Radiocarbon age anomalies, resulting from ingestion of old carbonate, were measured in shell carbonate of live-collected snails from arid and semi-arid areas of Israel and the West Bank. The age anomalies were found to be similar to those in land snails from other climatic regions and averaged ca 1600 yr in Trochoidea seetzeni, 2200 yr in Sphincterochila spp, 800 yr in Levantina sp, and 1700 yr in coastal dune species. The differences are associated with ecological differences among taxa. The uncertainties of the age anomalies average several hundred years within each group. This renders radiocarbon dates of late Holecene snails relatively imprecise, whereas it has almost no effect on the age uncertainties of relatively old samples (ie, those with large errors of measurement). Procedures for correction for fractionation are discussed.

When single species of foraminifera picked from marine sediments are 14C dated with Accelerator Mass Spectrometry (AMS), bioturbation puts limits on the minimal sample size to be used, as uncertainty is added to the result by statistics of the picking process. The model presented here simulates the additional statistical uncertainty introduced into the measurement by the coupling of bioturbation and small sample amounts. As there is no general solution for this problem, we present two simple cases only. The model can also be used to simulate more complicated situations occurring in sediments.

The following list consists of dates, obtained by liquid scintillation counting of benzene, for archaeologic samples mostly measured from June 1985 to June 1986.

This list contains the results of 14C determinations obtained at the laboratory in 1985. ∗δ13C values are estimated (Stuiver & Polach, 1977).

The dates presented in this list were determined between June 1974 and October 1983. They relate to projects in North America and in Algeria. Dates with numbers prior to SMU-500 have generally no correction for fractionation. Following this initial series of dates an increasing number of δ13C/12C measurements were made by an outside laboratory, especially if the submitter requested a fractionation correction or if the sample was of carbonate or bone.

Results presented below were obtained by the Radiocarbon Laboratory of Tbilisi State University from 1976 to 1983. Throughout that period dates were determined not only for archaeologic samples but also for samples of mineral waters, soil humus, and geologic origin. Georgian wines of 1909–1975 were also analyzed but the results obtained are not discussed in this paper as they were published elsewhere (Burchuladze et al, 1977, 1979, 1980, 1982).

The radiocarbon dating laboratory at Waikato was established in 1975, primarily as a research tool in the fields of geomorphology, volcanology, tephrostratigraphy, coastal studies, and paleolimnology, to cope with the increasing supply of late Quaternary lake sediment, wood, peat, and shell samples submitted by University staff and postgraduate students undertaking research in the North Island of New Zealand. The method employed is scintillation counting of benzene using the procedures and vacuum systems designed by H A Polach for the Australian National University (ANU) Radiocarbon Dating Research Laboratory (Hogg, 1982). This date list reports on samples submitted by University of Waikato researchers and assayed in the Waikato laboratory mainly between 1979 and 1985. Other dates on material submitted by individuals working in other organizations in New Zealand, and overseas, are to be reported later.

Graphite in various forms has become the standard target for accelerator 14C dating. Graphite has been made by catalytic graphitization of charcoals (Lowe, 1984). Thin films of graphite have also been produced by thermal cracking (Beukens & Lee, 1981), electric discharge (Andrée et al, 1984; Wand, Gillespie & Hedges, 1984). Vogel et al (1984) pointed out the ease of graphite formation on iron from CO2 and H2 mixtures at ca 600°C. The deposition reactions of carbon from the CO, H2, and CO2 equilibria are well known (Wagman et al, 1945) and well studied. Formation of graphite from CO2 was discussed extensively by Boudouard (1902) and Schenck and Zimmerman (1903), and was known to chemists in France in 1851. We have used a related method, where graphite forms away from the iron, by using a higher temperature, and reduction of CO2 to CO over Zn in the presence of H2 (Jull et al, 1986) as an alternative to the use of Fe alone. The object of this paper is to point out an even simpler graphite preparation system, which eliminates hydrogen. The decomposition reaction of CO (Boudouard, 1902) takes place according to reaction (1).