Synthesis and ion transport property studies on hot-pressed Na+ ion
conducting solid polymer electrolytes (SPEs): (1-x) PEO: x NaPO3, where
x in wt.%, are reported. The compositional dependent conductivity
(σ) studies revealed SPE film: (75PEO: 25NaPO3) as the optimum
conducting composition (OCC) with room temperature conductivity σ
~ 6.7 × 10-7 S cm-1, which is more than two orders of
magnitude higher than that of pure PEO polymer host (σ ~ 3.2 × 10-9 S cm-1). Materials characterization and polymer-salt
complexation were done with the help of XRD, FTIR, SEM, DSC techniques. In
order to understand the ion transport behaviour in SPEs, the measurement on
some basic ionic parameters viz. ionic conductivity (σ), ionic
mobility (μ), mobile ion concentration (n), ionic transference number
(tion) have been carried out using different experimental techniques.
The activation energy (Ea) values involved in the thermally activated
conductivity processes have been computed from “log σ - 1/T”
Arrhenius plots.