studies, University of South Africa (UNISA), Muckleneuk ridge, P.O. Box 392, Pretoria-South Africa Physics Department, University of Cheikh Anta Diop, Dakar, Senegal
J. Sackey
Affiliation:
Nanosciences African Network (NANOAFNET), iThemba LABS-National Research Foundation, Old Faure road, 7129, Somerset West, South Africa UNESCO-UNISA Africa Chair in Nanosciences/Nanotechnology, College of Graduate Studies, University of South Africa (UNISA), Muckleneuk ridge, P.O. Box 392, Pretoria-South Africa
B.D. Ngom
Affiliation:
Nanosciences African Network (NANOAFNET), iThemba LABS-National Research Foundation, Old Faure road, 7129, Somerset West, South Africa UNESCO-UNISA Africa Chair in Nanosciences/Nanotechnology, College of Graduate Studies, University of South Africa (UNISA), Muckleneuk ridge, P.O. Box 392, Pretoria-South Africa Physics Department, University of Cheikh Anta Diop, Dakar, Senegal
P.D. Tall
Affiliation:
Physics Department, University of Cheikh Anta Diop, Dakar, Senegal
M. Maaza
Affiliation:
Nanosciences African Network (NANOAFNET), iThemba LABS-National Research Foundation, Old Faure road, 7129, Somerset West, South Africa UNESCO-UNISA Africa Chair in Nanosciences/Nanotechnology, College of Graduate Studies, University of South Africa (UNISA), Muckleneuk ridge, P.O. Box 392, Pretoria-South Africa
*
*(Email: mbakayoko@tlabs.ac.za)
Get access

Abstract:

In this study, zinc oxide nanoparticles (ZnO NPs) in powder and in thin film were successfully synthesized first time using an eco-friendly, simple and cost effective green synthesis method mediated by corn husk (Zea mays) extract as an effective chelating agent, and zinc nitrate hexahydrate as precursor. Diverse characterizations techniques such as High Resolution – Scanning Electron Microscopy (HR-SEM), Energy Dispersive X- rays Spectroscopy (EDS), X-Rays Diffraction (XRD), and UV – Vis – NIR spectroscopy as well as Photoluminescence (PL) were investigated to confirm ZnO NPs nature. For the ZnO NPs powder, highly crystalline ZnO nanoparticles (ZnO NPs) annealed at 500°C which are 48.635 nm in particles size were characterised by HR-SEM and XRD analysis. The structure morphology and the constituents of the resultant ZnO powder were investigated respectively by HR-SEM and EDS. UV – Visible spectroscopy analysis was investigated on the optical band gap of ZnO NPs, which was calculated to be 3.31 eV. This result indicates that ZnO NPs can be used in metal oxide semiconductor-based devices. For the ZnO NPs thin film, XRD patterns of hexagonal wurtzite structure with c/a ratio about of 1.60 and μ – parameter of 0.38 were obtained. PL measurements showed a broad emission band in the 380 – 800 nm range, centred at 481 nm. ZnO NPs thin film yielded relatively more intense photoluminescence spectra than the ZnO NPs powder. The intrinsic point defects and defect level transitions responsible for the broad emission are discussed.

Keywords

biological synthesis (chemical reaction)chemical synthesiscrystallographic structurenanoscaleoptical properties
Type
Articles
Information
MRS Advances , Volume 5 , Issue 21-22: African Materials Research Society 2019 , 2020 , pp. 1083 - 1093
Copyright
Copyright © Materials Research Society 2020

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

References:

