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6 - Composition and reactions of wood

Published online by Cambridge University Press:  05 February 2013

Harold Schobert
Affiliation:
Pennsylvania State University
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Summary

Inspecting a collection of various kinds of wood would show considerable variability in physical properties such as color, density, and hardness. Densities range over an order of magnitude, from 110 kg/m3 for balsa to 1330 kg/m3 for lignum vitae. Colors vary from the nearly white of some varieties of maple to ebony wood, which lends its name as a synonym for black. A measure of hardness, the Janka test [A], shows again the extremes between lignum vitae, with a hardness of 20 000 N, and balsa, at 440 N. Some woods display almost no obvious grain structure, while others have structures so remarkable that they are prized for applications such as making fine furniture. Yet, despite the great range of diversity among woods, all varieties, regardless of botanical or geographical origin, also have many properties in common.

All woods have a cellular structure in which the cell walls are composed of a matrix of biopolymers, discussed later in this chapter. Wood is anisotropic, displaying different physical properties along the three major axes. Anisotropy results from the structure of cellulose in the cell walls, along with the shapes of wood cells and their orientation vis-à-vis the trunk. Wood gains and loses moisture (i.e. it is hygroscopic) as a result of changes in humidity and temperature. Because of the anisotropy, gain or loss of moisture results in unequal swelling or shrinkage along the three axes. Fungi, bacteria, and insects such as termites attack wood. The fact that wood is, as a result, biodegradable has both good and bad points. Obviously it is undesirable when, for example, a wooden structure rots. But, this behavior can also be turned to good use in chemical processing, when fungi or bacteria can be used deliberately to degrade the biopolymers in wood to produce useful chemical or fuel products.

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Publisher: Cambridge University Press
Print publication year: 2013

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References

Goodwin, T.W. and Mercer, E.I.Introduction to Plant Biochemistry. Pergamon: Oxford, 1983; page 69.Google Scholar
Smil, Vaclav. Energy in Nature and Society. MIT Press: Cambridge, 2008; page 191.Google Scholar
Modified from Tillman, David A.Wood as an Energy Resource. Academic Press: New York, 1978; page 68.Google Scholar
Breitmaier, Eberhard. Terpenes. Wiley-VCH: Weinheim, 2006. A short monograph on these compounds, recommended for those seeking more detailed information on this extensive family of plant components.CrossRefGoogle Scholar
Goodwin, T.W. and Mercer, E.I.Introduction to Plant Biochemistry. Pergamon Press: Oxford, 1983. This excellent book has a wealth of additional information on the composition, biosynthesis, and reactions of the many types of compound discussed in this chapter.Google Scholar
Higman, Christopher and van der Burgt, Maarten. Gasification. Elsevier: Amsterdam, 2008. Chapter 5 of this fine book discusses aspects of biomass gasification.CrossRefGoogle Scholar
Mauseth, James D.Botany. Jones and Bartlett: Sudbury, MA, 1998. Chapter 8 has a useful discussion, supplemented by numerous excellent illustrations, on the structure of wood from a botanical perspective.Google Scholar
Ryan, John Fuller. Wartime Woodburners. Schiffer Military History: Atglen, PA, 2009. The well-known adage that “necessity is the mother of invention” is amply illustrated in this book, which discusses the use of gas produced from wood as a motor vehicle fuel – in effect, how to convert a vehicle (including motorcycles) into a rolling wood gasifier.Google Scholar
Tillman, David A.Wood as an Energy Resource. Academic Press: New York, 1978. Though some sections, on current uses and forecasts, are now out of date, this book remains a very useful review of the applications of wood as fuel.Google Scholar
Young, Raymond A.Wood and wood products. In: Riegel's Handbook of Industrial Chemistry. (Kent, James A., ed.) Van Nostrand Reinhold: New York, 1992; Chapter 7. A comprehensive review of the reactions and processes of wood in the chemical industries, with much useful information on processes – such as pulp and paper manufacturing – not covered in this book.Google Scholar

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