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Quantification Challenges for Atom Probe Tomography of Hydrogen and Deuterium in Zircaloy-4

  • Isabelle Mouton (a1), Andrew J. Breen (a1), Siyang Wang (a2), Yanhong Chang (a1), Agnieszka Szczepaniak (a1), Paraskevas Kontis (a1), Leigh T. Stephenson (a1), Dierk Raabe (a1), M. Herbig (a1), T. Ben Britton (a2) and Baptiste Gault (a1)...

Abstract

Analysis and understanding of the role of hydrogen in metals is a significant challenge for the future of materials science, and this is a clear objective of recent work in the atom probe tomography (APT) community. Isotopic marking by deuteration has often been proposed as the preferred route to enable quantification of hydrogen by APT. Zircaloy-4 was charged electrochemically with hydrogen and deuterium under the same conditions to form large hydrides and deuterides. Our results from a Zr hydride and a Zr deuteride highlight the challenges associated with accurate quantification of hydrogen and deuterium, in particular associated with the overlap of peaks at a low mass-to-charge ratio and of hydrogen/deuterium containing molecular ions. We discuss possible ways to ensure that appropriate information is extracted from APT analysis of hydrogen in zirconium alloy systems that are important for nuclear power applications.

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*Authors for correspondence: Isabelle Mouton, E-mail: i.mouton@mpie.de; Baptiste Gault, E-mail: b.gault@mpie.de

