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Metal/Self-Assembled Monolayer/Metal Junctions for Magnetoelectronic Applications.

Published online by Cambridge University Press:  10 February 2011

Y. A. Ovchenkov
Affiliation:
Department of Physics and Astronomy, University of Nebraska-Lincoln, Lincoln, NE 68588–0111
Chunjuan Zhang
Affiliation:
Department of Chemistry, University of Nebraska-Lincoln, Lincoln, NE 68588–0304
J. Redepenning
Affiliation:
Department of Chemistry, University of Nebraska-Lincoln, Lincoln, NE 68588–0304
B. Doudin
Affiliation:
Department of Chemistry, University of Nebraska-Lincoln, Lincoln, NE 68588–0304
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Abstract

Metal/organic self-assembled monolayer/metal junctions were investigated for junction areas 10-2 to 102 μm2. Several types and thickness of monolayers are investigated, and magnetic electrodes were made. Electroless deposition was used to make the top metal without disrupting the organic film. This deposition is activated with Pd clusters obtained by evaporation or by chemical reduction of a Pd-based catalyst. This method allows us to obtain a high yield of junctions that are not electrically shorted and are mechanically and electrically stable over a wide temperature range. Low-temperatures investigations reveal strong non-linearity in the IV curves and an increase of resistance with decreasing temperature. Zero bias anomalies observed at low temperatures are attributed to a Coulomb blockade associated with the Pd clusters.

Type
Research Article
Copyright
Copyright © Materials Research Society 2003

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