Hostname: page-component-8448b6f56d-qsmjn Total loading time: 0 Render date: 2024-04-23T07:07:51.704Z Has data issue: false hasContentIssue false

Experimental Hydration Studies of Natural and Synthetic Glasses

Published online by Cambridge University Press:  21 February 2011

John K. Bates
Affiliation:
Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439
Teofilo A. Abrajano Jr.
Affiliation:
Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439
William L. Ebert
Affiliation:
Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439
James J. Mazer
Affiliation:
Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439
Thomas J. Gerding
Affiliation:
Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439
Get access

Abstract

The results of a series of hydration experiments on natural glasses (Hawaiian basalt, obsidian) and the nuclear waste glass WV-44 done to examine laboratory methods of accelerating reaction processes are summarized. The glasses were reacted in hydrothermal solution and in saturated vapor water. It was found that different reaction rates and processes were found using the differing conditions, and that laboratory efforts to accelerate and duplicate natural processes must account for the physical processes that occur naturally.

Type
Research Article
Copyright
Copyright © Materials Research Society 1988

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Moore, J. G., U.S. Geol. Survey Prof. Paper 550D, p. D163-D171 (1966).Google Scholar
2. Moore, J. G., Fornari, D. J., and Clague, D. A., U.S. Geol. Survey Bull. 1663 (1985).Google Scholar
3. Morgenstein, M. and Riley, T. J., Asian Perspectives 17, 145 (1975).Google Scholar
4. Furnes, H., Mineral. Petrol. 50, 105113 (1975).Google Scholar
5. Crovisier, J. L., Honnorez, J., and Eberhart, J. P., Geochim. et Cosmochim. Acta 51, 29772990 (1987).Google Scholar
6. D.Byers, C., Jercinovic, M. J., Ewing, R. C., and Keil, K., in Scientific Basis for Nuclear Waste Management 44, 583591 (1985).Google Scholar
7. Lanford, W. A., Science 196, 975976(1977).Google Scholar
8. Tsong, I. S. T. et al., Science 201, 339341 (1978).Google Scholar
9. Karhanis, S. N. et al., Nature 284, 435437 (1980).Google Scholar
10. Friedman, I. and Trembour, F. W., Amer. Scientist 66, 4451 (1978).Google Scholar
11. Bates, J. K., Jardine, L. J., and Steindler, M. J., Science 218, 5154 (1982).Google Scholar
12. Bates, J. K. et al., Lawrence Livermore National Laboratory report UCRL-15801 (1988).Google Scholar
13. Byers, C. D., Jercinovic, M. J., and Ewing, R. C., U.S. Nuclear Regulatory Commission report NUREG/CR-4842 (1987).Google Scholar
14. Ebert, W. L. and Bates, J. K., “NNWSI Waste Form Testing at Argonne National Laboratory, Semiannual Report, July-December 1987,” in press.Google Scholar
15. Bates, J. K., Jardine, L. J., and Steindler, M. J., Argonne National Laboratory report ANL-82-11 (1982).Google Scholar
16. Abrajano, T. A. and Bates, J. K., in preparation.Google Scholar
17. Stevenson, C. M., Archaeological and Historial Consultants, Inc., personal communication.Google Scholar
18. Ambrose, W., in Advances in Obsidian Glass Studies, edited by Taylor, R. E. (Noyes Press Publishers, Park Ridge, NJ, 1976), p. 81.Google Scholar