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Ai, CF & Tsong, TT (1984). A study of the temperature dependence of a surface catalyzed and field enhanced formation of H3 and NH3 on metal surfaces. J Chem Phys 81, 28452854.
Bair, J, Asle Zaeem, M & Tonks, M (2015). A review on hydride precipitation in zirconium alloys. J Nucl Mater 466, 1220.
Birch, R, Wang, S, Tong, V & Britton, TB (2018). The effect of cooling rate and grain size on hydride formation in Zircaloy-4. arXiv:1807.11927 [cond-mat]. Available at http://arxiv.org/abs/1807.11927 (retrieved October 10, 2018).
Breen, AJ, Mouton, I, Lu, W, Wang, S, Szczepaniak, A, Kontis, P, Stephenson, LT, Chang, Y, da Silva, AK, Liebscher, CH, Raabe, D, Britton, TB, Herbig, M & Gault, B (2018). Atomic scale analysis of grain boundary deuteride growth front in Zircaloy-4. Scr Mater 156, 4246.
Chang, Y, Breen, AJ, Tarzimoghadam, Z, Kürnsteiner, P, Gardner, H, Ackerman, A, Radecka, A, Bagot, PAJ, Lu, W, Li, T, Jägle, EA, Herbig, M, Stephenson, LT, Moody, MP, Rugg, D, Dye, D, Ponge, D, Raabe, D & Gault, B (2018). Characterizing solute hydrogen and hydrides in pure and alloyed titanium at the atomic scale. Acta Mater 150, 273280.
Chen, Y-S, Haley, D, Gerstl, SSA, London, AJ, Sweeney, F, Wepf, RA, Rainforth, WM, Bagot, PAJ & Moody, MP (2017). Direct observation of individual hydrogen atoms at trapping sites in a ferritic steel. Science 355, 11961199.
Chi-fong, A & Tsong, TT (1984). Field promoted and surface catalyzed formation of H3 and NH3 on transition metal surfaces: A pulsed-laser imaging atom-probe study. Surf Sci 138, 339360.
Christensen, M, Wolf, W, Freeman, C, Wimmer, E, Adamson, RB, Hallstadius, L, Cantonwine, PE & Mader, EV (2015). H in α -Zr and in zirconium hydrides: Solubility, effect on dimensional changes, and the role of defects. J Phys: Condens Matter 27, 025402.
Devaraj, A, Perea, DE, Liu, J, Gordon, LM, Prosa, TJ, Parikh, P, Diercks, DR, Meher, S, Kolli, RP, Meng, YS & Thevuthasan, S (2018). Three-dimensional nanoscale characterisation of materials by atom probe tomography. Int Mater Rev 63, 68101.
Gault, B, La Fontaine, A, Moody, MPMP, Ringer, SPSP & Marquis, EAEA (2010). Impact of laser pulsing on the reconstruction in an atom probe tomography. Ultramicroscopy 110, 12151222.
Gault, B, Saxey, DW, Ashton, MW, Sinnott, SB, Chiaramonti, AN, Moody, MP & Schreiber, DK (2016). Behavior of molecules and molecular ions near a field emitter. This work is a partial contribution of the US Government and therefore is not subject to copyright in the United States. New J Phys 18, 33031.
Gemma, R, Al-Kassab, T, Kirchheim, R & Pundt, A (2007). Studies on hydrogen loaded V–Fe8 at% films on Al2O3 substrate. J Alloys Compd 446–447, 534538.
Gemma, R, Al-Kassab, T, Kirchheim, R & Pundt, A (2011). Analysis of deuterium in V–Fe5 at.% film by atom probe tomography (APT). J Alloys Compd 509, S872S876.
Giroldi, JP, Vizcaíno, P, Flores, AV & Banchik, AD (2009). Hydrogen terminal solid solubility determinations in Zr–2.5Nb pressure tube microstructure in an extended concentration range. J Alloys Compd 474, 140146.
Grosse, M, Steinbrueck, M, Lehmann, E & Vontobel, P (2008). Kinetics of hydrogen absorption and release in zirconium alloys during steam oxidation. Oxid Met 70, 149162.
Kellogg, GL (1981). Determining the field emitter temperature during laser irradiation in the pulsed laser atom probe. J Appl Phys 52, 5320.
Kelly, TF & Miller, MK (2007). Invited review article: Atom probe tomography. Rev Sci Instrum 78, 031101.
Kestel, BJ (1986). Non-acid electrolyte thins many materials for TEM without causing hydride formation. Ultramicroscopy 19, 205211.
Kingham, DR (1982). The post-ionization of field evaporated ions: A theoretical explanation of multiple charge states. Surf Sci 116, 273301.
Kitaguchi, HS, Lozano-Perez, S & Moody, MP (2014). Quantitative analysis of carbon in cementite using pulsed laser atom probe. Ultramicroscopy 147, 5160.
Li, S, Wang, Y, Che, Z, Liu, G, Ren, Y & Wang, Y (2017). Investigations of deformation-induced δ→ζ phase transformation in zirconium hydride by in situ high-energy X-ray diffraction. Acta Mater 140, 168175.
Li, T, Kasian, O, Cherevko, S, Zhang, S, Geiger, S, Scheu, C, Felfer, P, Raabe, D, Gault, B & Mayrhofer, KJJ (2018). Atomic-scale insights into surface species of electrocatalysts in three dimensions. Nat Catal 1, 300305.
