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Synthesis of Pt-TM(transition metals) Catalysts and Their Hydrogenation Ability of Methyl Acrylate

Published online by Cambridge University Press:  31 January 2011

Miki Amari
Affiliation:
asama.ishi@gmail.com
Satoshi Okada
Affiliation:
ri_dial@hotmail.com, Tokyo University of Science, Chiba, Japan
Masahiko Demura
Affiliation:
DEMURA.Masahiko@nims.go.jp, NIMS, Fuel Cell Material Center, Tsukuba, Japan
Keishi Nishio
Affiliation:
k-nishio@rs.noda.tus.ac.jp, Tokyou University of Science, Materials Science and Technology, 2641 yamazaki, Noda-shi, 278-8510, Japan
Hirobumi Shibata
Affiliation:
shibata@rs.noda.tus.ac.jp, Tokyo University of Science, Department of Materials Science and Technology, Noda, Japan
Tohru Kineri
Affiliation:
tkineri@ed.yama.tus.ac.jp, Tokyo University of Science, Yamaguchi, Materials Science & Environmental Engineering, Sanyo-Onoda-shi, Japan
Takahiro Gunji
Affiliation:
gunji@rs.noda.tus.ac.jp, Tokyo University of Science, Department of Pure and Applied Chemistry, 2641 Yamazaki, Noda, 278-8510, Japan, +81-4-7122-9499, +81-4-7123-9890
Ryuji Tamura
Affiliation:
tamura@rs.noda.tus.ac.jp, Tokyo University of Science, 2641 Yamazaki, Noda, Chiba, Tokyo, 278-8510, Japan
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Abstract

We have prepared a number of Pt-TM(transition metals) alloys with various TM elements and evaluated their catalytic abilities by means of hydrogenation of methyl acrylate. High catalytic activities are obtained when the crystalline structures are similar, i.e., fcc structure, indicating that the crystal structure of a catalyst plays an important role in hydrogenation of methyl acrylate. Furthermore, for a certain TM element, i.e., Mo, the catalytic activity is found to surpass that of Pt metal.

Type
Research Article
Copyright
Copyright © Materials Research Society 2010

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