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Does Exceptional Viscous Drag Impede Flow Through a Nano-Sieve's Pores?

Published online by Cambridge University Press:  01 February 2011

Peter J. Feibelman
Affiliation:
pjfeibe@sandia.gov, Sandia National Laboratories, Surface and Interface Sciences, Mail Stop 1415, Albuquerque, NM, 87185-1415, United States, 505-844-6706, 505-844-5470
J. E. Houston
Affiliation:
jehoust@sandia.gov, Sandia National Laboratories, Surface and Interface Sciences, Mail Stop 1415, Albuquerque, NM, 87185-1415, United States
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Abstract

To address the concern that a material functionalized to reject dissolved ions may give rise to a highly viscous aqueous interphase within nanometers of its surface, we conducted and interpreted Interfacial Force Microscope measurements of the dissipative forces that resist motion of a tip parallel to a sample, in water. The results are consistent with earlier measurements where the tip approached the sample. They confirm that near hydrophilically functionalized surfaces, interphase viscosities more than a million times that of bulk water can be expected.

Type
Research Article
Copyright
Copyright © Materials Research Society 2006

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References

1. Joyce, S. A. and Houston, J. E., Rev. Sci. Instrum. 62, 710 (1991).Google Scholar
2. Kim, H. I., Kushmerick, J. G., Houston, J. E. and Bunker, B. C., Langmuir 19, 271 (2003).Google Scholar
3. Feibelman, P. J., Langmuir 20, 1239 (2004).Google Scholar
4. Major, R. C., Houston, J. E., McGrath, M. J., Siepmann, J. I., and Zhu, X.-Y., Phys. Rev. Lett. (in press), and unpublished.Google Scholar
5. Schwendel, D., et al., Langmuir, 19 2284 (2003).Google Scholar
6. Cheng, L., et al., Phys. Rev. Lett. 87, 156103 (2001).Google Scholar
7.See, e.g., Antognozzi, M., A. Humphris, D. L., and Miles, M. J., App. Phys. Lett. 78, 300 (2001).Google Scholar
8. Freitas, R. A. Jr , Nanomedicine, Volume I: Basic Capabilities, (Landes Bioscience, Georgetown, TX, 1999).Google Scholar
9. Feibelman, P. J., Langmuir 22, 2136(2006).Google Scholar