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Heteroepitaxy of GaAs, GaP and InP on Si By Omvpe and Their Application to thin Film Solar Cells

Published online by Cambridge University Press:  28 February 2011

Akio Yamamoto
Affiliation:
NTT Opto-electronics Laboratories, 3-1 Morinosato-Wakamiya, Atsugi, Kanagawa 243-01, Japan
Safumi Yamaguchi
Affiliation:
NTT Opto-electronics Laboratories, 3-1 Morinosato-Wakamiya, Atsugi, Kanagawa 243-01, Japan
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Abstract

Organometallic vapor phase epitaxial (OMVPE) growth of GaAs, GaP and InP on Si has been studied using the two-step growth method. Growth parameters for a heteroepitaxial film with a specular surface, a single-domain structure and high crystallinity are demonstrated and discussed. Residual strains in grown films are evaluated and analyzed by taking account of elastic lattice deformation due to lattice mismatch or thermally- induced strain accomodation by rearrangement of misfit dislocations. Thin film GaAs and InP solar cells are fabricated and their performances are discussed in relation to defect density in the films. For GaAs cells, an efficiency of 18 % (AM1.5, active area) is attained by reducing defect density to 2×106 >cm−2 . The defect density is ~. 5×107 cm−2 in the present InP films, and is needed to be less than 106 cm−2 to attain an efficiency of 18 %.

Type
Research Article
Copyright
Copyright © Materials Research Society 1988

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References

1 Ziel, J. P. van der, Dupuis, R. D., Logan, R. A., and Pinzone, C. J., Appl. Phys. Lett., 51, 89 (1987).CrossRefGoogle Scholar
2 Akiyama, M., Kawarada, Y., and Kaminishi, K., Jpn. J. Appl. Phys., 23, L843 (1984).Google Scholar
3 Yamamoto, A., Tohno, S., and Uemura, C., J. Electrochem. Soc., 128, 1095 (1981).Google Scholar
4 Henderson, R. C., Marcus, R. B., and Polite, W. J., J. Appl. Phys., 42, 1203 (1971).Google Scholar
5 Yamamoto, A., Uchida, N., and Yamaguchi, M., OPTOELECTRONICS Devices and Technologies, 1, 41 (1986).Google Scholar
6 Sugo, M., Uchida, N., Yamamoto, A., Nishioka, T., and Yamaguchi, M., to be submitted to J. Appl. Phys.Google Scholar
7 Nagai, H., J. Appl. Phys., 45, 3789 (1974).CrossRefGoogle Scholar
8 Tohno, S. and Katsui, A., Defect Recognition and Image Processing in III-V Compounds II, ed. Weber, E. R. (Elsevier Science Publishers B.V., Amsterdam, 1987) p. 87.Google Scholar
9 Nishioka, T., Itoh, Y., Yamamoto, A., and Yamaguchi, M., Appl. Phys. Lett., 51, 1928 (1987).Google Scholar
10 El-Masry, N. and Tarn, J. C. L., Appl. Phys. Lett., 51, 1608 (1987).Google Scholar
11 Al-Jassim, M. M., Nishioka, T., Itoh, Y., Yamamoto, A., and Yamaguchi, M., This symposium; Paper No. A8.14.Google Scholar
12 Yamaguchi, M., Yamamoto, A., and Itoh, Y., J. Appl. Phys., 59, 1751 (1986).Google Scholar
13 Yamaguchi, M., Yamamoto, A., Uchida, N., and Uemura, C., Solar Cells, 19, 85 (1986-1987).Google Scholar