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Raman and Photoluminescence Spectroscopic Study of 1-Undecene Functionalized Nanodiamonds

Published online by Cambridge University Press:  02 December 2013

Y. Astuti ,
N. R. J. Poolton  and
L. Šiller
Y. Astuti
Affiliation:
School of Chemical Engineering and Advanced Materials, Newcastle University, Newcastle upon Tyne, NE1 7RU, UK Chemistry Department, Science and Mathematics Faculty, Diponegoro University, Central Java, 50275, Indonesia
N. R. J. Poolton
Affiliation:
Spectral Imaging Systems, 36 Waterside House, Denton Mill, Carlisle CA2 5HF, UK
L. Šiller
Affiliation:
School of Chemical Engineering and Advanced Materials, Newcastle University, Newcastle upon Tyne, NE1 7RU, UK
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Abstract

Nanodiamond holds great interest in a variety of optical applications, the properties being correlated with surface modification, and the presence of both impurities and defects (contained either on their surface or within the crystal structure). Undecyl-nanodiamond produced by attachment of 1-undecene onto the nanodiamond surface could be a good candidate as a luminescent marker in the future; therefore, understanding of its optical properties is essential. In this work, the optical properties of the acid-purified nanodiamond and undecyl-nanodiamond were characterised using surface enhanced Raman spectroscopy (SERS) and photoluminescence spectroscopy. The results demonstrate that the characteristic diamond Raman signal at 1330 cm-1 was still observed after chemical surface modification, while the signal at ∼1600 cm-1 (attributed to graphite bands) disappeared after the modification. Broad photoluminescence emission is detected in the range 1.5-2.5 eV (500-800 nm), as typically found for isolated nanodiamond; these emission bands became narrower with attachment of 1-undecene as compared to the sample without surface functionalisation. The observed emission could be related to structural disorder on the nanodiamond surface. The temperature dependence of the intensity, peak position and band widths of each sample has been characterised.

Keywords

optical propertiesluminescencediamond
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1597: Symposium N – Nanodiamond-From Basics to Medical and Other Potential Applications , 2014 , jsapmrs13-7187
Copyright
Copyright © Materials Research Society 2013 

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