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Preparation of indole surface molecularly imprinted polymer by atom transfer radical emulsion polymerization and its adsorption performance

  • Yang Wenming (a1), Cao Yang (a2), Xu Xiaoling (a2), Zhou Zhiping (a3), Liu Lukuan (a4) and Xu Wanzhen (a4)...
Abstract
Abstract

The indole molecularly imprinted polymer (indole-MIP) was synthesized by atom transfer radical emulsion polymerization (ATREP). The novel adsorbent was used to adsorb indole from fuel oil. The indole-MIP had a high selectivity to indole, and the mass transfer limitations were overcome. The property and morphology of indole-MIP were described by a series of characterization methods. A great specific area and more pores of indole-MIP were shown. The static adsorption experiments display that equilibrium adsorption capacity of indole-MIP was 34.488 mg/g. The adsorption process was spontaneous by thermodynamic analysis, and a dense mass of indole was adsorbed onto indole-MIP at a proper low temperature (298 K). Pseudo-second-order kinetic model was more fitted with experimental data. Both Langmuir and Freundlich isotherm models were obeyed by adsorption isotherm test. The selective and competitive performances of indole-MIP were favorable, and the regeneration capacity was appreciable.

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a)Address all correspondence to these authors. e-mail: zhouzp@ujs.edu.cn
b)e-mail: xwz09@ujs.edu.cn
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Journal of Materials Research
  • ISSN: 0884-2914
  • EISSN: 2044-5326
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