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Fe-based bulk metallic glasses with diameter thickness larger than one centimeter

  • V. Ponnambalam (a1), S. Joseph Poon (a1) and Gary J. Shiflet (a2)
  • DOI: http://dx.doi.org/10.1557/JMR.2004.0176
  • Published online: 01 March 2011
Abstract

Fe–Cr–Mo–(Y,Ln)–C–B bulk metallic glasses (Ln are lanthanides) with maximum diameter thicknesses reaching 12 mm have been obtained by casting. The high glass formability is attained despite a low reduced glass transition temperature of 0.58. The inclusion of Y/Ln is motivated by the idea that elements with large atomic sizes can destabilize the competing crystalline phase, enabling the amorphous phase to be formed. It is found that the role of Y/Ln as a fluxing agent is relatively small in terms of glass formability enhancement. The obtained bulk metallic glasses are non-ferromagnetic and exhibit high elastic moduli of approximately 180–200 GPa and microhardness of approximately 13 GPa.

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a)Address all correspondence to this author. e-mail: sjp9x@virginia.edu
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2V. Ponnambalam , S.J. Poon , G.J. Shiflet , V.M. Keppens , R. Taylor , and G. Petculescu , Appl. Phys. Lett. 83,1131 (2003).

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Journal of Materials Research
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