Hostname: page-component-848d4c4894-5nwft Total loading time: 0 Render date: 2024-06-09T10:13:05.147Z Has data issue: false hasContentIssue false
  • English
  • Français

Acidity control of the gliding arc treatments of aqueous solutions: application to pollutant abatement and biodecontamination

Published online by Cambridge University Press:  21 December 2004

D. Moussa ,
F. Abdelmalek ,
B. Benstaali ,
A. Addou ,
E. Hnatiuc  and
J.-L. Brisset
D. Moussa
Affiliation:
Laboratoire d'Électrochimie (L.E.I.C.A.), UFR des Sciences de l'Université de Rouen, 76821 Mont Saint-Aignan, France
F. Abdelmalek
Affiliation:
Laboratoire d'Électrochimie (L.E.I.C.A.), UFR des Sciences de l'Université de Rouen, 76821 Mont Saint-Aignan, France Laboratoire des Sciences et Techniques de l'Environnement et de la Valorisation (S.T.E.V.A.), Faculté des Sciences de l'Ingénieur, BP 188, Mostaganem, Algeria
B. Benstaali
Affiliation:
Laboratoire d'Électrochimie (L.E.I.C.A.), UFR des Sciences de l'Université de Rouen, 76821 Mont Saint-Aignan, France Laboratoire des Sciences et Techniques de l'Environnement et de la Valorisation (S.T.E.V.A.), Faculté des Sciences de l'Ingénieur, BP 188, Mostaganem, Algeria
A. Addou
Affiliation:
Laboratoire des Sciences et Techniques de l'Environnement et de la Valorisation (S.T.E.V.A.), Faculté des Sciences de l'Ingénieur, BP 188, Mostaganem, Algeria
E. Hnatiuc
Affiliation:
Laboratoire d'Électrochimie (L.E.I.C.A.), UFR des Sciences de l'Université de Rouen, 76821 Mont Saint-Aignan, France George Asashi Technical University, 51–53 Boulevardu Mangeron, 66000 Iasi, Romania
J.-L. Brisset*
Affiliation:
Laboratoire d'Électrochimie (L.E.I.C.A.), UFR des Sciences de l'Université de Rouen, 76821 Mont Saint-Aignan, France
*
Jean-Louis.Brisset@univ-rouen.fr
Get access

Abstract

A tight control of acidity is needed for performing oxidation–reduction reactions of organic compounds dissolved in liquid media, since the relevant reactions often involve the occurrence of protons; the matching kinetics are therefore acidity dependent. This feature holds for plasma treatments of aqueous wastes which are intended to abate the concentration in organic pollutants. Exposure of aqueous solutions to a gliding arc plasma in humid air induces acid and oxidising reactions in the condensed phase. Acid effect results from the occurrence of NO species formed in the plasma and leads to the formation in water of nitrous and nitric acids, which are responsible for a steep pH fall. Using selected buffers allows accurate controlling of the acidity, which is necessary for most of the plasma-chemical or plasma-biochemical reactions.

Keywords

Type
Research Article
Information
The European Physical Journal - Applied Physics , Volume 29 , Issue 2 , February 2005 , pp. 189 - 199
Copyright
© EDP Sciences, 2005

