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The Use of Functionalized Polybenzoxazoles and Polybenzobisthiazoles in Polymer-Silica Hybrid Materials

Published online by Cambridge University Press:  10 February 2011

J. E. Mark ,
J. Premachandra ,
C. Kumudinie ,
W. Zhao ,
T. D. Dang ,
J. P. Chen  and
F. E. Arnold
J. E. Mark
Affiliation:
Department of Chemistry and the Polymer Research Center, University of Cincinnati, Cincinnati, OH 45221-0172
J. Premachandra
Affiliation:
Department of Chemistry and the Polymer Research Center, University of Cincinnati, Cincinnati, OH 45221-0172
C. Kumudinie
Affiliation:
Department of Chemistry and the Polymer Research Center, University of Cincinnati, Cincinnati, OH 45221-0172
W. Zhao
Affiliation:
Department of Chemistry and the Polymer Research Center, University of Cincinnati, Cincinnati, OH 45221-0172
T. D. Dang
Affiliation:
Wright Laboratory, Materials Directorate, Wright-Patterson Air Force Base, Dayton, OH 45433
J. P. Chen
Affiliation:
Wright Laboratory, Materials Directorate, Wright-Patterson Air Force Base, Dayton, OH 45433
F. E. Arnold
Affiliation:
Wright Laboratory, Materials Directorate, Wright-Patterson Air Force Base, Dayton, OH 45433
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Abstract

Hybrid organic-inorganic composites were prepared by precipitating silica into hydroxypolybenzoxazole (HPBO) and sulfopolybenzobisthiazole (SPBT) polymers, with interfacial bonding between the phases improved by use of isocyanatopropyltriethoxy silane and N,N-diethylaminopropyltrimethoxy silane, respectively. The resulting materials were characterized with regard to their transparency, silica particle distribution, tensile modulus and tensile strength, thermal stability, and tendency to absorb water.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 435: Symposium V – Better Ceramics Through Chemistry VII , 1996 , 93
Copyright
Copyright © Materials Research Society 1996

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