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High-Temperature Processing and Applications of Silica-Modified Portland Cement CBC Composites

Published online by Cambridge University Press:  21 February 2011

Sean Wise
Affiliation:
CEMCOM Corporation/CBC Products Group, Occidental Chemical Corporation
R. Kevan
Affiliation:
CEMCOM Corporation/CBC Products Group, Occidental Chemical Corporation
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Abstract

Silica-modified portland cement-based Chemically Bonded Composites (CBCs) have been prepared and cured to elevated temperatures. It has been found that when cementitious composites with calcium-to-silica (C/S) ratios of 0.83 are thoroughly hydrated through hydrothermal curing, followed by careful dehydration, mortars of exceptional strength are produced. The bulk of this strength is maintained to over 600°C. X-ray diffraction studies of binder samples dried at 200°C and 500°C show only slight differences in mineral product contents. Above 600°C, a drop in strength is noted, and a substantial portion of the binder converts to wollastonite. Even so, these CBC composites retain as much as 40% of their peak compressive strength to temperatures up to 800°C. Applications of these materials in high-temperature industrial processes are presented.

Type
Research Article
Copyright
Copyright © Materials Research Society 1991

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References

1. Schnieder, U., Diedrichs, U., and Ehm, C., “Effect of Temperature on Steel and Concrete for PCRV's,” Nuclear Engineering and Design, 67, 245258 (1981).Google Scholar
2. Williamson, R. B. and Rashed, A. I., “High Strength Concrete and Mortars in High Temperature Environments,” Materials Research Society Symposium Proceedings, 42, 295303 (1985).Google Scholar
3. Hertz, K., “Heat Induced Explosion of Dense Concretes,” Lyngby, Technical University of Denmark, Institute of Building Design Report No. 166 (1984).Google Scholar
4. Wise, S., Satkowski, J., Scheetz, B., Rizer, J., MacKenzie, M., and Double, D., “The Development of a High Strength Cementitious Tooling/Molding Material,” Materials Research Society Symposium Proceedings, 42, 251263 (1985).Google Scholar
5. Wise, S., Jones, K., Herzfeld, C., and Double, D., “Chopped Fiber Reinforced Chemically Bonded Ceramic (CBC) Composites,” Materials Research Society Symposium Proceedings, 114, 197203 (1987).Google Scholar
6. Sun, G. K. and Young, J. F., “A Study of Reaction in Autoclaved DSP Cements,” Presented at the American Ceramic Society Annual Meeting, April 2426, 1989.Google Scholar
7. Scheetz, B. E., Roy, D., and Duffy, C., “Physical and Mechanical Properties of Thermally Altered Cementitious Sealing Materials for a Nuclear Waste Repository in Tuff,” International Conference on the Use of Fly Ash, Silica Fume, Slag and Natural Pozzolans in Concrete, Trondheim, Norway, 3rd CANMET/ACI Ed. V. M. Malhotra V. II (1989).Google Scholar
8. Wise, S., Bright, R. P., and Double, D. D., “Control of Thermal Expansion in Castable Tooling Materials,” Proceedings of Composites in Manufacturing 5, EM 86–105, Jan. 1986.Google Scholar
9. Wise, S. and Kuo, S., “A Cementitious Tooling/Molding Material-Room Temperature Castable, High Temperature Capable,” SAE SP623 Composites: Design and Manufacturing for General Aviation Aircraft, p. 61, April 1985.Google Scholar
10. Wise, S., “Chemically Bonded Ceramic Tooling for Thermoplastic Composites Fabrication,” SME Tooling for Composites Conference, TE88–210, May 1988.Google Scholar