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Leakage Current and Reliability on Planar High-k Capacitor with Al2O3 Dielectric Deposited by Thermal-ALD

Published online by Cambridge University Press:  05 August 2015

S. Madassamy
Affiliation:
IPDIA, R&D, 2 Rue de la Girafe, 14000 Caen, France CEA Leti, LCRF, Univ. Grenoble Alpes, F-38000 Grenoble, France, CEA, LETI, MINATEC Campus, F-38054 Grenoble, France CEA-Grenoble, SiNaPs, Minatec-BCA, 17 Avenue des Martyr, 38054 Grenoble Cedex 9, France Univ. Grenoble Alpes, G2Elab, CNRS, F-38000 Grenoble, France
F. Voiron
Affiliation:
IPDIA, R&D, 2 Rue de la Girafe, 14000 Caen, France
A. P. Nguyen
Affiliation:
IPDIA, R&D, 2 Rue de la Girafe, 14000 Caen, France CEA Leti, LCRF, Univ. Grenoble Alpes, F-38000 Grenoble, France, CEA, LETI, MINATEC Campus, F-38054 Grenoble, France
A. Lefèvre
Affiliation:
CEA Leti, LCRF, Univ. Grenoble Alpes, F-38000 Grenoble, France, CEA, LETI, MINATEC Campus, F-38054 Grenoble, France
G. Parat
Affiliation:
CEA Leti, LCRF, Univ. Grenoble Alpes, F-38000 Grenoble, France, CEA, LETI, MINATEC Campus, F-38054 Grenoble, France
D. Buttard
Affiliation:
CEA-Grenoble, SiNaPs, Minatec-BCA, 17 Avenue des Martyr, 38054 Grenoble Cedex 9, France
A. Sylvestre
Affiliation:
Univ. Grenoble Alpes, G2Elab, CNRS, F-38000 Grenoble, France
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Abstract

Due to its wide band-gap, Al2O3 is known to have a moderate leakage current and a good dielectric strength [1]. Moreover, this dielectric has a fair permittivity and so constitutes interesting candidate as dielectric for Metal-Insulator-Metal (MIM) capacitor. Atomic Layer Deposition (ALD) allows obtaining a dense and thin Al2O3 amorphous layer. ALD limits problems of interlayer diffusion because Al2O3 is deposited underneath 400°C [2] which is essential when MIM are co-integrated with temperature sensitive structures.

The aim of our investigation is to attempt to tie aluminum oxide properties dielectric with reliability from the help of capacitors of the entire wafer. In this way, conduction mechanism analysis and capacitance measurements were statistically led on the wafer. We particularly focus our study on the quantification of defects and their influence on the leakage current in planar capacitor. Firstly, to estimate the fixed oxide charges densities in the bulk of Al2O3 and to analyze conduction mechanism, Metal-Oxide-Semiconductor (MOS) (Al/Al2O3/HR-Si) is developed. Then, a MIM stack (Al/TiN/Al2O3/TiN/HR-Si) is developed in order to evaluate the leakage current and the electrical reliability of thin films Al2O3 based MIM capacitors. Different performances are observed according to the area on the wafer. That could be explained by the quality of the Al2O3 layer and the interfaces between TiN and the oxide.

Type
Articles
Copyright
Copyright © Materials Research Society 2015 

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References

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