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Preparation and Mechanical Properties of Hafnium-based Bulk Metallic Glasses

Published online by Cambridge University Press:  17 March 2011

Xiaofeng Gu
Affiliation:
Department of Materials Science and Engineering, Johns Hopkins University, Baltimore, MD 21218, U.S.A.
Li-qian Xing
Affiliation:
Department of Materials Science and Engineering, Johns Hopkins University, Baltimore, MD 21218, U.S.A.
T. C. Hufnagel
Affiliation:
Department of Materials Science and Engineering, Johns Hopkins University, Baltimore, MD 21218, U.S.A.
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Abstract

We have prepared bulk metallic glasses of composition (HfxZr1-x)52.5Cu17.9Ni14.6Al10Ti5 (with x=0-1) by an arc melting/suction casting method. The density of these alloys increases by nearly 67% with increasing Hf content, which is advantageous for their potential use as kinetic energy armor-piercing projectile materials. The glass transition temperature and the melting temperature increase linearly with increasing Hf content. The reduced glass transition temperature (Tg/Tm) decreases from 0.64 (x=0) to 0.62 (x=1), indicating reduced glass-forming ability for the Hf- based alloy. The fracture strength in uniaxial compression at quasi-static strain rates also increases with increasing Hf content, reaching ∼ 2.2 GPa for Hf52.5Cu17.9Ni14.6Al10Ti5.

Type
Research Article
Copyright
Copyright © Materials Research Society 2001

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References

[1] Peker, A. and Johnson, W. L., Appl. Phys. Lett. 63 (1993) 2342.Google Scholar
[2] Lin, X. H., Johnson, W. L., and Rhim, W. K., Mater. Trans. JIM 39 (1997) 477.Google Scholar
[3] Xing, L. Q., Eckert, J., Loser, W., and Schultz, L., Appl. Phys. Lett. 73 (1998) 2110.Google Scholar
[4] Turnbull, D. and fisher, J. C., J. Chem. Phys. 17 (1949) 71; D. Turnbull, J. Chem. Phys. 18 (1950) 198.Google Scholar
[5] Pampillo, C. A., Scripta Metall. 6 (1972) 915.Google Scholar
[6] Pampillo, C. A., J. Mat. Sci. 10 (1975) 1194.Google Scholar
[7] Spaepen, F., Acta Metall. 25 (1977) 407.Google Scholar
[8] Li, J. C. M., Met. Trans. A 16A (1985) 2227.Google Scholar
[9] Zielinski, P. H. and Ast, D. G., Phil. Mag. A48 (1983) 811.Google Scholar
[10] Argon, A. S., Megusar, J., and Grant, N. J., Scripta Metall. 19 (1985) 591.Google Scholar
[11] Magness, Lee S. Jr, Mech. Mat. 17 (1994) 147.Google Scholar
[12] Gu, X., Xing, L. Q., and Hufnagel, T. C., submitted to J. of Non-Cryst. Solids.Google Scholar
[13] Xing, L. Q., Eckert, J., Loser, W., and Schultz, L., Appl. Phys. Lett. 74 (1999) 664.Google Scholar