Skip to main content
×
Home
    • Aa
    • Aa

Dielectric properties and energy storage capability of antiferroelectric Pb0.92La0.08Zr0.95Ti0.05O3 film-on-foil capacitors

  • Beihai Ma (a1), Do-Kyun Kwon (a1), Manoj Narayanan and U. (Balu) Balachandran (a1)
Abstract

Antiferroelectric (AFE) Pb0.92La0.08Zr0.95Ti0.05O3 (PLZT) films were grown on nickel foils with lanthanum nickel oxide buffer by chemical solution deposition. We observed field-induced AFE-to-ferroelectric (FE) phase transition. The electric field for the AFE-to-FE phase transition (EAF ≈ 270 kV/cm) and that for the reverse phase transition (EFA ≈ 230 kV/cm) were measured at room temperature on samples with PLZT films of ≈1-µm thickness. Relative permittivity of ≈560 and dielectric loss of <0.05 were measured near zero DC bias field. Hysteresis loop analysis showed that energy densities of ≈53 and 37 J/cm3 can be stored and recovered from the film-on-foil capacitors at 25 and 150 °C, respectively. Highly accelerated life tests were conducted. The projected mean time to failure is >5000 h when the capacitors are operated at room temperature with an applied field of ≈300 kV/cm.

Copyright
Corresponding author
a) Address all correspondence to this author. e-mail: bma@anl.gov
Linked references
Hide All

This list contains references from the content that can be linked to their source. For a full set of references and notes please see the PDF or HTML where available.

1 W. Pan , Q. Zhang , A. Bhalla and L.E. Cross : Field-forced anti-ferroelectric-to-ferroelectric switching in modified lead zirconate titanate stannate ceramics. J. Am. Ceram. Soc. 72, 571 (1989).

2 K. Yamakawa , S. Trolier-Mckinstry , J.P. Dougherty and S.B. Krupanidhi : Reactive magnetron co-sputtered antiferroelectric lead zirconate thin films. Appl. Phys. Lett. 67, 2014 (1995).

3 I.W. Kim , D.S. Lee , S.H. Kang and C.W. Ahn : Antiferroelectric characteristics and low frequency dielectric dispersion of Pb1.075 La0.025(Zr0.95Ti0.05)O3 thin films. Thin Solid Films 441, 115 (2003).

5 A. Pelaiz-Barranco , J.D.S. Guerra , O. Garcia-Zaldivar , F. CalderonPinar , E.B. Araujo , D.A. Hall , M.E. Mendoza and J.A. Eiras : Effects of lanthanum modification on dielectric properties of Pb(Zr0.90,Ti0.10)O3 ceramics: Enhanced antiferroelectric stability. J. Mater. Sci. 43, 6087 (2008).

6 B. Ma , D.K. Kwon , M. Narayanan and U. Balachandran : Leakage current characteristics and dielectric breakdown of antiferro-electric Pb0.92La0.08Zr0.95Ti0.05O3 film capacitors grown on metal foils. J. Phys. D: Appl. Phys. 41, 205003 (2008).

7 V.M. Ishchuk , V.N. Baumer and V.L. Sobolev : The influence of the coexistence of ferroelectric and antiferroelectric states on the lead lanthanum zirconate titanate crystal structure. J. Phys. Con-dens. Matter 17, L177 (2005).

8 B. Ma , D.K. Kwon , M. Narayanan and U. Balachandran : Fabrication of antiferroelectric PLZT films on metal foils. Mater. Res. Bull. 44, 11 (2009).

9 L.B. Kong and J. Ma : Preparation and characterization of antiferroelectric PLZT2/95/5 thin films via a sol–gel process. Mater. Lett. 56, 30 (2002).

10 R. Seveno , H.W. Gundel and S. Seifert : Preparation of antiferro-electric PbZrxTi1-xO3 thin films on LaSrMnO3-coated steel substrates. Appl. Phys. Lett. 79, 4204 (2001).

11 Q. Zou , H.E. Ruda and B.G. Yacobi : Improved dielectric properties of lead zirconate titanate thin films deposited on metal foils with LaNiO3 buffer layers. Appl. Phys. Lett. 78, 1282 (2001).

12 B. Ma , M. Narayanan and U. Balachandran : Dielectric strength and reliability of ferroelectric PLZT films deposited on nickel substrates. Mater. Lett. 63, 1353 (2009).

Recommend this journal

Email your librarian or administrator to recommend adding this journal to your organisation's collection.

Journal of Materials Research
  • ISSN: 0884-2914
  • EISSN: 2044-5326
  • URL: /core/journals/journal-of-materials-research
Please enter your name
Please enter a valid email address
Who would you like to send this to? *
×

Keywords:

Metrics

Full text views

Total number of HTML views: 0
Total number of PDF views: 48 *
Loading metrics...

Abstract views

Total abstract views: 133 *
Loading metrics...

* Views captured on Cambridge Core between September 2016 - 27th June 2017. This data will be updated every 24 hours.