Hostname: page-component-8448b6f56d-cfpbc Total loading time: 0 Render date: 2024-04-18T01:36:16.964Z Has data issue: false hasContentIssue false
  • English
  • Français

Synthesis of hcp-Co and mixture of hcp/fcc-Co crystals: Insight into their Congo red removal ability

Published online by Cambridge University Press:  17 April 2014

Lixia Wang ,
Lijun Zhao  and
Min Wang
Lixia Wang*
Affiliation:
Key Laboratory of Applied Chemistry, College of Chemistry, Chemical Engineering and Food Safety, Bohai University, Jinzhou 121013, China
Lijun Zhao
Affiliation:
Key Laboratory of Automobile Materials, Ministry of Education and School of Materials Science and Engineering, Jilin University, Changchun 130022, China
Min Wang
Affiliation:
Key Laboratory of Applied Chemistry, College of Chemistry, Chemical Engineering and Food Safety, Bohai University, Jinzhou 121013, China
*
a)Address all correspondence to this author. e-mail: wlxdqpi@163.com
Get access

Abstract

Cobalt crystals with hcp or hcp/fcc mixed structure were prepared by a solvothermal process based on the dosages of N2H4·H2O and the effect of crystal structure on their magnetic properties and Congo red (CR) removal abilities was studied. To our best knowledge, it is the first report on CR removal by micrometer and submicrometer sizes of Co crystals with the best CR removal ability reaching 694.4 mg g−1. For the hcp and fcc mixed structure, the degree of mixing can be clearly observed from the high-resolution transmission electron microscopy images. The micrometer and submicrometer sizes of Co crystals will be good for magnetic separation after CR removal.

