Hostname: page-component-848d4c4894-mwx4w Total loading time: 0 Render date: 2024-06-15T21:47:02.161Z Has data issue: false hasContentIssue false

Using a Gas Ion Source for Radiocarbon AMS and GC-AMS

Published online by Cambridge University Press:  18 July 2016

Christopher Bronk Ramsey*
Affiliation:
Oxford Radiocarbon Accelerator Unit, University of Oxford, United Kingdom.
Peter Ditchfield
Affiliation:
Oxford Radiocarbon Accelerator Unit, University of Oxford, United Kingdom.
Martin Humm
Affiliation:
Oxford Radiocarbon Accelerator Unit, University of Oxford, United Kingdom.
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

This paper reports on the performance of a new method of sample injection using the High Voltage Engineering Europa (HVEE) SO-110 ion source jointly developed between HVEE and Oxford. In order to use this source, we have developed a new gas handling system which works on the direct injection of carbon dioxide mixed into a continuous flow of helium. Preliminary work has also been carried out on online gas chromatography-accelerator mass spectrometry (GC-AMS). In this application, a GC is directly coupled to the AMS system using a GC-IRMS combustion interface and Nafion drier. We show here results for the measurement of natural abundance in separated compounds with good peak separation and precisions of about 10%. This type of system should be ideal for source apportionment studies, biomedical, and other similar work where high precision is not required but where sample sizes are very low.

Type
Articles
Copyright
Copyright © 2004 by the Arizona Board of Regents on behalf of the University of Arizona 

References

Bronk Ramsey, C, Hedges, REM. 1994a. Carbon dioxide sputter source development at Oxford. Nuclear Instruments and Methods in Physics Research B 92:100–4.Google Scholar
Bronk Ramsey, C, Hedges, REM. 1994b. Gas handling systems for radiocarbon dating by AMS. Nuclear Instruments and Methods in Physics Research B 92: 105–10.Google Scholar
Bronk Ramsey, C, Hedges, REM. 1994c. Radiocarbon with gas chromatography. Radiocarbon 37(2):711–6.Google Scholar
Bronk Ramsey, C, Hedges, REM. 1997. Hybrid ion sources: radiocarbon measurements from microgram to milligram. Nuclear Instruments and Methods in Physics Research B 123:539–45.Google Scholar
Bronk Ramsey, C, Humm, MJ. 2000. On-line combustion of samples for AMS and ion source developments at ORAU. Nuclear Instruments and Methods in Physical Research B 172:242–6.Google Scholar
Bronk Ramsey, C, Higham, TFG, Leach, P. 2004. Towards high precision AMS: progress and limitations. Radiocarbon , these proceedings.CrossRefGoogle Scholar
Mous, DJW, Fokker, W, van den Broek, R, Koopmans, R, Bronk Ramsey, C, Hedges, REM. 1998. An ion source for the HVEE 14C isotope ratio mass spectrometer for biomedical applications. Radiocarbon 40(1):283–8.Google Scholar
Staddon, PL, Bronk Ramsey, C, Ostle, N, Ineson, P, Fitter, A. 2003. Rapid turnover of hyphae of mycorrhizal fungi determined by AMS microanalysis of 14C. Science 300:1138–40.Google Scholar
Uhl, T, Kretschmer, W, Luppold, W, Scharf, A. 2004. Direct coupling of an elemental analyser and a hybrid ion source for AMS measurements. Radiocarbon , these proceedings.CrossRefGoogle Scholar