Fuku, X., Diallo, A., and Maaza, M., “Nanoscaled Electrocatalytic Optically Modulated ZnO Nanoparticles through Green Process of Punica granatum L. and Their Antibacterial Activities”, International Journal of Electrochemistry, Vol. 2016, Article ID 4682967, 10 pages, (2016).CrossRefGoogle Scholar
Imani, R., Kononenko, V., Romih, T. et al., “Growth of a novel nanostructured ZnO urchin: control of cytotoxicity and dissolution of the ZnO urchin”, Nanoscale Research Letters, Vol. 10, Article ID 441, (2015).CrossRefGoogle ScholarPubMed
Matinise, N., Fuku, X. G., Kaviyarasu, K., Mayedwa, N., and Maaza, M., “ZnO nanoparticles via Moringa oleifera green synthesis: Physical properties & mechanism of formation”, Applied Surface Science 406 (2017) 339-347.CrossRefGoogle Scholar
Kadir, R. A., et al., “Effect of Substrates on Zinc Oxide Thin Films Fabrication using Sol-gel Method”, IOP Conf. Ser.: Sci. Eng. 340 (2018).CrossRefGoogle Scholar
Hong, R., and Xu, S., “ZnO:Al films prepared by reactive mid-frequency magnetron sputtering with rotating cathode”, J. Mater. Sci. Technol. 26 (10) (2010) 872–877.CrossRefGoogle Scholar
Wang, C., Hu, B., and Yi, H., “The study of structure and optoelectronic properties of ZnS and ZnO films on porous silicon substrates”, Optik 123 (2012) 1040–1043.CrossRefGoogle Scholar
Jagadish, C., and Pearton, S., “Zinc Oxide Bulk, Thin Films and Nanostructures”, Elsevier Limited, 2006, pp. 1–20.Google Scholar
Chaari, M., Matoussi, A., “Electrical conduction and dielectric studies of ZnO pellets”, Phys. B Condens. Matter 407 (2012) 3441–3447.CrossRefGoogle Scholar
Auret, F. D., Goodman, S. A., Hayes, M., Legodi, M. J., Van Laarhoven, H. A., and Look, D. C., “Electrical characterization of 1.8 MeV proton-bombarded ZnO”, Appl. Phys. Lett., Vol. 79, No. 19, pp. 3074-3076, (2001).CrossRefGoogle Scholar
Morfa, A. J., Kirkwood, N., Karg, M., Singh, T .B., and Mulvaney, P., “Effect of defects on the behavior of ZnO nanoparticle FETs”, J. Phys. Chem. C 115 (2011) 8312–8315.CrossRefGoogle Scholar
Jones, N., Ray, B., Ranjit, K. T., and Manna, A. C., “Antibacterial activity of ZnO nanoparticle suspensions on a broad spectrum of microorganisms”, FEMS Microbiol. Lett. 279 (2008) 7176.CrossRefGoogle ScholarPubMed
Salah, N., Habib, S. S., Khan, Z. H., Memic, A., Azam, A., Alarfaj, E., Zahed, N., and Al-Hamedi, S., “High-energy ball milling technique for ZnO nanoparticles as antibacterial materials”, Int. J. Nanomed. 6 (2011) 863–869.CrossRefGoogle Scholar
Nwanya, A. C., Razanamahandry, L. C., Bashir, A. K. H., Ikpo, C. O., Nwanya, S. C., Botha, S., and Maaza, M., “Industrial textile effluent treatment and antibacterial effectiveness of Zea mays L. Dry husk mediated bio-synthesized copper oxide nanoparticles’’, Journal of hazardous materials, 375 (2019) 281-289.CrossRefGoogle Scholar
Sackey, J., Nwanya, A. C., Bashir, A. K. H., Matinise, N., Ngilirabanga, J. B., Ameh, A. E., and Maaza, M., “Electrochemical properties of Euphorbia pulcherrima mediated copper oxide nanoparticles’’, Materials Chemistry and Physics, 122714 (2020).CrossRefGoogle Scholar
Nwanya, A. C., Ndipingwi, M. M., Ikpo, C. O., Ezema, F. I., Iwuoha, E. I., and Maaza, M., “Biomass mediated multi layered NaNixCo1− xO2 (x= 0.4) and α-Fe2O3 nanoparticles for aqueous sodium ion battery’’, Journal of Electroanalytical Chemistry, 113809 (2019).Google Scholar
Gurunathan, S., Kalishwaralal, K., Vaidyanathan, R., Venkataraman, D., Pandian, S. R. K., Muniyandi, J., et al. , “Biosynthesis, Purification and Characterization Of Silver Nanoparticles Using Escherichia Coli”, Colloids and Surfaces B 74(1), 328–335, (2009).CrossRefGoogle ScholarPubMed
Diallo, A., Ngom, B. D., Park, E., and Maaza, M., “Green synthesis of ZnO nanoparticles by Aspalathus linearis: Structural & optical properties”, Journal of Alloys and Compounds 646 (2015) 425 - 430.CrossRefGoogle Scholar