Keywords

adsorptioncrystallographic structuremagnetic properties
Type
Articles
Information
Journal of Materials Research , Volume 29 , Issue 8 , 28 April 2014 , pp. 989 - 995
Copyright
Copyright © Materials Research Society 2014 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Zhang, J.M., Wang, D.D., and Xu, K.W.: Calculation of the surface energy of hcp metals by using the modified embedded atom method. Appl. Surf. Sci. 253, 2018 (2006).CrossRefGoogle Scholar
Fu, B.Q., Liu, W., and Li, Z.L.: Calculation of the surface energy of fcc-metals with the empirical electron surface model. Appl. Surf. Sci. 256, 6899 (2010).CrossRefGoogle Scholar
Aghemenloh, E., Idiodi, J.O.A., and Azi, S.O.: Surface energies of hcp metals using equivalent crystal theory. Comp. Mater. Sci. 46, 524 (2009).CrossRefGoogle Scholar
Jiang, Q., Lu, H.M., and Zhao, M.: Modelling of surface energies of elemental crystals. J. Phys.: Condens. Matter. 16, 521 (2004).Google Scholar
Li, Y.D., Li, L.Q., Liao, H.W., and Wang, H.R.: Preparation of pure nickel, cobalt, nickel-cobalt and nickel-copper alloys by hydrothermal reduction. J. Mater. Chem. 9, 2675 (1999).CrossRefGoogle Scholar
Xu, R., Xie, T., Zhao, Y.G., and Li, Y.D.: Single-crystal metal nanoplatelets: Cobalt, nickel, copper, and silver. Cryst. Growth Des. 7, 1904 (2007).CrossRefGoogle Scholar
Duan, L.F., Jia, S.S., and Zhao, L.J.: Synthesis and characterization of metallic Co with different hierarchical structures prepared by a simple solvothermal method. Eur. J. Inorg. Chem. 13, 1957 (2010).CrossRefGoogle Scholar
Cao, Y.B., Zhang, X., Fan, J.M., Hu, P., Bai, L.Y., Zhang, H.B., Yuan, F.L., and Chen, Y.F.: Synthesis of hierarchical Co micro/nanocomposites with hexagonal plate and polyhedron shapes and their catalytic activities in glycerol hydrogenolysis. Cryst. Growth Des. 11, 472 (2011).CrossRefGoogle Scholar
Zhu, L.P., Zhang, W.D., Xiao, H.M., Yang, Y., and Fu, S.Y.: Facile synthesis of metallic Co hierarchical nanostructured microspheres by a simple solvothermal process. J. Phys. Chem. C 112, 10073 (2008).CrossRefGoogle Scholar
Zhang, Y.J., Yao, Q., Zhang, Y., Cui, T.Y., Li, D., Liu, W., Lawrence, W., and Zhang, Z.D.: Solvothermal synthesis of magnetic chains self-assembled by flowerlike cobalt submicrospheres. Cryst. Growth Des. 8, 3206 (2008).CrossRefGoogle Scholar
Duan, L.F., Jia, S.S., Cheng, R.M., and Zhao, L.J.: Synthesis and characterization of Co sub-micro chains by solvothermal route: Process design, magnetism and excellent thermal stability. Chem. Eng. J. 173, 233 (2011).CrossRefGoogle Scholar
Nguyen, T.D., Phan, N.H., Do, M.H., and Ngo, K.T.: Magnetic Fe2MO4 (M = Fe, Mn) activated carbons: Fabrication, characterization and heterogeneous Fenton oxidation of methyl orange. J. Hazard. Mater. 185, 653 (2011).CrossRefGoogle ScholarPubMed
Wu, R.C. and Qu, J.H.: Removal of water-soluble azo dye by the magnetic material MnFe2O4. J. Chem. Technol. Biotechnol. 80, 20 (2005).CrossRefGoogle Scholar
Iram, M., Guo, C., Guan, Y.P., Ishfaq, A., and Liu, H.Z.: Adsorption and magnetic removal of neutral red dye from aqueous solution using Fe3O4 hollow nanospheres. J. Hazard. Mater. 181, 1039 (2010).CrossRefGoogle ScholarPubMed
Chen, C.P., Gunawan, P., and Zhou, R.X.: Self-assembled Fe3O4-layered double hydroxide colloidal nanohybrids with excellent performance for treatment of organic dyes in water. J. Mater. Chem. 21, 1218 (2011).CrossRefGoogle Scholar
Afkhami, A., Tehrani, M.S., and Bagheri, H.: Modified maghemite nanoparticles as an efficient adsorbent for removing some cationic dyes from aqueous solution. Desalination 263, 240 (2010).CrossRefGoogle Scholar
Xiong, J.B., He, Z.L., Mahmood, Q., Liu, D., Yang, X., and Islam, E.: Phosphate removal from solution using steel slag through magnetic separation. J. Hazard. Mater. 152, 211 (2008).CrossRefGoogle ScholarPubMed
Shen, Y.F., Tang, J., Nie, Z.H., Wang, Y.D., Ren, Y., and Zuo, L.: Preparation and application of magnetic Fe3O4 nanoparticles for wastewater purification. Sep. Purif. Technol. 68, 312 (2009).CrossRefGoogle Scholar
