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A Solid Polymer Electrolyte from Photo-Crosslinked Polytetrahydrofuran and a Cycloaliphatic Epoxide for Lithium-Ion Conduction

Published online by Cambridge University Press:  18 June 2020

Francielli S. Genier Open the ORCID record for Francielli S. Genier [Opens in a new window] ,
James Barna ,
Jiayue Wang ,
Saeid Biria  and
Ian D. Hosein
Francielli S. Genier
Affiliation:
Syracuse University, Department of Biomedical and Chemical Engineering, Syracuse, NY, 13244
James Barna
Affiliation:
Cazenovia High School, Cazenovia, NY, 13035.
Jiayue Wang
Affiliation:
Syracuse University, Department of Biomedical and Chemical Engineering, Syracuse, NY, 13244
Saeid Biria
Affiliation:
Syracuse University, Department of Biomedical and Chemical Engineering, Syracuse, NY, 13244
Ian D. Hosein*
Affiliation:
Syracuse University, Department of Biomedical and Chemical Engineering, Syracuse, NY, 13244
*
*Corresponding Author: Ian D. Hosein (idhosein@syr.edu, 315.443.4126)
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Abstract

We report on the synthesis, properties, and ion conductivity of a solid polymer electrolyte produced from polytetrahydrofuran (PTHF) photo-crosslinked with 3,4-epoxycyclohexylmethyl 3ʹ,4ʹ-epoxycyclohexane carboxylate (Epoxy), via an active monomer mechanism that facilitates the reaction of the native hydroxyl and epoxide end-groups. Crosslinked samples were loaded with different quantities of lithium tetrafluoroborate (LiBF4) and evaluated by electrochemical spectroscopy impedance (EIS) to determine their ionic conductivity. An increase in lithium salt loading led to an increase in ionic transport, reaching competitive conductivities of up to 10-3 S/cm at temperatures typical for battery operation. Thermal analysis confirms the amorphous structure and high thermal stability (30-90°). The mechanical analysis shows the materials possess suitable stiffness for applications. The results demonstrate a new synthetic route to tunable crosslinked networks for a broad range of chemical building blocks to achieve high lithium-ion conduction and attain desirable thermal and mechanical properties.

Keywords

solid polymer electrolytecrosslinkinglithium conductionpolytetrahydrofuran
Type
Articles
Information
MRS Advances , Volume 5 , Issue 48-49: Energy, Storage and Conversion , 2020 , pp. 2467 - 2476
Copyright
Copyright © Materials Research Society 2020

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