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Electronic Transport Measurements in Tin Oxide Microfibers Created From a Polymer Solution

Published online by Cambridge University Press:  01 February 2011

Maria Taku ,
Chris Rodd  and
Jorge Santiago
Maria Taku
Affiliation:
takua@seas.upenn.edu, University of Pennsylvania, Electrical & Systems Engineering, 220 South 33rd Street, Towne 110, Philadelphia, PA, 19104, United States
Chris Rodd
Affiliation:
rodd@seas.upenn.edu, University of Pennsylvania, Materials Science & Engineering, 220 South 33rd Street, Towne 110, Philadelphia, PA, 19104, United States
Jorge Santiago
Affiliation:
santiago@seas.upenn.edu, University of Pennsylvania, Electrical & Systems Engineering, 220 South 33rd Street, Towne 110, Philadelphia, PA, 19104, United States
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Abstract

Tin oxide microfibers were created through electrospinning using a precursor solution consisting of poly(ethylene oxide) (PEO) and chloroform (CHCl3) which was then mixed with its tin precursor, dimethyldineodecanoatin (C22H44O4Sn). Since the conductivity of SnO2 is affected by any chemisorbed oxygen molecules on its surface, this semiconductor has high potential for use as a gas sensor for both oxidizing and reducing gases. Due to the fact that a greater surface area will produce gas sensors with improved sensitivity, work is underway to reduce the fibers size into the nanoscale range. Thus, this study explores various electronic transport characteristics—such as the conductivity and magnetoresistance—of the tin oxide microfibers. Additionally, the composition and phase of the fibers were characterized through XRD and Raman spectroscopy.

Keywords

magnetoresistance (transport)electrical propertiesSn
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 948: Symposium B – Structure, Processing and Properties of Polymer Nanofibers for Emerging Technologies , 2006 , 0948-B01-05
Copyright
Copyright © Materials Research Society 2007

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References

REFERENCES

1. Wang, Y., Aponte, M., Leon, N., Ramos, I., Furlan, R., and Santiago-Avilés, J., “Synthesis and Characterization of Ultra-Fine Tin Oxide Microfibers Using Electrospinning”, Journal of the American Ceramic Society, 88 (8) (2005): 2059–2063.Google Scholar
2. Wang, Y., Aponte, M., Leon, N., Ramos, I., Furlan, R., and Santiago-Avilés, J., “Synthesis and Characterization of Tin Oxide Microfibers Electrospun From a Simple Precursor Solution”, Semiconductor Science and Technology, 19 (2004): 1057–1060.Google Scholar
3. Lui, Z., Zhang, D., Han, S., Li, C., Tang, T., Jin, W., Liu, X., Lei, B., and Zhou, C, “Laser Ablation Synthesis and Electron Transport Studies of Tin Oxide Nanowires”, Advanced Materials, 15 No 20 (2003): 1754–1757.Google Scholar
4. Kolmakov, A., Zhang, Y., Cheng, G., and Moskovits, M., “Detection of CO and O2 Using Tin Oxide Nanowire Sensors”, Advanced Materials, 15 No 12 (2003): 997–1000.Google Scholar
5. Xu, C., Xu, G., Liu, Y., Zhao, X., and Wang, G., “Preparation and Characterization of SnO2 Nanorods by Thermal Decomposition of SnC2O4 Precursor”, Scripta Materialia, 46 (2002): 789–794.Google Scholar
6. Nayral, C., Viala, E., Colliere, V., Fau, P., Senocq, F., Maisonnat, A., and Chaudret, B., “Synthesis and Use of a Novel SnO2 Nanomaterial for Gas Sensing”, Applied Surface Science, 164 (2000): 219–226.Google Scholar
7. Pan, Z., Dai, Z., and Wang, Z., “Nanobelts of Semiconducting Oxides”, Science, 291 (2001): 1947–1949.Google Scholar
8. Norris, I., Shaker, M., Ko, F., and MacDiarmid, A., “Electrostatic Fabrication of Ultrafine Conducting Fibers: Polyaniline/Polyethylene Oxide Blends”, Synthetic Materials, 114 (2000): 109–114.Google Scholar
9. Kissine, V., Voroshilov, S., and Sysoev, V., “A Comparative Study of SnO2 and SnO2:Cu Thin Films for Gas Sensor Applications”, Thin Solid Films, 348 (1999): 304–311.Google Scholar
10. Dai, Z., Gole, J., Stout, D., and Wang, Z, “Tin Oxide Nanowires, Nanoribbons, and Nanotubes”, Journal of Physical Chemistry B, 106 (2002): 1274–1279.Google Scholar
11. Comini, E., Faglia, G., and Sberveglieri, G., “Stable and Highly Sensitive Gas Sensors Based on Semiconducting Oxide Nanobelts”, Applied Physics Letters, 81 10 (2002): 1869–1871.Google Scholar
12. Ramakrishna, , Fujihara, , Teo, , Lim, and Ma, , An Introduction to Electrospinning and Nanofibers, (Singapore World Scientific Publishing, Singapore, 2005)Google Scholar
13. Mott, N. F. and Davis, E., Electronic Processes in Non-Crystalline Materials, (Clarendon Press, Oxford, 1971), second edition.Google Scholar