Hostname: page-component-8448b6f56d-tj2md Total loading time: 0 Render date: 2024-04-23T22:34:08.654Z Has data issue: false hasContentIssue false

Photoablation Studies of Polymers, Quartz, and Semiconductors with Vacuum Ultraviolet Laser Radiation

Published online by Cambridge University Press:  25 February 2011

Peter R. Herman
Affiliation:
Department of Electrical Engineering, University of Toronto, Toronto, Ont., Canada M5S-1A4
Boyi Chen
Affiliation:
Department of Electrical Engineering, University of Toronto, Toronto, Ont., Canada M5S-1A4
David J. Moore
Affiliation:
Department of Electrical Engineering, University of Toronto, Toronto, Ont., Canada M5S-1A4
Mark Canaga-Retnam
Affiliation:
Department of Electrical Engineering, University of Toronto, Toronto, Ont., Canada M5S-1A4
Get access

Abstract

Excimer lasers sources of 193nm and 157 nm wavelength were used to obtain new photoablation etching rates for several materials of interest to the microelectronics industry. The harder 157nm radiation provided lower ablation rates and smaller threshold fluences for Polyimide and Polymethyl Methacrylate (PMMA) than with 193nm. For normally robust materials like quartz and Teflon (PTFE), the 157nm laser produced clean and smooth ablation sites with low threshold fluences of 620mJ/cm2 and 68mJ/cm2, respectively, features impossible to obtain with conventional excimer lasers at longer wavelengths. The data should help define new micromachining applications of these two materials for the electronic, optical or medical industry. Results are also reported for GaAs and InP based materials which are found to undergo moderate etch rates of 30-80nm/pulse at fluences of ∼3J/cm2, but suffer thermal damage and material segregation due to surface melting.

Type
Research Article
Copyright
Copyright © Materials Research Society 1992

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Yamada, K., Miyazaki, K., Hasama, T., and Sato, T., Appl. Phys. Lett., 54, 597 (1989); M. Kakehata, E. Hashimoto, F. Kannari, and M. Obara, ibid., 56, 2599 (1990).Google Scholar
2. Henderson, D. and White, J.C., Appl. Phys. Lett., 46, 900 (1985).Google Scholar
3. Craighead, H.G., White, J.C., Howard, R.E., Jackel, L.D., Behringer, R.E., Sweeney, J.E., and Epworth, R.W., J. Vac. Sci. Technol., 1, 1186 (1983).CrossRefGoogle Scholar
4. Ehrlich, D.J., Tsao, J.Y., and Bozler, C.O., J. Vac. Sci. Technol., 3, 1 (1985).CrossRefGoogle Scholar
5. Dyer, P.E. and Sidhu, J., J. Opt. Soc. Am., 3, 792 (1986).Google Scholar
6. Srinivasan, V., Smrtis, M.A., and Babu, S.V., J. Appl. Phys., 59, 3861 (1986); R. Srinivasan, B. Braren, and R.W. Dreyfus, ibid., 61, 372 (1987).CrossRefGoogle Scholar
7. Sutcliffe, E. and Srinivasan, R., J. Appl. Phys., 60, 3315, (1986).Google Scholar
8. Arakawa, E.T., Williams, M.W., Ashley, J., Painter, L.R., J. Appl. Phys., 52, 3579, (1981).Google Scholar
9. Kuper, S. and Stuke, M., Appl Phys. B, 44, 199, (1987).Google Scholar
10. Kuper, S. and Stuke, M., Appl. Phys. Lett., 54, 4, (1989).CrossRefGoogle Scholar
11. Hiraoka, H. and Lazare, S., paper CFF4 presented at the 1991 Conference on Lasers and Electro-Optics, Baltimore, Md., May 1991.Google Scholar
12. Braren, B. and Srinivasan, R., J. Vac. Sci. Technol. B, 6, 537, (1988).Google Scholar
13. Davis, G.M., Thomas, D.W., and Gower, M.C., J. Phys. D: Appl. Phys., 21, 683, (1988).Google Scholar
14. Meiler, J., Matz, R., and Haarer, D., Applied Surface Science, 43, 416, (1989).CrossRefGoogle Scholar