Thema, F. T., Manikandan, E., Dhlamini, M. S., and Maaza, M., “Green synthesis of ZnO nanoparticles via Agathosma betulina natural extract”, Materils Letters 161 (2015) 124 - 127.CrossRefGoogle Scholar
Nwanya, A. C., Ndipingwi, M. M., Mayedwaa, N., Razanamahandry, L. C., Ikpo, C. O., Waryo, T., and Iwuoha, E. I., “Maize (Zea mays L.) fresh husk mediated biosynthesis of copper oxides: Potentials for pseudo capacitive energy storage’’, Electrochimica Acta, 301 (2019) 436-448.CrossRefGoogle Scholar
Nwanya, A. C., Ndipingwi, M. M., Ikpo, C. O., Obodo, R. M., Nwanya, S. C., Botha, S., and Maaza, M., “Zea mays lea silk extract mediated synthesis of nickel oxide nanoparticles as positive electrode material for asymmetric supercabattery. Journal of Alloys and Compounds, 153581 (2019).Google Scholar
Brobbey, A. A., Somuah-Asante, S., Asare-Nkansah, S., Boateng, F. O., and Ayensu, I., “Preliminary phytochemical screening and scientific validation of the anti-diabetic effect of the dried husk of Zea mays L. (Corn, Poaceae)”, International Journal of Phytopharmacy, 7 (1) (2017) 01-05.Google Scholar
Mendes, C. A. C., Adnet, F. A. O., Leite, M. C. A. M., Furtado, C. R. C., and De Sousa, A. M. F., “Chemical, Physical, Mechanical, Thermal and Morphological characterization of Corn Husk”, Chemical Institute, Rio de Janeiro State University, (2014).Google Scholar
Li, C. Y., Kim, H. W., Won, S. R., Min, H. K., Park, K. J., Park, J. Y., Ahn, M. S., and Rhee, H. I., “Corn Husk as a Potential Source of Anthocyanins. Journal of Agricultural and Food Chemistry”, 56 (23) (2008) 11413-11416.CrossRefGoogle Scholar
Wang, X. S., Wu, Z. C., Webb, J. F., and Liu, Z. G., “Ferroelectric and dielectric properties of Li-doped ZnO thin films prepared by pulsed laser deposition”, Appl. Phys. A. 77 (2003) 561–565.CrossRefGoogle Scholar
Warren, B. E., “X-ray diffraction”, (1990), p. 253.Google Scholar
Elmas, S., and Korkmaz, S., “Deposition of Al doped ZnO thin films on the different substrates with radio frequency magnetron sputtering”, Journal of Non-Crystalline Solids, Vol. 359, 1 January 2013, Pages 69-72.CrossRefGoogle Scholar
Hu, Y., Diao, X., Wang, C., Hao, W., and Wang, T., “Effects of heat treatment on properties of ITO films prepared by rf magnetron sputtering “, Vacuum, 75(2), (2004) 183-188.CrossRefGoogle Scholar
Singh, A. K., “Synthesis, Characterization, Electrical and Sensing Properties of ZnO Nanoparticles”, Advanced Powder Technology, Vol. 21, No. 6, pp. 609–613, (2010).CrossRefGoogle Scholar
Sridevi, D., and Rajendran, K.V., “Synthesisand Optical Characteristics of ZnO Nanocrystals”, Bulletin of Materials Science, Vol. 32, No. 2, pp. 165–168, (2009).CrossRefGoogle Scholar
Sithole, J., Ngom, B. D., Khamlich, S., Manikanadan, E., Manyala, N., and Maaza, M., “Simonkolleite nano-platelets: synthesis and temperature effect on hydrogen gas sensing properties”, Applied surface science 258 (20), 7839-7843 (2012).CrossRefGoogle Scholar
Khamlich, S., Abdullaeva, Z., Kennedy, J. V., and Maaza, M, “High performance symmetric supercapacitor based on zinc hydroxychloride nanosheets and 3D graphene-nickel foam composite”, Applied Surface Science 405 (2017) 329-336.CrossRefGoogle Scholar
Kaviyarasu, K., Magdalane, C. M., Anand, K., Manikandan, E., and Maaza, M, “Synthesis and characterization studies of MgO: CuO nanocrystals by wet-chemical method Spectrochimica Acta Part A: Molecular and Biomolecular”, Spectroscopy 142 (2015) 405-409.CrossRefGoogle Scholar
Simo, A., Mwakikunga, B., Sone, B. T., Julies, B., Madjoe, R., and Maaza, M, “VO2 nanostructures based chemiresistors for low power energy consumption hydrogen sensing”, International Journal of Hydrogen Energy 39 (15), 8147-8157 (2014).CrossRefGoogle Scholar