We determined the carbon and lithium abundances and carbon isotopic ratios for 4 peculiar carbon stars by means of spectral synthesis method. Li abundances were derived using Li resonance line at λ6707.8 Â. For carbon abundance determinations we used the lines of the red system of CN molecule. Spectral region of λλ7994 — 8030 Â containing the lines of molecules 12CN and 13CN was used also for 12C/13C ratio measuring. The high-resolution spectra were obtained on the 1.52m telescope of ESO with the Fiber-fed Extended Range Optical Spectrograph (FEROS). These observations were obtained under the agreement between the CNPq-Observatório Nacional, Brazil, and ESO.