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A solvothermal decomposition process for fabrication and particle sizes control of Bi2S3 nanowires

Published online by Cambridge University Press:  31 January 2011

Shu-Hong Yu ,
Lei Shu ,
Jian Yang ,
Zhao-Hui Han ,
Yi-Tai Qian  and
Yu-Heng Zhang
Shu-Hong Yu*
Affiliation:
Structure Research Laboratory and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, People's Republic of China
Lei Shu
Affiliation:
Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, People's Republic of China
Jian Yang
Affiliation:
Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, People's Republic of China
Zhao-Hui Han
Affiliation:
Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, People's Republic of China
Yi-Tai Qian*
Affiliation:
Structure Research Laboratory and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, People's Republic of China
Yu-Heng Zhang
Affiliation:
Structure Research Laboratory and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, People's Republic of China
*
a)Address all correspondence to this author. e-mail: shyu@ustc.edu.cn
a)Address all correspondence to this author. e-mail: shyu@ustc.edu.cn
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Abstract

A novel one-step solvothermal decomposition process (SDP) was successfully developed for fabrication of Bi2S3 nanowires via a reaction between BiCl3 and thiourea in polar solvents at 140 °C for 6–12 h. The influence of solvents, reaction temperature, and reaction time on the formation of Bi2S3 nanowires was investigated. The yield was as high as 98%. The particle sizes of Bi2S3 nanowires are controlled by the choice of solvents. The possible formation mechanism of Bi2S3 nanowires via the so-called SDP method is proposed. The present technique is expected to synthesize other nanostructural metal chalcogenides under mild conditions.

Type
Articles
Information
Journal of Materials Research , Volume 14 , Issue 11 , November 1999 , pp. 4157 - 4162
Copyright
Copyright © Materials Research Society 1999

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