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Double transition-metal MXenes: Atomistic design of two-dimensional carbides and nitrides

Published online by Cambridge University Press:  09 October 2020

Weichen Hong ,
Brian C. Wyatt ,
Srinivasa Kartik Nemani  and
Babak Anasori
Weichen Hong
Affiliation:
Department of Mechanical and Energy Engineering and Integrated Nanosystems Development Institute, Purdue School of Engineering and Technology, Indiana University–Purdue University Indianapolis, USA; hweichen@purdue.edu
Brian C. Wyatt
Affiliation:
Department of Mechanical and Energy Engineering and Integrated Nanosystems Development Institute, Purdue School of Engineering and Technology, Indiana University–Purdue University Indianapolis, USA; bcwyatt@iu.edu
Srinivasa Kartik Nemani
Affiliation:
Department of Mechanical and Energy Engineering and Integrated Nanosystems Development Institute, Purdue School of Engineering and Technology, Indiana University–Purdue University Indianapolis, USA; snemani@purdue.edu
Babak Anasori
Affiliation:
Department of Mechanical and Energy Engineering and Integrated Nanosystems Development Institute, Purdue School of Engineering and Technology, Indiana University–Purdue University Indianapolis, USA; banasori@iupui.edu
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Abstract

MXenes are a large family of two-dimensional (2D) transition-metal carbides, nitrides, and carbonitrides. The MXene family has expanded since their original discovery in 2011, and has grown larger with the discovery of ordered double transition-metal (DTM) MXenes. These DTM MXenes differ from their counterpart mono-transition-metal (mono-M) MXenes, where two transition metals can occupy the metal sites. Ordered DTM MXenes are comprised of transition metals in either an in-plane or out-of-plane ordered structure. Additionally, some DTM MXenes are in the form of random solid solutions, which are defined by two randomly distributed transition metals throughout the 2D structure. Their different structures and array of transition-metal pairs provide the ability to tune DTM MXenes for specific optical, magnetic, electrochemical, thermoelectric, catalytic, or mechanical behavior. This degree of control over their composition and structure is unique in the field of 2D materials and offers a new avenue for application-driven design of functional nanomaterials. In this article, we review the synthesis, structure, and properties of DTM MXenes and provide an outlook for future research in this field.

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Technical Feature
Information
MRS Bulletin , Volume 45 , Issue 10: Functional Materials and Devices by Self-Assembly , October 2020 , pp. 850 - 861
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Copyright
Copyright © The Author(s), 2020, published on behalf of Materials Research Society by Cambridge University Press

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