Hostname: page-component-8448b6f56d-qsmjn Total loading time: 0 Render date: 2024-04-24T08:51:12.840Z Has data issue: false hasContentIssue false

High-Permeability Particles for Magnetic Composites

Published online by Cambridge University Press:  26 February 2011

Robert Sailer
Affiliation:
rob.sailer@ndsu.edu, North Dakota State University, Center for Nanoscale Science and Engineering, United States
Pamela J Jeppson
Affiliation:
pamela.jeppson@ndsu.edu, North Dakota State University, Center for Nanoscale Science and Engineering, United States
Eric L Jarabek
Affiliation:
eric.jarabek@ndsu.edu, North Dakota State University, Center for Nanoscale Science and Engineering, United States
Joseph A Sandstrom
Affiliation:
joseph.sandstrom@ndsu.edu, North Dakota State University, Center for Nanoscale Science and Engineering, United States
Zoha Al-Badri
Affiliation:
zoha.albadri@ndsu.edu, North Dakota State University, Center for Nanoscale Science and Engineering, United States
Dean G Grier
Affiliation:
dean.grier@ndsu.edu, North Dakota State University, Center for Nanoscale Science and Engineering, United States
Anthony N Caruso
Affiliation:
anthony.caruso@ndsu.edu, North Dakota State University, Center for Nanoscale Science and Engineering, United States
Philip R Boudjouk
Affiliation:
philip.boudjouk@ndsu.edu, North Dakota State University, Research, Creative Activities and Tech Transfer, United States
Pete Eames
Affiliation:
peames@nve.com, NVE, United States
Mark Tondra
Affiliation:
markt@nve.com, NVE, United States
Douglas L Schulz
Affiliation:
doug.schulz@ndsu.edu, North Dakota State University, Center for Nanoscale Science and Engineering, United States
Get access

Abstract

Electromagnetic shields and flux concentrators for magnetic sensors could utilize flexible and insulating composites applied using simple thin film deposition methods such as dip-coating, spin-coating, spraying, etc. As the first step towards development of composites with superior performance, efforts focused on isolating nanoparticles with large magnetizations under low fields. In this paper, we provide the results of proof-of-concept studies for two systems: metal-functionalized silicone-based materials (metal-silicone); and, Co-ferrite (Co2+1−xFe2+xFe3+2O4) nanoparticles. The metal-silicone materials studied included a polysiloxane that contained a pendant ferrocene where an optimum saturization magnetization of 5.9 emu/g (coercivity = 11 Oe) was observed. Co-ferrite nanoparticle samples prepared in this study showed unprecendented saturation magnetization (i.e., Ms > 150 emu/g) with low coercivity (Hc ∼ 10 Oe) at room temperature and offer potential application as flux concentrators.

Type
Research Article
Copyright
Copyright © Materials Research Society 2006

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1 Ph.D. Dissertation, AL-Badri, Zoha M., “Metal Containing Polysiloxanes: Precursors to Novel Magnetic Ceramic Nanocomposites, (2004).Google Scholar
2 Manova, E., Kunev, B., Paneva, D., Mitov, I., Petrov, L., Estournès, C., D'Orleans, C., Rehspringer, J.-L., Kurmoo, M., Chem. Mater. 16, 5689–5609 (2004).Google Scholar
3 Olsson, R.T., Salazar-Alvarez, G., Hedenqvist, M.S., Gedde, U.W., Lindberg, F., Savage, S.J., Chem. Mater. 17, 51095118 (2005).Google Scholar
4 Betancourt-Galindo, R., Ayala-Valenzuela, O., Garcia-Cerda, L.A., Fernandez, O. Rodriguez, Matutes-Aquino, J., Ramos, G., Yee-Madeira, H., J. Magn. Magn. Mater. 294, e33–e36 (2005); ibid pp e37-e41.Google Scholar
5 Moumen, N., Pileni, M.P., J. Phys. Chem. 100, 18671873 (1996); A.T. Ngo, P. Bonville, M.P. Pileni, Eur. Phys. J. B9, 583-592 (1999).Google Scholar
6 Li, X., Kutal, C., J. Alloys Comp. 349, 264268 (2003).Google Scholar
7 Pillai, V., Shah, D.O., J. Magn. Magn. Mater. 163, 243248 (1996).Google Scholar
8 Seip, C.T., Carpenter, E.E., O'Connor, C.J., John, V.T., Li, S., IEEE Trans. Magn. 34, 11111113 (1998).Google Scholar
9 Shafi, K.V.P.M., Gedanken, A., Prozorov, R., Balogh, J., Chem. Mater. 10, 34453450 (1998).Google Scholar
10 Klug, H. P., Alexander, L. E., X-ray Diffraction Procedures for Polycrystalline and Amorphous Materials; (Wiley, 1962), pp. 491538 Google Scholar
11 Hoh, J.C., Yaacob, I.I., J. Mater. Res. 17 (2002) 31053109.Google Scholar