Hostname: page-component-8448b6f56d-cfpbc Total loading time: 0 Render date: 2024-04-23T18:29:18.048Z Has data issue: false hasContentIssue false
  • English
  • Français

X-Ray And Neutron Small Angle Scattering Investigations On Precursor Derived B-C-N Ceramics

Published online by Cambridge University Press:  10 February 2011

D. Sauter ,
S. Schempp ,
M. Weinmann ,
A. Müller ,
J. Bill ,
P. Lamparter  and
F. Aldinger
D. Sauter
Affiliation:
Universität Stuttgart, Institut für Nichtmetallische Anorganische Materialien, Pulvermetallurgisches Laboratorium, Heisenbergstr. 5, 70569 Stuttgart
S. Schempp
Affiliation:
Max-Planck-Institut für Metallforschung, Seestraβe 92, 70174 Stuttgart
M. Weinmann
Affiliation:
Max-Planck-Institut für Metallforschung, Heisenbergstr. 5, 70569 Stuttgart
A. Müller
Affiliation:
Universität Stuttgart, Institut für Nichtmetallische Anorganische Materialien, Pulvermetallurgisches Laboratorium, Heisenbergstr. 5, 70569 Stuttgart
J. Bill
Affiliation:
Universität Stuttgart, Institut für Nichtmetallische Anorganische Materialien, Pulvermetallurgisches Laboratorium, Heisenbergstr. 5, 70569 Stuttgart
P. Lamparter
Affiliation:
Max-Planck-Institut für Metallforschung, Seestraβe 92, 70174 Stuttgart
F. Aldinger
Affiliation:
Max-Planck-Institut für Metallforschung, Heisenbergstr. 5, 70569 Stuttgart Universität Stuttgart, Institut für Nichtmetallische Anorganische Materialien, Pulvermetallurgisches Laboratorium, Heisenbergstr. 5, 70569 Stuttgart
Get access

Abstract

Amorphous 11B31,9C36,8N31,3 ceramic samples were produced by thermolysis of poly(borosesquicarbodiimide) of idealized formula [B2(NCN)3]n at 1100°C in inert gas atmosphere. Small angle scattering (SAS) experiments reveal, that the as-obtained ceramics are chemically inhomogeneous. Using small angle neutron and X-ray scattering measurements, the temperature dependency of the medium range order was investigated. The SAS curves show a strong temperature dependence of the Guinier-radius (RG) of the scattering regions. Contrast variation by X-ray and neutron diffraction shows that the observed SAS signal is caused by amorphous BC2N enclosing amorphous boron-nitride segregations. The fact, that the measured invariant remains constant over the whole temperature range supports the view of complete phase separation.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 576: Symposium DD – Organic/Inorganic Hybrid Materials II , 1999 , 39
Copyright
Copyright © Materials Research Society 1999

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Bill, J. and Aldinger, F., Adv. Mater., 7 (9), 775–785 (1995).10.1002/adma.19950070903Google Scholar
2. Aldinger, F., Bill, J. and Wurm, K., Offenlegungsschrift DE 196 34 777 A1 (1998).Google Scholar
3. Guinier, A. and Fournet, G., Small-Angle Scattering of X-Rays, (John Wiley & Sons, New York and Chapman and Hall, London, 1955) pp. 1–78.Google Scholar
4. Dürr, J., Schempp, S., Lamparter, P., Bill, J., Steeb, S. and Aldinger, F., Solid State Ionics, 101–103, 1041–1047 (1997).10.1016/S0167-2738(97)00166-5Google Scholar
5. Kratky, O. and Porod, G., Small-Angle X-ray Scattering, (Academic Press, London/New York, 1982) pp. 3–53.Google Scholar
6. Feigin, L. A., Servgun, D. I., Structure Analysis by Small Angle X-ray and Neutron Scattering, (Plenum Press, New York/London, 1987) pp. 59–90.10.1007/978-1-4757-6624-0_3Google Scholar
7. Alfa, , Finest Inorganic Research Chemicals and Metals, (Johnson Matthey, Karisruhe, 1997/98).Google Scholar
8. Cohen, M. L., J. Hard Mater., 2, 13 (1991).Google Scholar
9. Bill, J., PhD thesis, University of Stuttgart, 1993.Google Scholar
10. Koester, L., Yelon, W. B., Neutron Diffraction Newsletter, 1983.Google Scholar
11. Schempp, S., Dürr, J., Lamparter, P., Bill, J. and Aldinger, F., Z. Naturforschung, 53a, 127–133 (1998).Google Scholar