London, AJ, Haley, D & Moody, MP (2017). Single-ion deconvolution of mass peak overlaps for atom probe microscopy. Microsc Microanal 23, 300306.
Mancini, L, Amirifar, N, Shinde, D, Blum, I, Gilbert, M, Vella, A, Vurpillot, F, Lefebvre, W, Lardé, R, Talbot, E, Pareige, P, Portier, X, Ziani, A, Davesnne, C, Durand, C, Eymery, J, Butté, R, Carlin, J-F, Grandjean, N & Rigutti, L (2014). Composition of wide bandgap semiconductor materials and nanostructures measured by atom probe tomography and its dependence on the surface electric field. J Phys Chem C 118, 2413624151.
Marquis, EAEA & Gault, B (2008). Determination of the tip temperature in laser assisted atom-probe tomography using charge state distributions. J Appl Phys 104, 084914.
McMinn, A, Darby, EC & Schofield, JS (2000). Terminal solid solubility of hydrogen in zirconium alloys. In Proc 12th Int Symp on Zirconium in the Nuclear Industry ASTM STP 1354, Sabol, GB & Moan, GD (Eds.), West Conshohocken, USA: ASTM, 173194.
Miller, MK (1981). An atom probe study of the anomalous field evaporation of alloys containing silicon. J Vac Sci Technol 19, 57.
Miller, MK (2000). Atom Probe Tomography: Analysis at the New, Atomic Level. York: Kluwer Academic/Plenum Publishers.
Müller, EW, Panitz, JA, McLane, SB & Müller, EW (1968). Atom-probe field ion microscope. Rev Sci Instrum 39, 8386.
Müller, M, Saxey, DWW, Smith, GDWDW & Gault, B (2011). Some aspects of the field evaporation behaviour of GaSb. Ultramicroscopy 111, 487492.
Orloff, J (2008). Handbook of Charged Particle Optics, 2nd ed. Boca Raton, USA: CRC Press.
Sha, W, Chang, L, Smith, GDWDW, Mittemeijer, EJJ, Liu, C & Mittemeijer, EJJ (1992). Some aspects of atom-probe analysis of Fe-c and Fe-n systems. Surf Sci 266, 416423.
Shariq, A, Mutas, S, Wedderhoff, K, Klein, C, Hortenbach, H, Teichert, S, Kücher, P & Gerstl, SSA (2009). Investigations of field-evaporated end forms in voltage- and laser-pulsed atom probe tomography. Ultramicroscopy 109, 472479.
Shen, HH, Zu, XT, Chen, B, Huang, CQ & Sun, K (2016). Direct observation of hydrogenation and dehydrogenation of a zirconium alloy. J Alloys Compd 659, 2330.
Suman, S, Khan, MK, Pathak, M, Singh, RN & Chakravartty, JK (2015). Hydrogen in Zircaloy: Mechanism and its impacts. Int J Hydrogen Energy 40, 59765994.
Sundell, G, Thuvander, M & Andrén, H-O (2013). Hydrogen analysis in APT: Methods to control adsorption and dissociation of H2. Ultramicroscopy 132, 285289.
Takahashi, J, Kawakami, K & Kobayashi, Y (2018). Origin of hydrogen trapping site in vanadium carbide precipitation strengthening steel. Acta Mater 153, 193204.
Takahashi, J, Kawakami, K, Kobayashi, Y & Tarui, T (2010). The first direct observation of hydrogen trapping sites in TiC precipitation-hardening steel through atom probe tomography. Scr Mater 63, 261264.
Takahashi, J, Kawakami, K, Otsuka, H & Fujii, H (2009). Atom probe analysis of titanium hydride precipitates. Ultramicroscopy 109, 568573.
Thompson, K, Lawrence, D, Larson, DJ, Olson, JD, Kelly, TF & Gorman, B (2007). In situ site-specific specimen preparation for atom probe tomography. Ultramicroscopy 107, 131139.
Tong, VS & Britton, TB (2017). Formation of very large ‘blocky alpha’ grains in Zircaloy-4. Acta Mater 129, 510520.
Tsong, TT, Kinkus, TJ & Ai, CF (1983). Field induced and surface catalyzed formation of novel ions: A pulsed-laser time-of-flight atom-probe study. J Chem Phys 78, 47634775.
Vurpillot, F, Houard, J, Vella, A & Deconihout, B (2009). Thermal response of a field emitter subjected to ultra-fast laser illumination. J Phys D: Appl Phys 42, 125502.
Yamanaka, S, Higuchi, K & Miyake, M (1995). Hydrogen solubility in zirconium alloys. J Alloys Compd 231, 503507.
Yao, L, Cairney, JM, Zhu, C & Ringer, SP (2011). Optimisation of specimen temperature and pulse fraction in atom probe microscopy experiments on a microalloyed steel. Ultramicroscopy 111, 648651.

Keywords

Quantification Challenges for Atom Probe Tomography of Hydrogen and Deuterium in Zircaloy-4

  • Isabelle Mouton (a1), Andrew J. Breen (a1), Siyang Wang (a2), Yanhong Chang (a1), Agnieszka Szczepaniak (a1), Paraskevas Kontis (a1), Leigh T. Stephenson (a1), Dierk Raabe (a1), M. Herbig (a1), T. Ben Britton (a2) and Baptiste Gault (a1)...

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