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Effects of Substrate Misorientation and the Growth Mechanism of Si Doped GaAs Grown on (111)A Substrate by MBE

Published online by Cambridge University Press:  28 February 2011

Y. Okano
Affiliation:
ATR Optical and Radio Communications Research Laboratories, Sanpeidani, Inuidani, Seika-cho, Soraku-gun, Kyoto 619-02, Japan
H. Seto
Affiliation:
ATR Optical and Radio Communications Research Laboratories, Sanpeidani, Inuidani, Seika-cho, Soraku-gun, Kyoto 619-02, Japan
M. Shigeta
Affiliation:
ATR Optical and Radio Communications Research Laboratories, Sanpeidani, Inuidani, Seika-cho, Soraku-gun, Kyoto 619-02, Japan
S. Nishine
Affiliation:
ATR Optical and Radio Communications Research Laboratories, Sanpeidani, Inuidani, Seika-cho, Soraku-gun, Kyoto 619-02, Japan
I. Fujimoto
Affiliation:
ATR Optical and Radio Communications Research Laboratories, Sanpeidani, Inuidani, Seika-cho, Soraku-gun, Kyoto 619-02, Japan
T. Suzuki
Affiliation:
Science and Technical Research Laboratories of NHK, 1-10-11 Kinuta, Setagaya-ku, Tokyo 157, Japan
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Abstract

The MBE growth of Si doped GaAs on slightly misoriented (111)A substrates was examined. The conduction types and the carrier concentrations were greatly affected by the degree of substrate misorientation. In the growth on an exactly (111)A oriented substrate, substantially all Si atoms acted as acceptors. With increase of the degree of misorientation and/or with increase of the flux ratio (JAs4/JGa), the number of donor-site Si atoms increased, that is, the hole concentration first decreased by autocompensation of Si and then the conductivity reversed from p-type to n-type. The photoluminescence of highly compensated (111)A films showed characteristics of donor-acceptor pair recombination. A doping mechanism including preferential decomposition of As4 molecules at the steps was proposed.

Type
Research Article
Copyright
Copyright © Materials Research Society 1990

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