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Langmuir-Blodgett Assembly of Soft Carbon Sheets

Published online by Cambridge University Press:  06 September 2011

Laura J. Cote
Affiliation:
Department of Materials Science and Engineering, Northwestern University, Evanston, USA
Jaemyung Kim
Affiliation:
Department of Materials Science and Engineering, Northwestern University, Evanston, USA
Jiaxing Huang
Affiliation:
Department of Materials Science and Engineering, Northwestern University, Evanston, USA
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Abstract

Graphene oxide sheets have recently gained immense interest as a building block for graphene based materials and devices. Rapid developments have been made in the chemistry and applications of GO. However, assembly, too, plays a critical role in the final properties of bulk graphene based materials as it determines the microstructures of the 2D sheets. There is thus a pressing need for controllable assembly strategies. Based on the recent identification of the pH dependent surfactant-like behavior of GO sheets, we are now able to control the tiling morphologies of such sheets to produce thin films with either wrinkled or overlapped types of microstructures. This allows for the deconvolution of the effects of these two basic morphological features in the electrical and optical properties of the resulting thin films, providing a well-defined example of the processing-microstructure-properties relationship for this unique soft material building block.

Type
Research Article
Copyright
Copyright © Materials Research Society 2011

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References

Notes and References

1. Brodie, B.C., Philos. Trans. R. Soc. London, 1859, 149, 249259.Google Scholar
2. Hummers, W.S. and Offeman, R.E., J. Am. Chem. Soc., 1958, 80, 1339.Google Scholar
3. Cai, W., Piner, R.D., Stadermann, F.J., Park, S., Shaibat, M.A., Ishii, Y., Yang, D., Velamakanni, A., An, S.J., Stoller, M., An, J., Chen, D. and Ruoff, R.S., Science, 2008, 321, 18151817.Google Scholar
4. Lerf, A., He, H.Y., Forster, M. and Klinowski, J., J. Phys. Chem. B, 1998, 102, 44774482.Google Scholar
5. Li, D., Muller, M.B., Gilje, S., Kaner, R.B., and Wallace, G.G., Nat. Nanotechnol., 2008, 3, 101105.Google Scholar
6. Gao, W., Alemany, L.B., Ci, L., and Ajayan, P.M., Nat. Chem., 2009, 1, 403408.Google Scholar
7. Bagri, A., Mattevi, C., Acik, M., Chabal, Y.J., Chhowalla, M. and Shenoy, V.B., Nat. Chem., 2010, 2, 581587.Google Scholar
8. Wei, Z., Wang, D., Kim, S., Kim, S.Y., Hu, Y., Yakes, M.K., Laracuente, A.R., Dai, Z., Marder, S.R., Berger, C., King, W.P., de Heer, W.A., Sheehan, P.E. and Riedo, E., Science, 2010, 328, 13731376.Google Scholar
9. Li, D. and Kaner, R.B., Science, 2008, 320, 11701171.Google Scholar
10. Allen, M.J., Tung, V.C. and Kaner, R.B., Chem. Rev., 2010, 110, 132145.Google Scholar
11. Park, S. and Ruoff, R.S., Nat. Nanotechnol., 2009, 4, 217224.Google Scholar
12. Compton, O.C. and Nguyen, S.T., Small, 2010, 6, 711723.Google Scholar
13. Cote, L.J., Kim, F., and Huang, J., J. Am. Chem. Soc., 2009, 131, 10431049.Google Scholar
14. Kim, J., Cote, L.J., Kim, F., Yuang, W., Shull, K.R. and Huang, J., J. Am. Chem. Soc., 2010, 132, 81808186 Google Scholar
15. Wang, X., Zhi, L. and Mullen, K., Nano Lett., 2007, 8, 323327.Google Scholar
16. Eda, G., Fanchini, G. and Chhowalla, M., Nat. Nanotechnol., 2008, 3, 270274.Google Scholar
17. Tung, V.C., Allen, M.J., Yang, Y., and Kaner, R.B., Nat. Nanotechnol., 2009, 4, 2529.Google Scholar
18. Becerril, H.A., Mao, J., Liu, Z., Stoltenberg, R.M., Bao, Z. and Chen, Y., ACS Nano, 2008, 2, 463470.Google Scholar
19. De, S. and Coleman, J.N., ACS Nano, 2010, 4, 27132720.Google Scholar
20. Liang, Y.Y., Frisch, J., Zhi, L.J., Norouzi-Arasi, H., Feng, X.L., Rabe, J.P.. Koch, N. and Mullen, K., Nanotechnology, 2009, 20, 4007.Google Scholar
21. Su, Q., Pang, S.P., Alijani, V., Li, C., Feng, X.L. and Mullen, K., Adv. Mater., 2009, 21, 31913195.Google Scholar
22. Kim, J., Kim, F. and Huang, J., Mater. Today, 2010, 13, 2838.Google Scholar