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IX.—The Synthesis of 8-Phenyl-7H-Benz[de]anthracene*

  • Neil Campbell (a1) and Jamieson Walker (a1)
Extract

2-Benzylidene-2,3-dihydrophenalen-i-one with ethyl acetoacetate and sodium ethoxide yields four products depending on the concentration of the alkali. One of these, ethyl 7a,8,9,10-tetrahydro-10-oxo-8- phenyl-7H-benz[de]-anthracene-9-carboxylate has been converted into 8-phenyl-7H-benz[de]anthracene and its reduction with sodium borohydride or hydrogen in the presence of platinum oxide or Raney nickel presents points of interest.

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References
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Anderson, D. M. W., Campbell, N., Leaver, D., and Stafford, W. H., 1959, J. Chem. Soc., 3992.
Anderson, D. M. W., and Leaver, D., 1962, J. Chem. Soc., 450.
Campbell, N., Neale, R. F., and Wall, R. A., 1959, J. Chem. Soc., 1409.
Campbell, N., Neale, R. F., Swan, B. M., and Walker, J., 1966, J. Chem. Soc., 2011.
Cole, A. R. H., and Miller, C. T. A., 1959, J. Chem. Soc., 1224.
Kuhn, L. P., van Schleyer, P., Bartinger, W. F., Eberson, L., 1964, J. Am. Chem. Soc., 86, 650.
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Proceedings of the Royal Society of Edinburgh Section A: Mathematics
  • ISSN: 0308-2105
  • EISSN: 1473-7124
  • URL: /core/journals/proceedings-of-the-royal-society-of-edinburgh-section-a-mathematics
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