Tuutijärvi, T., Lu, J., Sillanpää, M., and Chen, G.: As(V) adsorption on maghemite nanoparticles. J. Hazard. Mater. 166, 1415 (2009).CrossRefGoogle ScholarPubMed
Liu, Z.G., Zhang, F.S., and Sasai, R.: Arsenate removal from water using Fe3O4-loaded activated carbon prepared from waste biomass. Chem. Eng. J. 160, 57 (2010).CrossRefGoogle Scholar
Zhao, X.L., Wang, J.M., Wu, F.C., Wang, T., Cai, Y.Q., Shi, Y.L., and Jiang, G.B.: Removal of fluoride from aqueous media by Fe3O4@Al(OH)3 magnetic nanoparticles. J. Hazard. Mater. 173, 102 (2010).CrossRefGoogle ScholarPubMed
Sun, L., Chen, L.G., Sun, X., Du, X.B., Yue, Y.S., He, D.Q., Xu, H.Y., Zeng, Q.L., Wang, H., and Ding, L.: Analysis of sulfonamides in environmental water samples based on magnetic mixed hemimicelles solid-phase extraction coupled with HPLC–UV detection. Chemosphere 77, 1306 (2009).CrossRefGoogle ScholarPubMed
Dmitry, P.D. and Bawendi, M.G., and A solution-phase chemical approach to a new crystal structure of cobalt. Angew. Chem. Int. Ed. 38, (12) 1788–1791 (1999).Google Scholar
Liu, Z.T., Li, X., and Liu, Z.W.: Synthesis and catalytic behaviors of cobalt nanocrystals with special morphologies. J. Powder Technol. 189, 514 (2009).CrossRefGoogle Scholar
Sato, H., Kitakami, O., Sakurai, T., Shimada, Y., Otani, Y., and Fukamichi, K.: Structure and magnetism of hcp-Co fine particles. J. Appl. Phys. 81, 1858 (1997).CrossRefGoogle Scholar
Ohodnicki, P.R. Jr., Keylin, V., McWilliams, H.K., Laughlin, D.E., and McHenry, M.E.: Phase evolution and field-induced magnetic anisotropy of the nanocomposite three-phase fcc, hcp, and amorphous soft magnetic alloy Co89Zr7B4. J. Appl. Phys. 103, 07E740 (2008).CrossRefGoogle Scholar
Ohodnicki, P.R. Jr., Qin, Y.L., McHenry, M.E., Laughlin, D.E., and . Keylin, V: Transmission electron microscopy study of large field induced anisotropy (Co1−xFex)89Zr7B4 nanocomposite ribbons with dilute Fe-contents. J. Magn. Magn. Mater. 322, 315 (2010).CrossRefGoogle Scholar
O’Handley, R.C., Corb, B.W., and Grant, N.J.: Reversible structural transformation in cobalt‐base amorphous alloys. J. Appl. Phys. 55, 1808 (1984).CrossRefGoogle Scholar
Li, F.H., Bao, Y., Chai, J., Zhang, Q.X., Han, D.X., and . Niu, L: Synthesis and application of widely soluble graphene sheets. Langmuir 26, 12314 (2010).CrossRefGoogle ScholarPubMed
Deng, S.D., Li, X.H., and Fu, H.: Acid violet 6B as a novel corrosion inhibitor for cold rolled steel in hydrochloric acid solution. Corros. Sci. 53, 760 (2011).CrossRefGoogle Scholar
Zhang, G.S., Qu, J.H., Liu, H.J., Cooper, A.T., and Wu, R.C.: CuFe2O4/activated carbon composite: A novel magnetic adsorbent for the removal of acid orange II and catalytic regeneration. Chemosphere 68, 1058 (2007).CrossRefGoogle ScholarPubMed
Liang, X.M. and Zhao, L.J.: Room-temperature synthesis of air-stable cobalt nanoparticles and their highly efficient adsorption ability for Congo red. RSC Adv. 2, 5485–5487 (2012).CrossRefGoogle Scholar
Afkhami, A. and Moosavi, R.: Adsorptive removal of Congo red, a carcinogenic textile dye, from aqueous solutions by maghemite nanoparticles. J. Hazard. Mater. 174, 398 (2010).CrossRefGoogle ScholarPubMed
Zhai, Y., Zhai, J.F., Zhou, M., and J. Dong, S.: Ordered magnetic core–manganese oxide shell nanostructures and their application in water treatment. J. Mater. Chem. 19, 7030 (2009).CrossRefGoogle Scholar
Zhang, Y.X., Xu, S.C., Luo, Y., Pan, S., Ding, H., and Li, G.H.: Synthesis of mesoporous carbon capsules encapsulated with magnetite nanoparticles and their application in wastewater treatment. J. Mater. Chem. 21, 3664 (2011).CrossRefGoogle Scholar
Wang, L.X., Li, J.C., Wang, Y.Q., and Zhao, L.J.: Preparation of nanocrystalline Fe3−xLaxO4 ferrite and their adsorption capability for Congo red. J. Hazard. Mater. 196, 342 (2011).Google ScholarPubMed
Wang, L.X., Li, J.C., Wang, Y.Q., Zhao, L.J., and Jiang, Q.: Adsorption capability for Congo red on nanocrystalline MFe2O4 (M = Mn, Fe, Co, Ni) spinel ferrites. Chem. Eng. J. 181–182, 72 (2012).CrossRefGoogle Scholar