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Jacq, J., Electrochim. Acta 12, 1 (1967) CrossRef
H. Lund, M.M. Baizer, in Organic Electrochemistry (M. Dekker, New-York, 1991), Chap. 2
H. Lesueur, A. Czernichowski, J. Chapelle, Fr. Pat. 2 639 172 (1988)
G. Fillon, A. Czernichowski, H. Lesueur, Fr. Pat. 90-11278 (1990)
P. Jorgensen, J. Chapelle, A. Czernichowski, K. Meguernes, Fr. Pat. 2 620 436 (1987)
B. Benstaali, B.G. Chéron, A. Addou, J.L. Brisset, Proc. ISPC-14 (Praga, Czech Rep., 1999), edited by H. Hrabovski, M. Konrad, V. Kopecki, pp. 939–944
Benstaali, B., Boubert, P., Chéron, B.G., Addou, A., Brisset, J.L., Plasma Chem. Plasma Process. 22, 553 (2002) CrossRef
Velikonja, J., Bergougnou, M.A., Castle, G.S.P., Cairns, W.L., Inculet, I.I., Ozone Sci. Eng. 23, 467 (2001) CrossRef
Peyrous, R., Ozone Sci. Eng. 12, 41 (1990) CrossRef
Peyrous, R., Lapeyre, R.M., Atmos. Environ. 16, 959 (1982) CrossRef
W.L. Morgan, M. Jacob, E.R. Fisher, Proc. ISPC-12 (Minneapolis, USA, 1995), pp. 741–476
E.M.F Van Veldhuizen, Electric Discharges for Environmental Purposes: Fundamentals and Applications (Nova Science Pub., New York, 2000)
J.P. Hoare, in Standard Potentials in Aqueous Solution, edited by A.J. Bard, R. Parsons, J. Jordan (M. Dekker, New-York, 1985), Chap. 4, p. 59
Fabyan, C., Monatsh. Chem. 106, 513 (1975), quoted in [13]
J.L. Brisset, A. Doubla, J. Amouroux, Proc. ISPC-8 (Tokyo, Japan, 1987), pp. 1793–1798
Brisset, J.L., Doubla, A., Amouroux, J., Rev. Int. Hautes Temp. Réfract. Fr. 26, 199 (1990)
Brisset, J.L., Lelièvre, J., Doubla, A., Amouroux, J., Analusis 18, 185 (1990)
F. Abdelmalek, A. Addou, J.L. Brisset, to be published (2005)
Herron, J.T., Green, D.S., Plasma Chem. Plasma Proc. 21, 459 (2003) CrossRef
Roth, J.A., Sullivan, D.E., Ozone Sci. Eng. 5, 37 (1983) CrossRef
N.V. Alexeev, A.V. Samokhin, E.V. Troiskaya, A.N. Belivtsev, V.T. Zhavoronkova, Proc ISPC-16 (Taormina, Italy, 2003), p. 761
Moussa, D., Brisset, J.L., J. Hazard. Mat. B 102, 189 (2003) CrossRef
D. Moussa, J.L. Brisset, S. Barguès, Fr. Pat. 98-13439 (1998)
E. Hnatiuc, in Procédés électriques de mesure et de traitement des polluants, edited by E. Hnatiuc coord. (Tec&Doc, Paris, 2002), Chap. 10
F. Moras, J.L. Brisset, Proc. 4 ${th}$ Int Congress GRUTTEE (Limoges, France, 2001), pp. 231–234
A. Doubla, E. Tsagou-Sobze, D. Moussa, R. Burlica, E. Hnatiuc, J.L. Brisset, Rev. Sci. Eau (submitted)
Fanmoe, J., Kamgang, J.-O., Moussa, D., Brisset, J.-L., Phys. Chem. News 14, 1 (2003)
Goldman, M., Sigmond, R.S., J. Electrochem. Soc. 132, 2842 (1985) CrossRef
N. Bellakhal, J.L. Brisset, Proc. 7 ${th}$ Int. Symp. High Pressure Low Temp. Plasma Chem. “Hakone VII” (Greifswald, Ge, 2000), edited by H.E. Wagner, J.F Benke, Vol. 2, pp. 460–464
Benstaali, B., LeBreton, J.M., Addou, A., Chéron, B.G., Brisset, J.L., Phys. Chem. News 5, 87 (2002)
Y. Rutter, Rapport de DESS, Université de Bretagne Sud, 2002
M. Yamamoto, N.Nishioka, M. Sadakata, Proc. ISPC-15 (Orléans, France, 2001), edited by A. Bouchoule, J.M. Pouvesle, A.L. Thomann, J.M. Bauchire, E. Robert, Vol. 2, pp. 743–748
V.Yu. Bazhenov, A.I. Kuzmichev, V.I. Kryzhanovski, I.L. Milno, A.V. Ryabtsev, I.A. Soloshenko, V.A. Khomish, V.V. Tsiolko, A.I. Schredin, Proc. ISPC-15 (Orléans, France, 2001), edited by A. Bouchoule, J.M. Pouvesle, A.L. Thomann, J.M. Bauchire, E. Robert, Vol. 7, pp. 3005–3010
M. Laroussi, J.P. Richardson, F.C. Dobbs, Proc. ISPC-15 (Orléans, France, 2001), edited by A. Bouchoule, J.M. Pouvesle, A.L. Thomann, J.M. Bauchire, E. Robert, Vol. 2, pp. 729–734
A. Soloshenko, V.V. Tsiolko, V.A. Khomich, V. Yu. Bazhenov, A.V. Ryabtsev, A.I. Shchedrin, I.L. Mikhno, Proc. ISPC-15 (Orléans, France, 2001), edited by A. Bouchoule, J.M. Pouvesle, A.L. Thomann, J.M. Bauchire, E. Robert, Vol. 2, pp. 735–742
Moisan, M., Barbeau, J., Moreau, S., Pelletier, J., Tabrizian, M., L'H. Yahia, Int. J. Pharm. 221, 1 (2001) CrossRef
H. Vitrac, J. Guespin, J.L. Brisset, Proc. 7 ${th}$ Int. Symp. High Pressure Low Temp. Plasma Chem. “Hakone VII” (Greifswald, Ge, 2000), edited by H.E. Wagner, J.F. Benke, Vol. 2, pp. 393–397
M. Moreau, J.M.G. Feuilloley, N. Orange, J.-L. Brisset, J. Appl. Microbiol. (in press)
J.O. Kamgang, R. Briandet, Y. Rutter, J.M. Herry, M.N. Bellon-Fontaine, J.L. Brisset, Proc. Congrès de la S. Fr. Biochim. (Bordeaux, Fr., 2004)