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 Electron Probe Microscope studies in this work made use of EPIC (Electron Probe Instrumentation Center) facilities at NUANCE (Northwestern University's Atomic and Nanoscale Characterization Experimental Center), which has received support from the MRSEC program (NSF DMR-1121262) at the Materials Research Center, and the Nanoscale Science and Engineering Center (EEC-0118025/003), both programs of the National Science Foundation, the State of Illinois and Northwestern University.