Hostname: page-component-76fb5796d-5g6vh Total loading time: 0 Render date: 2024-04-25T12:10:56.321Z Has data issue: false hasContentIssue false

RESEARCH ARTICLE: Soil Contaminant Attenuation Characterization in an Army Impact Area

Published online by Cambridge University Press:  25 October 2006

Stephen T. Houston
Affiliation:
Department of Geography and Environmental Engineering, United States Military Academy, West Point, New York
Get access

Abstract

Chemical contaminants—such as explosives from unexploded ordnance and impact—found within cratered areas on military firing ranges are subject to environmental fate and transport processes. Depending on the solubility and charge of the pollutant, soils with higher fractions of organic carbon and/or higher cation exchange capacities may inhibit movement of contaminants and provide time for contaminant transformation and degradation to take place before resources such as groundwater are impacted. Cation exchange capacity should allow the use of the retardation factor approach in determining the relative risk for organic contaminant releases to soils. A soil property investigation, involving the collection of soil samples from an active impact area and subsequent mathematical modeling and statistical analysis of soil laboratory results, was used to determine the soil properties that best predict soil cation exchange capacity and describe crater disturbance, in terms of the resulting loss of organic matter. Organic matter content of the soil, in this study, proved to be a good predictor of cation exchange capacity and also a good descriptor of munitions disturbance. Because soil organic matter has an influence on contaminant fate and transport through the environment, and because its availability is affected by munitions disturbance, resource managers should be concerned with the effect of munitions use on soil organic matter dynamics.

Type
FEATURES & REVIEWS
Copyright
© 2006 National Association of Environmental Professionals

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Brady, N. C., and R. R. Weil. 2001. The Nature and Properties of Soils, 13th Edition. Prentice Hall, Upper Saddle River, NJ, 960 pp.
Brannon, J. M., and T. E. Myers. 1997. Review of Fate and Transport Processes of Explosives. Technical Report IRRP-97-21. US Army Corps of Engineers, Waterways Experiment Station, Vicksburg, MS, 24 pp.
Brannon, J. M., P. N. Deliman, J. A. Gerald, C. E. Ruiz, C. B. Price, C. Hayes, S. Yost, and M. Qasim. 1999. Conceptual Model and Process Descriptor Formulations for Fate and Transport of UXO. Technical Report IRRP-99-1. US Army Corps of Engineers, Waterways Experiment Station, Vicksburg, MS, 47 pp.
Center for the Ecological Management of Military Lands. 1999. Alaska Army Lands Withdrawal Renewal: Final Legislative Environmental Impact Statement, volume II. US Army Alaska, Department of the Army; Center for the Ecological Management of Military Lands, Colorado State University, Fort Collins, 369 pp.
Comfort, S. D., P. J. Shea, L. S. Hundal, Z. Li, B. L. Woodbury, J. L. Martin, and W. L. Powers. 1995. TNT Transport and Fate in Contaminated Soil. Journal of Environmental Quality 24(6):11741182.Google Scholar
Demarais, S., D. J. Tazik, P. J. Guertin, and E. E. Jorgensen. 1999. Disturbance Associated with Military Exercises. In Ecosystems of Disturbed Ground, L. R. Walker, ed. Elsevier, Amsterdam, 900 pp.
Freeze, R. A., and J. A. Cherry. 1979. Groundwater. Prentice Hall, Englewood Cliffs, NJ, 604 pp.
Houston, S. T. 2002. Simulation of Munitions Effects on Ecosystem Contamination in an Army Impact Area. PhD Dissertation. Colorado State University, Fort Collins, CO, 192 pp.
Hundal, L. S., P. J. Shea, S. D. Comfort, W. L. Powers, and J. Singj. 1997. Long-Term TNT Sorption and Bound Residue Formation in Soil. Journal of Environmental Quality 26(3):896904.Google Scholar
Jorgenson, M. T., J. E. Roth, M. D. Smith, S. Schlentner, W. Lentz, E. R. Pullman, and C. H. Racine. 2001. An Ecological Land Survey for Fort Greely, Alaska. Technical Report TR-01-4. US Army Corps of Engineers, Engineer Research and Development Center, and Cold Regions Engineering Laboratory, Hanover, NH, 89 pp.
Klute, A. 1986. Methods of Soil Analysis: Part 1. Physical and Mineralogical Methods. Soil Science of America, Madison, WI, 1,188 pp.
LaGrega, M. D., P. L. Buckingham, J. C. Evans, and The Environmental Resources Management Group. 1994. Hazardous Waste Management. In McGraw-Hill Series in Water Resources and Environmental Engineering, B. J. Clark and J. M. Morriss, eds. McGraw-Hill, New York, 1,146 pp.
Larson, S. L., C. A. Weiss_Jr., M. R. Martino, and J. W. Adams. 1998. Role of Expandable Clays in the Environmental Fate of Trinitroluene Contamination. Technical Report IRRP-98-6. US Army Corps of Engineers, Waterways Experiment Station, Vicksburg, MS, 50 pp.
Myers, T. E., J. M. Brannon, J. C. Pennington, W. M. Davis, K. F. Myers, D. M. Townsend, M. K. Ochman, and C. A. Hayes. 1998. Laboratory Studies of Soil Sorption/Transformation of TNT, RDX, and HMX. Technical Report IRRP-98-8. Installation Restoration Research Program, US Army Corps of Engineers, Waterways Experiment Station, Vicksburg, MS, 79 pp.
Ott, R. L. 1993. An Introduction to Statistical Methods and Data Analysis, 4th Edition. Wadsworth Publishing Company, Belmont, CA, 1,038 pp.
Pennington, J. C., P. H. Miyares, D. B. Ringelberg, M. Zakikhani, C. M. Reynolds, D. Felt, R. B. Coffin, D. Gunnison, L. Cifuentes, H. L. Fredrickson, and T. F. Jenkins. 1999. Natural Attenuation of Explosives in Soil and Water Systems at Department of Defense Sites: Final Report. Technical Report SERDP-99-1. Strategic Environmental Research and Development Program, US Army Corps of Engineers, Waterways Experiment Station, Vicksburg, MS, 54 pp.
Roberts, P. V., M. Reinhard, and A. J. Valocchi. 1982. Movement of Organic Contaminants in Groundwater: Implications for Water Supply. Journal of the American Water Works Association 74:408413.Google Scholar
Spark, D. L., ed. 1996. Methods of Soil Analysis: Part 3, Chemical Methods. Soil Science Society of America, Madison, WI, 1,390 pp.
Verschueren, K. 2001. Handbook of Environmental Data on Organic Chemicals, 4th Edition. Wiley, New York, 2,416 pp.
Walsh, M. E., C. M. Collins, C. H. Racine, T. F. Jenkins, A. B. Gelvin, and T. A. Ranney. 2001. Sampling for Explosives Residues at Fort Greely, Alaska: Reconnaissance Visit July 2000. Technical Report TR-01-15. US Army Corps of Engineers, Engineer Research and Development Center, and Cold Regions Engineering Laboratory, Hanover, NH, 49 pp.
Weissmahr, K. W., S. B. Haderlein, and R. P. Schwarzenbach. 1998. Complex Formation of Soil Minerals with Nitroaromatic Explosives and Other π-Acceptors. Soil Science Society of America Journal 62:369378.Google Scholar