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Interlamellar Incorporation of Charged Polymer Nanobeads into Sodium Montmorillonite

Published online by Cambridge University Press:  01 February 2011

Svetlana Khvan ,
Sang-Soo Lee  and
Junkyung Kim
Svetlana Khvan
Affiliation:
Materials Science and Technology Division, Polymer Hybrid Research Center, Korea Institute of Science and Technology, P.O. Box 131, Cheongryang, Seoul 130–650, Republic of Korea
Sang-Soo Lee
Affiliation:
Materials Science and Technology Division, Polymer Hybrid Research Center, Korea Institute of Science and Technology, P.O. Box 131, Cheongryang, Seoul 130–650, Republic of Korea
Junkyung Kim
Affiliation:
Materials Science and Technology Division, Polymer Hybrid Research Center, Korea Institute of Science and Technology, P.O. Box 131, Cheongryang, Seoul 130–650, Republic of Korea
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Abstract

Complete delamination of clay in polymer matrix has been strongly prohibited due to strong adhesion of guest polymer chains between hydrophilic clay as well as degradation and desorption of organic materials in the gallery at high temperature. Incorporation of charged nanosized polystyrene beads directly into the gallery of pristine clay through exfoliation-exchange mechanism has been proposed to overcome the drawbacks.

Synthesis of polymer nanobeads via emulsifier-free emulsion polymerization allowed to achieving formation of particles of appropriate particle size and surface charge density. Surface characterization, performed with XPS and ToF SIMS, has provided the results on the existence and the nature of the functional groups on the polymer particle surface, which have been found to be in a good compliance.

Morphology of polymer-incorporated clay was observed from TEM, FE-SEM images. Study on mechanism of incorporation via XRD, XPS, ToF-SIMS suggested that adsorption of polymer nanobeads through cationic exchange of intergallery cation of clay for onium ion at the surface of polymer nanobead not only improves compatibility of clay with polymer matrix, but, what is essential, dramatically promotes expansion of clay gallery.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 847: Symposium EE – Organic/Inorganic Hybrid Materials , 2004 , EE9.25
Copyright
Copyright © Materials Research Society 2005

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References

REFERENCES

1. Alexandre, M., Dubois, P., J. Mater. Sci. Eng., R Rep. 28, 1 (2000).Google Scholar
2. Polymer-clay nanocomposites, edited by Pinnavaia, T. J. and Beall, G.W. (John Wiley & Sons, Ltd., Chichester, 2000), p. 241.Google Scholar
3. Vaia, R.A. and Giannelis, E.P., J. Macromol. 30, 8000 (1997).Google Scholar
4. Vaia, R.A., Jandt, K.D., Kramer, E.J., Giannelis, E.P., Chem. Mater. 8 2628 (1996).Google Scholar
5. Fu, X., Qutubuddin, S.. Polymer 42 807 (2001).Google Scholar
6. Kato, C., Kuroda, K., Takahara, H.. Clay and Clay Miner. 29 294 (1981).Google Scholar
7. Fu, X., Qutubuddin, S.. Mat. Lett. 42 (2000).Google Scholar
8. Doh, J.G., Cho, I.. Polym. Bull. 41 511 (1998).Google Scholar
9. Chen, G., Ma, Y., Qi, Z.. Scripta mater. 44 125 (2001).Google Scholar
10. Akelah, A. and Moet, A.. J. Mater. Sci. 31 3589 (1996).Google Scholar
11. Weimer, M.W., Chen, H., Giannelis, E.P., Sogah, D.Y., J. Am. Chem. Soc. 121 1615 (1999).Google Scholar
12. Park, C.I., Park, O.O., Lim, J.G., Kim, H.J.. Polym. 42 7465 (2001).Google Scholar
13. van Olphen, H.. Clay Colloid Chemistry For Clay Technologists, Geologists, and Soil Scientists. (John Wiley & Sons, Inc. New York, London, Sydney, 1963), p.244.Google Scholar
14. Khvan, S., Gu, H.H., Lee, S-S., Kim., J., presented at the 2004 Fall PPS Asia-Australia Meeting, Gyeongju, Korea, 2004 (unpublished, prepared for submission).Google Scholar
15. Liu, Z., Xiao, H., Wiseman, N., Zheng, A., Coll. Polym. Sci. 281 815 (2003).Google Scholar
16. High Resolution XPS of Org. Polym.: the Scienta ESCA300 Database (1992)Google Scholar