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Effect of mechanical activation on catalytic properties of Fe2O3-pillared bentonite for Fenton-like reaction

Published online by Cambridge University Press:  27 February 2018

G.T. Wei ,
Y.S. Li ,
L.Y. Zhang ,
Z.M. Li ,
Y. Deng ,
L.H. Shao  and
J .H. Mo
G.T. Wei
Affiliation:
School of Chemistry and Chemical Engineering, Guangxi University, Nanning, China, Ministry-Province Jointly-Constructed Cultivation Base for State Key Laboratory of Processing for Non-ferrous Metal and Featured Materials, Guangxi Zhuang Autonomous Region, Nanning, China
Y.S. Li
Affiliation:
School of Chemistry and Chemical Engineering, Guangxi University, Nanning, China, Ministry-Province Jointly-Constructed Cultivation Base for State Key Laboratory of Processing for Non-ferrous Metal and Featured Materials, Guangxi Zhuang Autonomous Region, Nanning, China
L.Y. Zhang*
Affiliation:
School of Chemistry and Chemical Engineering, Guangxi University, Nanning, China, Ministry-Province Jointly-Constructed Cultivation Base for State Key Laboratory of Processing for Non-ferrous Metal and Featured Materials, Guangxi Zhuang Autonomous Region, Nanning, China
Z.M. Li
Affiliation:
School of Chemistry and Chemical Engineering, Guangxi University, Nanning, China, Ministry-Province Jointly-Constructed Cultivation Base for State Key Laboratory of Processing for Non-ferrous Metal and Featured Materials, Guangxi Zhuang Autonomous Region, Nanning, China
Y. Deng
Affiliation:
School of Chemistry and Chemical Engineering, Guangxi University, Nanning, China, Ministry-Province Jointly-Constructed Cultivation Base for State Key Laboratory of Processing for Non-ferrous Metal and Featured Materials, Guangxi Zhuang Autonomous Region, Nanning, China
L.H. Shao
Affiliation:
School of Chemistry and Chemical Engineering, Guangxi University, Nanning, China, Ministry-Province Jointly-Constructed Cultivation Base for State Key Laboratory of Processing for Non-ferrous Metal and Featured Materials, Guangxi Zhuang Autonomous Region, Nanning, China
J .H. Mo
Affiliation:
School of Chemistry and Chemical Engineering, Guangxi University, Nanning, China, Ministry-Province Jointly-Constructed Cultivation Base for State Key Laboratory of Processing for Non-ferrous Metal and Featured Materials, Guangxi Zhuang Autonomous Region, Nanning, China
*
*E-mail: yezi@gxu.edu.cn
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Abstract

A layered composite of Fe2O3-pillared bentonite (Fe-P-Bet), used as a catalyst in a Fenton-like process, was prepared and then its mechanical activation was studied in detail. The optimum conditions for preparation of Fe-P-Bet and the effects of mechanical activation on the catalytic activity of Fe-P-Bet were investigated systematically. The impact of the mechanical activation on the catalytic activity was affected by the filling ratio of the grinding medium, by the combination of different sized milling balls, by the rotation speed of the planet carrier, by the milling time and by the powder-to-ball ratio. Compared with the removal ratio of orange II of 14.5%, catalysed by Fe-P-Bet, the removal ratio catalysed by activated Fe2O3-pillared bentonite (A-Fe-P-Bet) was as high as 93.6%, and A-Fe-P-Bet had the merit of good stability and only a small amount of Fe leaching during the Fenton-like process. The catalysts prepared were characterized by scanning electron microscopy, transmission electron microscopy, X-ray diffraction and by the BET method; A-Fe-P-Bet has a small particle size and a rough surface. The lattice distortion and decrease in the crystal size of α-Fe2O3, as well as damage to the layer structure of smectite in the bentonite, were the main reasons for the increase in the catalytic activity of A-Fe-P-Bet. The results indicated that mechanical activation was an easy and effective method for improving the catalytic activity of this bentonite-based layered composite and that A-Fe-P-Bet was a safe, ‘green’, catalyst material for use in Fenton-like oxidation during treatment of wastewater.

Keywords

mechanical activationbentoniteα-Fe2O3Fenton-likepowdercatalytic material
Type
Research Article
Information
Clay Minerals , Volume 52 , Issue 4 , December 2017 , pp. 439 - 451
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2017

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