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Nonlinear Optical Properties of Polyphosphazenes

  • K.F. Ferris (a1) and S.M. Risser (a1)
Abstract

Theoretical second hyperpolarizabilities for a series of iso-electronic conjugated inorganic systems, including polyphosphazenes, have been evaluated using electronic structure methods. The nonlinear optical properties of these molecules are controlled by the electronegativity difference along the backbone, which may be modulated by the electron donating/accepting properties of the ligands.

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[1] Levine, B.F. and Bethea, C.G., J. Chem. Phys, 63, 2666 (1975)
[2] Allcock, H.R., Phosphorus-Nitrogen Compounds, New York: Academic Press (1972); D.P. Craig and N.L. Paddock, J. Chem. Soc. London 4118 (1962); D.P. Craig and K.A.R. Mitchell, J. Chem. Soc. London 4682 (1965); N.L. Paddock, Quart. Rev. Chem. Soc. 18, 168 (1964); M.J.S. Dewar, E.A.C. Lucken, and M.A. Whitehead, J. Chem. Soc. 2423 (1960); G.J. Trinqueir, J. Am. Chem. Soc. 108, 568 (1986); G. J. Trinquier, J. Am Chem. Soc. 104, 6969 (1982); R.A. Wheeler, R. Hoffman, and J. Strahle, J. Am. Chem. Soc. 108, 5381 (1986); K.F. Ferris, P. Friedman, and D.M. Friedrich, Int. J. Quant. Chem. Symp. 22, 207 (1988) and references therein.
[3] Ferris, K.F. and Duke, C.B., Int. J. Quant. Chem. Symp. 23, 397 (1989).
[4] Quantum Chemical Program Exchange, Program #57 1, “MOPAC 5.0”, Stewart, J.P.P. and Dewar, M.J.S..
[5] Ernst, C.A., Allred, A.L., Ratner, M.A., Newton, M. D., Gibbs, G.V., Moskowitz, J.W., S. Topiol Chem. Phys. Letters 81, 424 (1981); W.J. Mortier, J. Sauer, J.A. Lercher, and H. Noller J. Phys. Chem. 88, 905 (1984).
[6] Hedberg, J.K., J. Amer. Chem. Soc. 77, 6491 (1955); J. Barrow and E.A.V. Ebsworth, J. Chem. Soc., Dalton Trans. 563 (1984); A. Almenningen, K. Hedberg, R. Seip, Acta. Chem. Scand. 17, 2264 (1960); G.V. Gibbs, P. D'Arco, M.B. Boisen, J. Phys. Chem. 91, 5347 (1987); M.M. Julian, G.V. Gibbs, J. Phys. Chem. 92, 1444 (1988).
[7] Kurtz, H.A., Stewart, J.J.P. and Dieter, K.M., J. Comp. Chem. 11, 82 (1990)
[8] Ferris, K.F. and Risser, S.M., Chem. Phys. Lett. (1990) in press.
[9] Risser, S.M. and Ferris, K.F., Chem. Phys. Lett. 170, 349 (1990)
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  • EISSN: 1946-4274
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