Hostname: page-component-76fb5796d-r6qrq Total loading time: 0 Render date: 2024-04-25T15:15:57.654Z Has data issue: false hasContentIssue false

In-situ study of the stiffness of alumina thin films during vapor deposition

Published online by Cambridge University Press:  21 March 2011

Joris Proost
Affiliation:
Division of Engineering and Applied Sciences, Harvard University, Cambridge, MA 02138, USA
Frans Spaepen
Affiliation:
Division of Engineering and Applied Sciences, Harvard University, Cambridge, MA 02138, USA
Get access

Abstract

The evolution of the biaxial modulus of amorphous alumina thin films has been studied insitu during electron-beam evaporation at 400°C on Si and sapphire substrates. A constant value of 197 ± 30 GPa was measured up to a thickness of 1.17 μm when depositing at 3 Å/s. This value was identical to that of films thinner than 0.30 μm deposited at an average rate of 6 Å/s. Above 0.30 μm, the modulus in these films decreased continuously to a value of 50 ± 8 GPa at a final thickness of 2.05 μm. Based on their refractive indices, the films deposited at 6 Å/s are 30% less dense than those deposited at 3 Å/s. This density deficit is insufficient to account for the modulus decrease; the remainder is probably the result of slit-like microcracks.

Type
Research Article
Copyright
Copyright © Materials Research Society 2001

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

[1] Coble, R.L. and Kingery, W.D., J. Amer. Ceram. Soc. 39, 377 (1956)Google Scholar
[2] Siebert, B., Funke, C., Vassen, R. and Stover, D., J. Mat. Proc. Techn. 92, 217 (1999)Google Scholar
[3] Thornton, J.A. and Chin, J., Ceram. Bull. 56, 504 (1977)Google Scholar
[4] Floro, J.A. and Chason, E., Mater. Res. Soc. Symp. Proc. 406, 491 (1996)Google Scholar
[5] Simmons, G. and Wang, H., Single Crystal Elastic Constants and Calculated Aggregate Properties: A Handbook, 2nd ed. (MIT Press, 1971), p. 146 Google Scholar
[6] White, G.K., Thermochimica Acta 218, 83 (1993)Google Scholar
[7] Huang, H. and Spaepen, F., Acta Mater. 48, 3261 (2000)Google Scholar
[8] Born, M. and Wolf, E., Principle of Optics, 6nd ed. (Pergamon Press, 1980), p. 87 Google Scholar
[9] Parfitt, L., Goldiner, M., Jones, J.W. and Was, G.S., J. Appl. Phys. 77, 3029 (1995)Google Scholar
[10]Eshelby, J.D., Proc. Roy. Soc. London A 241, 376 (1957)Google Scholar