2 results
The interaction of a particle and a polymer brush coating a permeable surface
- Avshalom Offner, Guy Z. Ramon
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- Journal:
- Journal of Fluid Mechanics / Volume 913 / 25 April 2021
- Published online by Cambridge University Press:
- 05 March 2021, R3
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Coating of filtration membranes with a polymer brush holds great promise for efficiently preventing the deposition of fouling particles. The polymer chains are compressed by incoming particles, carried with the permeation flow towards the membrane, and consequently exert a repulsive force that acts to keep the particles away from the membrane surface. Here, we theoretically investigate the effect of a polymer brush coating on the permeation-induced hydrodynamic force, $F_{h}$, pulling a particle towards the membrane, and its balance with the steric repulsion exerted by the compressing brush, resisting the particle's approach. Lubrication theory yields an ordinary differential equation for the pressure, from which $F_{h}$ is calculated numerically. Further, an asymptotic analysis is performed for the limiting cases of a dilute or dense brush, providing analytic expressions that demonstrate how brush properties affect $F_{h}$. Finally, the equilibrium position of a particle is evaluated by considering a balance between the opposing forces. The results provide an upper boundary for the brush properties, beyond which the brush is barely compressed under conditions typical of membrane filtration processes. Further increasing the brush density or thickness only decreases the total system permeance, resulting in increased energy consumption. The results shed light on the mechanisms by which a polymer brush affects the forces acting on a foulant particle, providing quantitative measures for assessing the potential efficacy of brush coatings.
Acoustic oscillations driven by boundary mass exchange
- Avshalom Offner, Rui Yang, Daniel Felman, Nimrod Elkayam, Yehuda Agnon, Guy Z. Ramon
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- Journal:
- Journal of Fluid Mechanics / Volume 866 / 10 May 2019
- Published online by Cambridge University Press:
- 05 March 2019, pp. 316-349
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Thermoacoustic instability – self-sustained pressure oscillations triggered by temperature gradients – has become an increasingly studied topic in the context of energy conversion. Generally, the process relies on conductive heat transfer between a solid and the fluid in which the generated pressure oscillations are sustained. In the present study, the thermoacoustic theory is extended to include mass transfer; specifically, the working fluid is modified so as to incorporate a ‘reactive’ gas, able to exchange phase with a solid/liquid boundary through a sorption process (or through evaporation/condensation), such that most heat is transferred in the form of latent heat rather than through conduction. A set of differential equations is derived, accounting for phase-exchange heat and mass transfer, and de-coupled via a small-amplitude asymptotic expansion. These equations are solved and subsequently manipulated into the form of a wave equation, representing the small perturbation on the pressure field, and used to derive expressions for the time-averaged, second-order heat and mass fluxes. A stability analysis is performed on the wave equation, from which the marginal stability curve is calculated in terms of the temperature difference, $\unicode[STIX]{x0394}T_{onset}$, required for initiation of self-sustained oscillations. Calculated stability curves are compared with published experimental results, showing good agreement. Effects of gas mixture composition are studied, indicating that a lower heat capacity of the inert component, combined with a low boiling temperature and high latent heat of the reactive component substantially lower $\unicode[STIX]{x0394}T_{onset}$. Furthermore, an increase in the average mole fraction of the reactive gas, $C_{m}$ strongly affects onset conditions, leading to $\unicode[STIX]{x0394}T_{onset}\sim 5\,^{\circ }\text{C}$ at the highest value of $C_{m}$ achievable under atmospheric pressure. An analysis of the system limit cycle is performed for a wide range of parameters, indicating a systematic decrease in the temperature difference capable of sustaining the limit cycle, as well as a significant distortion of the acoustic wave form as the phase-exchange mechanism becomes dominant. These findings, combined, reveal the underlying mechanisms by which a phase-exchange engine may produce more acoustic power than its counterpart ‘classical’ thermoacoustic system, while its temperature difference is substantially lower.